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We review pitfalls in recent efforts to make a conventional semiconductor, namely ZnO, ferromagnetic by means of doping with transition metal ions. Since the solubility of those elements is rather low, formation of secondary phases and the…

Materials Science · Physics 2009-08-06 Kay Potzger , Shengqiang Zhou

We show that doped cubic iron pyrite, which is a diamagnetic semiconductor, becomes ferromagnetic when $p$-type doped. We furthermore find that this material can exhibit high spin polarization both for tunneling and transport devices. These…

Materials Science · Physics 2021-04-23 Bing-Hua Lei , David J. Singh

Recently theoretical works predict that some semiconductors (e.g. ZnO) doped with magnetic ions are diluted magnetic semiconductors (DMS). In DMS magnetic ions substitute cation sites of the host semiconductor and are coupled by free…

Materials Science · Physics 2009-07-22 Shengqiang Zhou , K. Potzger , Qingyu Xu , G. Talut , M. Lorenz , W. Skorupa , M. Helm , J. Fassbender , M. Grundmann , H. Schmidt

Diluted magnetic semiconductors (DMSs), in which magnetic elements are substituted for a small fraction of host elements in a semiconductor lattice, can become ferromagnetic when doped. In this article we discuss the physics of DMS…

Materials Science · Physics 2009-11-07 Byounghak Lee , T. Jungwirth , A. H. MacDonald

Following the theoretical predictions of ferromagnetism in Mn- and Co-doped ZnO, several workers reported ferromagnetism in thin films as well as in bulk samples of these materials. While some observe room-temperature ferromagnetism, others…

Materials Science · Physics 2007-05-23 C. N. R. Rao , F. L. Deepak

The possibility of half-metallic antiferromagnetism, a special case of ferrimagnetism with a compensated magnetization, in the diluted magnetic semiconductors is highlighted on the basis of the first principles electronic structure…

Materials Science · Physics 2009-11-11 H. Akai , M. Ogura

We report magnetism in carbon doped ZnO. Our first-principles calculations based on density functional theory predicted that carbon substitution for oxygen in ZnO results in a magnetic moment of 1.78 $\mu_B$ per carbon. The theoretical…

Materials Science · Physics 2013-05-29 H. Pan , J. B. Yi , J. Y. Lin , Y. P. Feng , J. Ding , L. H. Van , J. H. Yin

Diluted Magnetic Semiconductors (DMS) doped with a small concentration of magnetic impurities inducing ferromagnetic DMSs have attracted a lot of attention in the few last years. In particular, DMS based on III-V and II-VI semiconductors…

Materials Science · Physics 2011-05-31 L. B. Drissi

The realization of semiconductors that are ferromagnetic above room temperature will potentially lead to a new generation of spintronic devices with revolutionary electrical and optical properties. Transition temperatures in doped ZnO are…

Strongly Correlated Electrons · Physics 2009-11-11 XH Xu , AJ Behan , M Ziese , HJ Blythe , JR Neal , A Mokhtari , MR Ibrahim , AM Fox , GA Gehring

In the past decade, room temperature ferromagnetism was often observed in transition metal doped semiconductors, which were claimed as diluted magnetic semiconductors (DMS). Nowadays intensive activities are devoted to clarify wether the…

Materials Science · Physics 2013-01-03 Shengqiang Zhou , K. Potzger , G. Talut , J. von Borany , W. Skorupa , M. Helm , J. Fassbender

Films of ZnO doped with magnetic ions, Mn and Co and, in some cases, with Al have been fabricated with a very wide range of carrier densities. Ferromagnetic behaviour is observed in both insulating and metallic films, but not when the…

Materials Science · Physics 2009-11-13 A. J. Behan , A. Mokhtari , H. J. Blythe , D. Score , X-H. Xu , J. R. Neal , A. M. Fox , G. A. Gehring

The electronic and magnetic properties of transition-metal doped $\beta$-Ge3N4 have been studied using first-principles calculations. The results show that the substitutional transition-metal impurities tend to cluster. The V and Cr doped…

Materials Science · Physics 2015-05-18 Sheng-Li Zhang , Wei Wang , Er-Hu Zhang

Magneto-optical properties of ZnO:Co and ZnO:Ni films were measured. Magnetization measurements show that some of the films are paramagnetic and others are ferromagnetic. Magnetic circular dichroism clarified that Zn1-xCoxO and Zn1-xNixO…

Materials Science · Physics 2007-05-23 K. Ando

In this letter, the authors present a study of the energetics and magnetic interactions in Fe doped ZnO clusters by ab-initio density functional calculations. The results indicate that defects under suitable conditions can induce…

Materials Science · Physics 2009-05-15 Nirmal Ganguli , Indra Dasgupta , Biplab Sanyal

The magnetic and electrical properties of nitrogen doped diamond system have been studied within the framework of a density functional theoretical approach. Spin-polarised calculations reveal that only the nitrogen doped system with…

Materials Science · Physics 2025-05-08 Homnath Luitel

Magnetic oxide semiconductors, oxide semiconductors doped with transition metal elements, are one of the candidates for a high Curie temperature ferromagnetic semiconductor that is important to realize semiconductor spintronics at room…

Materials Science · Physics 2009-11-11 T. Fukumura , H. Toyosaki , Y. Yamada

We present the results of a computational study of ZnO in the presence of Co and Mn substitutional impurities. The goal of our work is to identify potential ferromagnetic ground states within the (Zn,Co)O or (Zn,Mn)O material systems that…

Materials Science · Physics 2021-03-09 Nicola A. Spaldin

We report here on the magnetic properties of ZnO:Mn and ZnO:Co doped nanoparticles. We have found that the ferromagnetism of ZnO:Mn can be switched on and off by consecutive low-temperature annealings in O2 and N2 respectively, while the…

Materials Science · Physics 2007-05-23 D. Rubi , J. Fontcuberta , A. Calleja , Ll. Aragones , X. G. Capdevila , M. Segarra

In contrast to semiconductors doped with transition metal magnetic elements, which become ferromagnetic at temperatures below ~ 100K, semiconductors doped with non-magnetic ions (e.g. silicon doped with phosphorous) have not shown evidence…

Strongly Correlated Electrons · Physics 2015-05-13 Erik Nielsen , R. N. Bhatt

We report spin polarized density functional calculations of ferromagnetic properties of a series of ZnO clusters and solid containing one or two substitutional carbon impurities. We analyze the eigen value spectra, spin densities and…

Materials Science · Physics 2016-09-28 B. J. Nagare , Sajeev Chacko , D. G. Kanhere
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