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At the dawn of thermodynamics, Carnot's constraint on efficiency of heat engines stimulated the formulation of one of the most universal physical principles, the second law of thermodynamics. In recent years, the field of heat engines…

Statistical Mechanics · Physics 2021-12-23 Viktor Holubec , Artem Ryabov

The second law of thermodynamics states that a system in contact with a heat bath can undergo a transformation if and only if its free energy decreases. However, the "if" part of this statement is only true when the effective heat bath is…

Quantum Physics · Physics 2018-06-27 Jonathan G. Richens , Álvaro M. Alhambra , Lluis Masanes

Whether the strong coupling to thermal baths can improve the performance of quantum thermal machines remains an open issue under active debate. Here, we revisit quantum thermal machines operating with the quasi-static Carnot cycle and aim…

Statistical Mechanics · Physics 2024-04-10 Junjie Liu , Kenneth A. Jung

Thermodynamics is the phenomenological theory of heat and work. Here we analyze to what extent quantum thermodynamic relations are immune to the underlying mathematical formulation of quantum mechanics. As a main result, we show that the…

Quantum Physics · Physics 2016-04-21 Bartłomiej Gardas , Sebastian Deffner , Avadh Saxena

We consider a class of quantum heat engines consisting of two subsystems interacting via a unitary transformation and coupled to two separate baths at different temperatures $T_h > T_c$. The purpose of the engine is to extract work due to…

Statistical Mechanics · Physics 2009-11-13 Armen E. Allahverdyan , Ramandeep S. Johal , Guenter Mahler

From thermodynamics point of view, in this era of aiming at energy conservation and sustainability, we need to develop more accurate ways to design thermal power, cooling and heat pump cycles. It has been the general practice in…

Statistical Mechanics · Physics 2013-07-23 GA Mansoori

The laws of thermodynamics strongly restrict the performance of thermal machines. Standard thermodynamics, initially developed for uncorrelated macroscopic systems, does not hold for microscopic systems correlated with their environments.…

Quantum Physics · Physics 2025-11-13 Milton Aguilar , Eric Lutz

The laws of thermodynamics are a cornerstone for describing nanoscale and open quantum systems. However, formulating these laws for systems under continuous feedback control and under experimentally relevant conditions is challenging. In…

Quantum Physics · Physics 2025-05-23 Kacper Prech , Joël Aschwanden , Patrick P. Potts

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small nonequilibrium systems. While work and heat are equally important forms of energy exchange, fluctuation relations have not been experimentally…

Statistical Mechanics · Physics 2022-02-24 Markus Rademacher , Michael Konopik , Maxime Debiossac , David Grass , Eric Lutz , Nikolai Kiesel

The second law of ordinary thermodynamics and the second law of steady state thermodynamics, as proposed by Oono and Paniconi, are investigated from the microscopic point of view for the open quantum system. Based on the H-theorem of…

Statistical Mechanics · Physics 2007-05-23 Satoshi Yukawa

A long standing open problem whether a heat engine with finite power achieves the Carnot efficiency is investigated. We rigorously prove a general trade-off inequality on thermodynamic efficiency and time interval of a cyclic process with…

Statistical Mechanics · Physics 2017-08-18 Naoto Shiraishi , Hiroyasu Tajima

The possibility of a controlled manipulation with molecules at the nanoscale allows us to gain net work from thermal energy, although this seems to be in contradiction to the Second Law of thermodynamics. Any manipulation, however, causes…

Statistical Mechanics · Physics 2019-07-03 Miroslav Holeček

We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

Statistical Mechanics · Physics 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe

Accurately describing work extraction from a quantum system is a central objective for the extension of thermodynamics to individual quantum systems. The concepts of work and heat are surprisingly subtle when generalizations are made to…

Quantum Physics · Physics 2015-03-30 Felix C. Binder , Sai Vinjanampathy , Kavan Modi , John Goold

On the one hand, the dissipated heat of a thermodynamic work extraction process upper bounds the non-predictive information, which the associated system encodes about its environment. Thus, emergent information processing capabilities can…

Neurons and Cognition · Quantitative Biology 2020-09-10 Kai Ueltzhöffer

In a thermodynamic process with measurement and feedback, the second law of thermodynamics is no longer valid. In its place, various second-law-like inequalities have been advanced that each incorporate a distinct additional term accounting…

Statistical Mechanics · Physics 2015-06-22 Jordan M. Horowitz , Henrik Sandberg

We consider a generalisation of thermodynamics that deals with multiple conserved quantities at the level of individual quantum systems. Each conserved quantity, which, importantly, need not commute with the rest, can be extracted and…

Quantum Physics · Physics 2016-07-14 Yelena Guryanova , Sandu Popescu , Anthony J. Short , Ralph Silva , Paul Skrzypczyk

How much work can be extracted from a heat bath using a thermal machine? The study of this question has a very long tradition in statistical physics in the weak-coupling limit, applied to macroscopic systems. However, the assumption that…

Quantum Physics · Physics 2015-06-17 R. Gallego , A. Riera , J. Eisert

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter

For a small driven system coupled strongly to a heat bath, internal energy and exchanged heat are identified such that they obey the usual additive form of the first law. By identifying this exchanged heat with the entropy change of the…

Statistical Mechanics · Physics 2016-02-03 Udo Seifert