Related papers: Chemistry in Protoplanetary Disks: A Sensitivity A…
The feasibility of contemporary gas-grain astrochemical models depends on the availability of accurate kinetics data, in particular, for surface processes. We study the sensitivity of gas-grain chemical models to the energy barrier Ea of…
(abridged) We analyse the evolution of the fractional ionisation in a steady-state protoplanetary disc with a vertical temperature gradient and with gas-grain chemistry including surface reactions. The ionisation due to stellar X-rays,…
Theoretical models and observations suggest that the abundances of molecular ions in protoplanetary disks should be highly sensitive to the variable ionization conditions set by the young central star. We present a search for temporal flux…
Massive star formation exhibits an extremely rich chemistry. However, not much evolutionary details are known yet, especially at high spatial resolution. Therefore, we synthesize previously published Submillimeter Array…
(abridged) We used the IRAM 30-m to perform a sensitive wideband survey of 30 protoplanetary disks in the Taurus Auriga region. We simultaneously observed HCO$^+$(3-2), HCN(3-2), C$_2$H(3-2), CS(5-4), and two transitions of SO. We combine…
We investigate the impact of photochemistry and X-ray ionization on the molecular composition of, and ionization fraction in, a protoplanetary disk surrounding a typical T Tauri star. We use a sophisticated physical model, which includes a…
We investigate the chemistry of ion molecules in protoplanetary disks, motivated by the detection of N$_2$H$^+$ ring around TW Hya. While the ring inner radius coincides with the CO snow line, it is not apparent why N$_2$H$^+$ is abundant…
We present for the first time a detailed study of the properties of molecular gas in metal-rich environments such as early-type galaxies (ETGs). We have explored Photon-Dominated Region (PDR) chemistry for a wide range of physical…
Recent observations show that the CO gas abundance, relative to H$_2$, in many 1-10 Myr old protoplanetary disks may be heavily depleted, by a factor of 10-100 compared to the canonical interstellar medium value of 10$^{-4}$. When and how…
The abundance and distribution of sulfur-bearing molecules in protoplanetary disks directly influences the composition and potential habitability of nascent planets in addition to providing powerful probes of the physical gas conditions in…
We calculate the ionisation fraction in protostellar disk models using a number of different chemical reaction networks, including gas-phase and gas-grain reaction schemes. The disk models we consider are conventional alpha-disks, which…
In an effort to further our interest in understanding basic chemistry of interstellar molecules, we carry out here an extensive investigation of the stabilities of interstellar carbon chains; Cn, H2Cn, HCnN and CnX (X=N, O, Si, S, H, P, H-,…
Planets form in disks of gas and dust around young stars. The disk molecular reservoirs and their chemical evolution affect all aspects of planet formation, from the coagulation of dust grains into pebbles, to the elemental and molecular…
Column density ratios of complex organic molecules are generally constant across protostellar systems with some low-level scatter. However, the scatter in formamide (NH$_2$CHO) to methanol (CH$_3$OH) column density ratio is one of the…
The chemical conditions in the planet forming regions of protoplanetary discs remain difficult to observe directly. Gas accreting from the disc on to the star provides a way to measure the elemental abundances because even refractory…
The chemistry of proto-planetary disks is thought to be dominated by two major processes: photodissociation near the disk surface, and depletion on dust grains in the disk mid-plane, resulting in a layered structure with molecules located…
Aims: We aim to simulate radial profiles of molecular abundances and the gas temperature in cold and heavily shielded starless cores by combining chemical and radiative transfer models. Methods: A determination of the dust temperature in a…
We upgraded the chemical network from the UMIST Database for Astrochemistry 2006 to include isotopes such as ^{13}C and ^{18}O. This includes all corresponding isotopologues, their chemical reactions and the properly scaled reaction rate…
Core-collapse supernovae, occurring at the end of massive star evolution, produce heavy elements, including those in the iron peak. Although the explosion mechanism is not yet fully understood, theoretical models can reproduce optical…
We aim to investigate the chemistry and gas phase abundance of HNCO and the variation of the HNCO/CS abundance ratio as a diagnostic of the physics and chemistry in regions of massive star formation. A numerical-chemical model has been…