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The structural, electronic and optical properties of Si nanocrystals of different size and shape, passivated with hydrogens, OH groups, or embedded in a SiO2 matrix are studied. The comparison between the embedded and free, suspended…

Materials Science · Physics 2010-09-01 Roberto Guerra , Elena Degoli , Stefano Ossicini

We introduce a general method which allows reconstruction of electronic band structure of nanocrystals from ordinary real-space electronic structure calculations. A comprehensive study of band structure of a realistic nanocrystal is given…

Mesoscale and Nanoscale Physics · Physics 2013-05-15 Prokop Hapala , Kateřina Kůsová , Ivan Pelant , Pavel Jelinek

With the reported synthesis of a fully planar 2D silicon carbide (SiC) allotrope, the possibilities of its technological applications are enormous. Recently, several authors have computationally studied the structures and electronic…

Materials Science · Physics 2023-11-22 Rupali Jindal , Vaishali Roondhe , Alok Shukla

Size-selected anionic silicon clusters, Sin- (n=14-20), have been investigated by photoelectron spectroscopy and density functional theory (DFT) calculations. Low-energy structures of the clusters are globally searched for by using a…

Atomic and Molecular Clusters · Physics 2018-08-29 Xue Wu , Xiaoqing Liang , Qiuying Du , Jijun Zhao , Maodu Chen , Miao Lin , Jiashuai Wang , Guangjia Yin , Lei Ma , R. Bruce King , Bernd von. Issendorff

The atomic and electronic structures of Pd3N, PdN and PdN2 were investigated using ab initio density-functional theory (DFT). We studied cohesive energy vs. volume equation of states (EOS) for a set of reported and hypothetical structures.…

Materials Science · Physics 2013-10-11 Mohammed S. H. Suleiman , Daniel P. Joubert

Based on first-principles calculations we showed that superlattices of periodically repeated junctions of hydrogen saturated silicon nanowire segments having different lengths and diameters form multiple quantum well structures. The band…

Mesoscale and Nanoscale Physics · Physics 2010-12-22 Seymur Cahangirov , Salim Ciraci

We have investigated the stability and conductivity of unsupported, two dimensional infinite gold nanowires using ab-initio density functional theory (DFT). Two dimensional ribbon like nanowires, with 1-5 rows of gold atoms in the…

Mesoscale and Nanoscale Physics · Physics 2016-10-05 Vikas Kashid , Vaishali Shah , H. G. Salunke

In this paper we review the theory of silicon nanowires. We focus on nanowires with diameters below 10 nm, where quantum effects become important and the properties diverge significantly from those of bulk silicon. These wires can be…

Mesoscale and Nanoscale Physics · Physics 2019-10-22 Riccardo Rurali

In the purpose of expanding the family of two-dimensional materials, we predict the existence of two-dimensional octa-structure of nitrogen group elements that are composed of squares and octagons in first-principle method based on density…

Materials Science · Physics 2015-12-08 Yu Zhang , Jason Lee , Wei-Liang Wang , Dao-Xin Yao

Density functional theory (DFT) and thermal DFT (thDFT) calculations were used to evaluate the energy band structure, bandgap, and the total energy of various graphene quantum dots (GQDs). The DFT calculations were performed using local…

Materials Science · Physics 2021-12-20 Majid Ghandchi , Ghafar Darvish , Mohammad Kazem Moravvej-Farshi

The two-dimensional (2D) IV-V semiconductors have attracted much attention due to their fascinating electronic and optical properties. In this work, we predicted three phases of silicon nitrides, denoted $\alpha$-Si$_{2}$N$_{2}$,…

Materials Science · Physics 2024-04-02 Jiesen Li , Wanxing Lin , Junjun Shi , Feng Zhu , Haiwen Xie , Dao-Xin Yao

Several models of oxygenated and hydrogenated surfaces of Si quantum wells and Si nanocrystals of variable shapes have been constructed in order to assess curvature effects on energy gaps due to the three Si-suboxides. Si-suboxides in…

Materials Science · Physics 2015-05-13 Pierre Carrier

Designing molecular organic semiconductors with distinct frontier orbitals is key for the development of devices with desirable properties. Generating defined organic nanostructures with atomic precision can be accomplished by on-surface…

We introduce a polariton-waveguide structure, comprised of a nanowire-based photonic crystal waveguide with a quantum dot embedded in each unit cell. Using realistic designs and parameters, we derive and calculate the fundamental…

Mesoscale and Nanoscale Physics · Physics 2015-09-08 Gerasimos Angelatos , Stephen Hughes

We compare, through first-principles pseudopotential calculations, the structural, electronic and optical properties of different size silicon nanoclusters embedded in a SiO2 crystalline or amorphous matrix, with that of free-standing,…

Density functional theory (DFT) is used to study vibrations, electrical dipole moments, and polarizabilities of NaF clusters. Because of prior experimental and theoretical studies, this is a good model system for tracking the evolution of…

Other Condensed Matter · Physics 2007-05-23 Christian Schmidt , Philip B. Allen , Tunna Baruah , Mark Pederson

Recent advances in hydrogen lithography on silicon surfaces now enable the fabrication of complex and error-free atom-scale circuitry. The structure of atomic wires, the most basic and common circuit elements, plays a crucial role at this…

Materials Science · Physics 2025-10-17 Max Yuan , Lucian Livadaru , Roshan Achal , Jason Pitters , Furkan Altincicek , Robert Wolkow

The electronic structure of crystalline CdTe, CdO, $\alpha$-TeO$_2$, CdTeO$_3$ and Cd$_3$TeO$_6$ is studied by means of first principles calculations. The band structure, total and partial density of states, and charge densities are…

Materials Science · Physics 2009-11-10 Eduardo Ariel Menendez Proupin , Gonzalo Gutierrez , Ernesto Palmero , J. L. Peña

Electronic band structure and energetic stability of two types of and oriented silicon nanowires in beta-Sn phase with the surface terminated by hydrogen atoms were studied using density functional theory. It was found that beta-Sn…

Materials Science · Physics 2015-05-13 Pavel B. Sorokin , Pavel V. Avramov , Viktor A. Demin , Leonid A. Chernozatonskii

Spin-polarized DFT has been used to perform a comprehensive study of the geometric structures and electronic properties for isolated M4X4 nano-clusters between their two stable isomers - a planar rhombus-like 2D structure and a cubane-like…

Mesoscale and Nanoscale Physics · Physics 2015-12-29 Soumendu Datta , Badiur Rahaman