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A detailed investigation using variable temperature powder neutron diffraction demonstrates that BiFeO3 undergoes a phase transition from the ferroelectric alpha phase (rhombohedral, R3c) to a paraelectric beta phase (orthorhombic, Pbnm)…

Materials Science · Physics 2009-08-21 Donna C. Arnold , Kevin S. Knight , Finlay D. Morrison , Philip Lightfoot

Recent results have demonstrated an exceptionally high dielectric constant in the range 200 K-330 K in a crystalline tianium oxide : Rb2Ti2O5. In this article, the possibility of a structural transition giving rise to ferroelectricity is…

A single crystal of lead-zirconate-titanate (PZT), composition Pb(Zr0.80Ti0.20)O3, was studied by polarized-Raman scattering as a function of temperature. Raman spectra reveal that the local structure deviates from the average structure in…

Materials Science · Physics 2015-06-23 J. Frantti , Y. Fujioka , A. Puretzky , Y. Xie , Z. -G. Ye , C. Parish , A. M. Glazer

We report results of ultrasonic studies of a single crystal of KDP in the temperature range 2-300 K. The longitudinal and transverse sound velocities along [001] and [100] directions were obtained as functions of temperature. The analysis…

Materials Science · Physics 2015-06-17 A. E. Petrova , S. M. Stishov

We study the phase transition behavior of the ferroelectric BaTi$_{0.8}$Zr$_{0.2}$O$_3$ in the paraelectric region. The temperature dependencies of thermal, polar, elastic and dielectric properties indicate the presence of local structures…

We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…

The normal ferroelectric to paraelectric phase transition in model ferroelectric materials such as BaTiO3 is typically characterized by a sharp, well-defined dielectric constant peak at a specific transition temperature. However, under…

Materials Science · Physics 2025-10-17 Prithwiraj Ganguly , Prashant Joshi , Maneesha Puthiyoth , Dilip Sasmal , Somaditya Sen

Dielectric spectroscopy of $SrTiO_3$ single crystal over a broad range of microwave frequency using quasi $TE_{m,1,1}$ and quasi $TM_{m,1,1}$ modes reveals crystal asymmetry from typical measurement of $Q$-factor, transmission or frequency…

Materials Science · Physics 2025-05-22 M. A. Hosain , J-M. Le Floch , J. F. Bourhill , J. Krupka , M. E. Tobar

A theoretical analysis of the internal structure of interphase boundaries separating domains of coexisting phases are presented for the perovskite ferroelectric BaTiO3. The temperature dependence of interphase boundary widths and surface…

Materials Science · Physics 2020-05-15 T. A. Liebsch , V. L. Sobolev

The current controversies about the existence of an intermediate 'beta' phase of BiFeO_3 and the high temperature paraelectric 'gamma' phase are resolved by studying the sequence of ferroic transitions in 0.8BiFeO_3-0.2Pb(Fe_1/2Nb_1/2)O_3…

Materials Science · Physics 2009-06-08 Jay Prakash Patel , Anar Singh , Dhananjai Pandey

Phase transitions in CsPbCl$_3$ crystals have been explored by photoacoustic (PA) method in a wide temperature range of 150--300 K. The PA signals, induced by ns-pulsed laser excitation of electronic states and detected with a piezoelectric…

Materials Science · Physics 2007-05-23 Masanobu Iwanaga

NiBi3 polycrystals were synthesized via a solid state method. X-ray diffraction analysis shows that the main phase present in the sample corresponds to NiBi3 in a weight fraction of 96.82 % according to the refinement of the crystalline…

The mechanical behavior of two-dimensional (2D) materials across 2D phase changes is unknown, and the finite temperature ($T$) elasticity of paradigmatic SnSe monolayers -- ferroelectric 2D materials turning paraelectric as their unit cell…

Materials Science · Physics 2022-06-15 Joseph E. Roll , John M. Davis , John W. Villanova , Salvador Barraza-Lopez

CuInP2S6 (CIPS) is an emerging layered material that exhibits ferrielectric ordering well above room temperature (Curie temperature TC ~ 315 K). When synthesized with Cu deficiencies, CIPS spontaneously segregates into CuInP2S6 and…

Materials Science · Physics 2021-11-02 Rahul Rao , Ryan Selhorst , Benjamin S. Conner , Michael A. Susner

The authors of paper commented claim that trimethylammonium tetrachlorozincate crystal shows at 282 K the ferroelectric-paraelectric phase transition. But no ferroelectric hysteresis loop was observed below this temperature. Moreover, in…

Materials Science · Physics 2016-04-07 Zbigniew Tylczynski

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

We present here the results of frequency dependent dielectric, polarization and powder X-ray powder diffraction studies in the 300 to 100K temperature range for Ba_0.55Sr_0.45TiO_3. The dielectric results indicate a succession of three…

Materials Science · Physics 2007-09-24 Satyendra Singh , Satendra Pal Singh , Dhananjai Pandey

Polycrystalline sample of (Ba_{0.90}Pb_{0.10})(Ti_{0.90}Sn_{0.10})O_3 was obtained by means of a conventional ceramic technology. The dielectric measurements were performed depending on temperature and frequency of electric measuring field.…

Materials Science · Physics 2013-09-25 C. Kajtoch , W. Bąk , B. Garbarz-Glos

The partially overlapped ferroelastic/martensitic and para-ferromagnetic phase transitions of a Ni$_{50.53}$Mn${33.65}$In$_{15.82}$ metamagnetic shape memory alloy have been studied from calorimetric, magnetic and acoustic emission…

We present the analytical study of stability loss and evolution of domain structure in inhomogeneous ferroelectric and ferroelastic samples for exactly solvable models. The model assumes a short-circuited ferroelectric capacitor (free…

Statistical Mechanics · Physics 2009-11-07 A. M. Bratkovsky , A. P. Levanyuk
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