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The electrostatic complexation between DOTAP-DOPC unilamellar liposomes and an oppositely charged polyelectrolyte (NaPA) has been investigated in a wide range of the liposome surface charge density. We systematically characterized the…

Soft Condensed Matter · Physics 2015-03-11 Simona Sennato , Laura Carlini , Domenico Truzzolillo , Federico Bordi

We examine the interactions between polyelectrolytes (PEs) and uncharged substrates at conditions corresponding to a dielectric discontinuity between the aqueous solution and the substrate. To this end, we vary the relevant system…

Soft Condensed Matter · Physics 2024-12-03 Hossein Vahid , Alberto Scacchi , Maria Sammalkorpi , Tapio Ala-Nissila

Biomolecular condensates are complex droplets comprising diverse molecules that interact using various mechanisms. Condensation is often driven by short-ranged attraction, but net charges can also mediate long-ranged repulsion. Using…

Soft Condensed Matter · Physics 2025-01-23 Chengjie Luo , Nathaniel Hess , Dilimulati Aierken , Yicheng Qiang , Jerelle A. Joseph , David Zwicker

Properties of polyelectrolytes in tetravalent salt solutions are intensively investigated by a coarse-grained model. The concentration of salt and the size of tetravalent counterions are found playing a decisive role on chain properties. If…

Soft Condensed Matter · Physics 2009-09-29 Pai-Yi Hsiao

We describe the process of electron condensation into a localized state in a structureless jellium that is coupled to a finite cavity. It is shown that there exists a temperature T_0 below which electrons within the jellium localize. This…

Mesoscale and Nanoscale Physics · Physics 2020-11-30 Pritha Mondal , Subham Kumar Saha , Awadhesh Narayan , Anshu Pandey

We study a two-dimensional binary mixture of patchy colloids in sedimentation-diffusion-equilibrium using Monte Carlo simulation and Wertheim's theory. By tuning the buoyant masses of the colloids we can control the gravity-induced sequence…

Soft Condensed Matter · Physics 2016-03-03 Daniel de las Heras , Lucas L. Treffenstädt , Matthias Schmidt

Within the Poisson-Boltzmann (PB) approach electrolytes in contact with planar, spherical, and cylindrical electrodes are analyzed systematically. The dependences of their capacitance $C$ on the surface charge density $\sigma$ and the ionic…

Soft Condensed Matter · Physics 2017-04-24 Andreas Reindl , Markus Bier , S. Dietrich

The dynamics of two two-level dipole-dipole interacting atoms coupled to a common electromagnetic bath and closely located inside a lossy cavity, is reported. Initially injecting only one excitation in the two atoms-cavity system, loss…

Quantum Physics · Physics 2009-11-10 S. Nicolosi , A. Napoli , A. Messina , F. Petruccione

A phenomenological description for active bundles of polar filaments is presented. The activity of the bundle results from crosslinks, that induce relative displacements between the aligned filaments. Our generic description is based on…

Statistical Mechanics · Physics 2009-11-07 Karsten Kruse , Frank Julicher

We model the behaviour of a single colloid embedded in a cross-linked polymer gel, immersed in a viscous background fluid. External fields actuate the particle into a periodic motion, which deforms the embedding matrix and creates a local…

Soft Condensed Matter · Physics 2022-11-09 Guido L. A. Kusters , Cornelis Storm , Paul van der Schoot

Studies of the thermodynamics of complex coacervation of pairs of symmetric, strongly ionizable, oppositely charged polyelectrolyte chains are abundant. To generalize such understanding to asymmetric chain lengths and variable ionizability…

Soft Condensed Matter · Physics 2023-06-07 Souradeep Ghosh , Soumik Mitra , Arindam Kundagrami

Using the complex Langevin sampling strategy, field theoretic simulations are performed to study the equilibrium phase behavior and structure of symmetric polycation-polyanion mixtures without salt in good solvents. Static structure factors…

Soft Condensed Matter · Physics 2008-06-14 Jonghoon Lee , Yuri O. Popov , Glenn H. Fredrickson

We investigate a multilayer stack of dipolar Bose-Einstein condensates in terms of a simple Gaussian variational ansatz and demonstrate that this arrangement is characterized by the existence several stationary states. Using a Hamiltonian…

Quantum Gases · Physics 2010-08-06 Andrej Junginger , Jörg Main , Günter Wunner

A new quantitative theory for polyelectrolytes in salt free dilute solutions is developed. Depending on the electrostatic interaction strength, polyelectrolytes in solutions can undergo strong stretching (with polyelectrolyte dimension…

Soft Condensed Matter · Physics 2009-10-31 N. V. Brilliantov , D. V. Kuznetsov , R. Klein

Synchrotron-X-ray and surface tension studies of a strong polyelectrolyte (PE) in the semi-dilute regime (~ 0.1M monomer-charges) with varying surfactant concentrations show that minute surfactant concentrations induce the formation of a…

Soft Condensed Matter · Physics 2009-11-10 D. Vaknin , S. Dahlke , A. Travesset , G. Nizri , S. Magdassi

We present a systematic statistical mechanical analysis of the conformational properties of a stiff polyelectrolyte chain with intrachain attractions that are due to counterion correlations. We show that the mean-field solution corresponds…

Soft Condensed Matter · Physics 2007-05-23 Per Lyngs Hansen , Rudi Podgornik , Daniel Svenšek , V. Adrian Parsegian

A model for direct two band excitons in a disordered quantum well coupled to light in a cavity is investigated. In the limit in which the exciton density is high, we assess the impact of weak `pair-breaking' disorder on the feasibility of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 F. M. Marchetti , B. D. Simons , P. B. Littlewood

In non-dilute colloidal suspensions, gradients in particle volume fraction result in gradients in electrical conductivity and permittivity. An externally applied electric field couples with gradients in electrical conductivity and…

Fluid Dynamics · Physics 2015-05-13 Carlos L. Perez , Jonathan D. Posner

We study the attractive interactions between rod-like charged polymers in solution that appear in the presence of multi-valence counterions. The counterions condensed to the rods exhibit both a strong transversal polarization and a…

Soft Condensed Matter · Physics 2009-10-31 Francisco J. Solis , Monica Olvera de la Cruz

Artifacts arise in the simulations of electrolytes using periodic boundary conditions (PBC). We show the origin of these artifacts are the periodic image charges and the constraint of charge neutrality inside the simulation box, both of…

Soft Condensed Matter · Physics 2015-09-30 Yihao Liang , Zhenli Xu , Xiangjun Xing
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