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We study the optical properties of hydrogen passivated silicon, germanium and mixed Ge/Si core/shell quantum dots (QDs) using high accuracy Density Functional Theory (DFT) and time-dependent DFT (TDFT). We employ the hybrid DFT functional…

Mesoscale and Nanoscale Physics · Physics 2016-04-19 Shanawer Niaz , Aristides D. Zdetsis , Manzoor Ahmad Badar , Safdar Hussain , Imran Sadiq , Muhammad Aslam Khan

We present a comprehensive and integrated model-independent ab initio study of the structural, cohesive, electronic, and optical properties of silicon quantum dots of various morphologies and sizes in the framework of all-electron static…

Mesoscale and Nanoscale Physics · Physics 2016-03-23 Shanawer Niaz , Aristides D. Zdetsis

The electronic structure calculation for the nanoclusters of (AsSiTeB/SiAsBTe) quaternary semiconductor alloy belonging to the (III-V Group elements) is performed. The two clusters one in the linear form and the other in the bent form have…

Atomic and Molecular Clusters · Physics 2020-12-02 Ankit Kargeti , Ravikant Shrivastav , Tabish Rasheed

The atomic and electronic structure of a set of proposed thin (1.6 nm in diameter) silicon/silica quantum nanodots and nanowires with narrow interface, as well as parent metastable silicon structures (1.2 nm in diameter), was studied in…

In most of the realistic ab initio and model calculations which have appeared on the emission of light from Si nanocrystals, the role of surface oxygen has been usually ignored, underestimated or completely ruled out. We investigate…

Mesoscale and Nanoscale Physics · Physics 2016-08-03 Shanawer Niaz , Aristides D. Zdetsis , Emmanuel N. Koukaras , Oguz Gulseren , Imran Sadiq

The electronic structure and size-scaling of optoelectronic properties in cycloparaphenylene carbon nanorings are investigated using time-dependent density functional theory (TDDFT). The TDDFT calculations on these molecular nanostructures…

Chemical Physics · Physics 2009-12-24 Bryan M. Wong

We have studied the electronic and optical properties of three low-symmetry graphene quantum dots (GQDs), with the point-group symmetries $C_{2v}$, and $C_{2h}$. For the calculations of linear optical absorption spectra, we employed both…

Chemical Physics · Physics 2024-12-06 Samayita Das , Alok Shukla

The electrical, magnetic, thermal and optical characteristics of Gallium (Ga) doped silicene are investigated using density functional theory (DFT). The effect of doping is studied by tuning dopant concentrations as well as examining varied…

Materials Science · Physics 2022-04-05 Nzar Rauf Abdullah , Botan Jawdat Abdullah , Vidar Gudmundsson

The optical and electronic properties of the {\alpha}-SiTe, {\beta}-SiTe, and RX-SiTe_2 are investigated. A detailed analysis of electronic properties is done using standard density functional theory (DFT) and hybrid functional (HSE06)…

Materials Science · Physics 2021-06-30 Romakanta Bhattarai , Xiao Shen

Results of a theoretical study of the electronic properties of (Si)Ge and (Ge)Si core/shell nanoparticles, homogeneous SiGe clusters, and Ge$|$Si clusters with an interphase separating the Si and Ge atoms are presented. In general, (Si)Ge…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Abu Md. Asaduzzaman , Michael Springborg

The band structure and size-scaling of electronic properties in self-assembled cyclic oligothiophene nanotubes are investigated using density functional theory (DFT) for the first time. In these unique tubular aggregates, the {\pi}-{\pi}…

Mesoscale and Nanoscale Physics · Physics 2015-03-13 Bryan M. Wong , Simon H. Ye

Novel low-band-gap copolymer oligomers are proposed on the basis of density functional theory (DFT) quantum chemical calculations of photophysical properties. These molecules have an electron donor-accepter (D-A) architecture involving…

Chemical Physics · Physics 2017-08-18 Tarek Mestiri , Ala Aldin M. H. M. Darghouth , Mark E. Casida , Kamel Alimi

The nonlinear optical properties and electro-optic effects of some oxygen-octahedric ferroelectrics are studied by the density functional theory (DFT) in the local density approximation (LDA) expressions based on first principle…

Materials Science · Physics 2011-12-30 Amirullah M. Mamedov , Ekmel Ozbay

The size-dependent structures and optical properties of CdSeS nanoclusters in water medium are investigated. The stability of different size-dependent Cd$_n$Se$_m$S$_p$ nanoclusters (up to n=6) is studied using density functional…

Materials Science · Physics 2020-11-10 Meenakshi Rana , Papia Chowdhury

We present a comprehensive first-principles investigation of the structural, electronic, optical, and thermodynamic properties of BeX compounds (X = S, Se, Te) under hydrostatic pressures ranging from 0 to 10 GPa. Calculations were…

Materials Science · Physics 2025-10-02 Muhammad Shahzad , Sikander Azam , Syed Awais Ahmad , Ming Li

We use an efficient projection scheme for the Fock operator to analyze the size dependence of silicon quantum dots (QDs) electronic properties. We compare the behavior of hybrid, screened hybrid and local density functionals as a function…

Chemical Physics · Physics 2018-04-06 Dor Gabay , Xueyang Wang , Vitaly Lomakin , Amir Boag , Manish Jain , Amir Natan

In the present work we investigate the adequacy of broken-symmetry unrestricted density functional theory (DFT) for constructing the potential energy curve of nickel dimer and nickel hydride, as a model for larger bare and hydrogenated…

Chemical Physics · Physics 2007-05-23 Cristian V. Diaconu , Art E. Cho , J. D. Doll , David L. Freeman

Embedded density functional theory (e-DFT) is used to describe the electronic structure of strongly interacting molecular subsystems. We present a general implementation of the Exact Embedding (EE) method [J. Chem. Phys. 133, 084103 (2010)]…

Other Condensed Matter · Physics 2011-07-27 Jason D. Goodpaster , Taylor A. Barnes , Thomas F. Miller

Rare-earth trihydrides ($R$H$_3$) exhibit intriguing coupled electronic and structural properties as a function of doping, hydrogen vacancies, and thermodynamic conditions. Theoretical studies of these materials typically rely on density…

Strongly Correlated Electrons · Physics 2024-10-07 Adam Denchfield , Hyeondeok Shin , Panchapakesan Ganesh , Russell J Hemley , Hyowon Park

In the present work, the atomic and the electronic structures of Au3N, AuN and AuN2 are investigated using first-principles density-functional theory (DFT). We studied cohesive energy vs. volume data for a wide range of possible structures…

Materials Science · Physics 2015-11-24 Mohammed S. H. Suleiman , Daniel P. Joubert
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