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The limit of small entropy production is reached in relaxing systems long after preparation, and in stationary driven systems in the limit of small driving power. Surprisingly, for extended systems this limit is not in general the…

Condensed Matter · Physics 2009-10-31 Leticia F. Cugliandolo , Jorge Kurchan

In the nonextensive Tsallis scenario, Page's conjecture for the average entropy of a subsystem[Phys. Rev. Lett. {\bf 71}, 1291(1993)] as well as its demonstration are generalized, i.e., when a pure quantum system, whose Hilbert space…

Statistical Mechanics · Physics 2009-11-07 L. C. Malacarne , R. S. Mendes , E. K. Lenzi

The second Tisza-Callen postulate of equilibrium thermodynamics states that for any system exists a function of the system's extensive parameters, called entropy, defined for all equilibrium states and having the property that the values…

Statistical Mechanics · Physics 2016-03-23 Dragos-Victor Anghel

The Boltzmann distribution predicts the collective behavior of systems at thermodynamic equilibrium as a function of their constituent parts. Yet most systems in nature are not at equilibrium, and a unified theory of their behavior does not…

Statistical Mechanics · Physics 2018-10-16 Milo M. Lin

Entropy is the distinguishing and most important concept of our efforts to understand and regularize our observations of a very large class of natural phenomena, and yet, it is one of the most contentious concepts of physics. In this…

Quantum Physics · Physics 2007-05-23 Elias P. Gyftopoulos

Asymptotically entropy of chaotic systems increases linearly and the sensitivity to initial conditions is exponential with time: these two behaviors are related. Such relationship is the analogous of and under specific conditions has been…

Statistical Mechanics · Physics 2011-01-04 Roberto Tonelli , Giuseppe Mezzorani , Franco Meloni , Marcello Lissia , Massimo Coraddu

We show that the generalized Boltzmann distribution is the only distribution for which the Gibbs-Shannon entropy equals the thermodynamic entropy. This result means that the thermodynamic entropy and the Gibbs-Shannon entropy are not…

Statistical Mechanics · Physics 2019-07-24 Xiang Gao , Emilio Gallicchio , Adrian E. Roitberg

To know the statistical distribution of a variable is an important problem in management of resources. Distributions of the power law type are observed in many real systems. However power law distributions have an infinite variance and thus…

Statistical Mechanics · Physics 2008-12-02 Hari M. Gupta , Jose R. Campanha

Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…

Statistical Mechanics · Physics 2024-09-20 Ananth Govind Rajan

We show that starting with either the non-extensive Tsallis entropy in Wang's formalism or the extensive Renyi entropy, it is possible to construct the equilibrium statistical mechanics with non-Gibbs canonical distribution functions. The…

High Energy Physics - Phenomenology · Physics 2009-11-10 A. S. Parvan , T. S. Biro

It has been argued in [EPL {\bf 90} (2010) 50004], entitled {\it Essential discreteness in generalized thermostatistics with non-logarithmic entropy}, that "continuous Hamiltonian systems with long-range interactions and the so-called…

Statistical Mechanics · Physics 2017-08-23 A. Plastino , M. C. Rocca

Nonadditive Tsallis $q$-statistics has successfully been applied for a plethora of systems in natural sciences and other branches of knowledge. Nevertheless, its foundations have been severely criticised by some authors based on the…

Statistical Mechanics · Physics 2020-05-20 J. A. S. Lima , A. Deppman

We examine the inference of quantum density operators from incomplete information by means of the maximization of general non-additive entropic forms. Extended thermodynamic relations are given. When applied to a bipartite spin 1/2 system,…

Quantum Physics · Physics 2015-05-20 N. Canosa , R. Rossignoli

Boltzmann-Gibbs statistical mechanics is based on the entropy $S_{BG}=-k \sum_{i=1}^W p_i \ln p_i$. It enables a successful thermal approach of ubiquitous systems, such as those involving short-range interactions, markovian processes, and,…

Statistical Mechanics · Physics 2009-11-10 Constantino Tsallis , Edgardo Brigatti

A consistent generalization of statistical mechanics is obtained by applying the maximum entropy principle to a trace-form entropy and by requiring that physically motivated mathematical properties are preserved. The emerging…

Statistical Mechanics · Physics 2009-11-10 G. Kaniadakis , M. Lissia , A. M. Scarfone

We propose a method to derive the stationary size distributions of a system, and the degree distributions of networks, using maximisation of the Gibbs-Shannon entropy. We apply this to a preferential attachment-type algorithm for systems of…

Physics and Society · Physics 2020-03-17 Cornelia Metzig , Caroline Colijn

Asymptotic behavior (with respect to the number of trials) of symmetric generalizations of binomial distributions and their related entropies are studied through three examples. The first one derives from the q-exponential as a generating…

Statistical Mechanics · Physics 2014-12-02 H. Bergeron , E. M. F. Curado , J. P. Gazeau , Ligia M. C. S. Rodrigues

Entropy can signify different things: For instance, heat transfer in thermodynamics or a measure of information in data analysis. Many entropies have been introduced and it can be difficult to ascertain their different importance and…

Mathematical Physics · Physics 2025-07-10 Henrik Jeldtoft Jensen , Piergiulio Tempesta

A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…

Statistical Mechanics · Physics 2007-05-23 A. Perez-Madrid

We consider the problem of defining free energy and other thermodynamic functions when the entropy is given as a general function of the probablity distribution, including that for non extensive forms. We find that the free energy, which is…

Statistical Mechanics · Physics 2007-11-07 Fariel Shafee