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The method recently developed to include Van der Waals interactions in the Density Functional Theory by using the Maximally-Localized Wannier functions, is improved and extended to the case of atoms and fragments weakly bonded (physisorbed)…

Other Condensed Matter · Physics 2009-11-13 Pier Luigi Silvestrelli , Karima Benyahia , Sonja Grubisic Francesco Ancilotto , Flavio Toigo

We present a new scheme to include the van der Waals (vdW) interactions in approximated Density Functional Theory (DFT) by combining the Quantum Harmonic Oscillator model with the Maximally Localized Wannier Function technique. With respect…

Materials Science · Physics 2015-06-16 Pier Luigi Silvestrelli

A new implementation is proposed for including van der Waals (vdW) interactions in Density Functional Theory (DFT) using the Maximally-Localized Wannier functions (MLWFs), which is free from empirical parameters. With respect to the…

Chemical Physics · Physics 2019-05-22 Pier Luigi Silvestrelli , Alberto Ambrosetti

A new implementation is proposed for including van der Waals interactions in Density Functional Theory using the Maximally-Localized Wannier functions. With respect to the previous DFT/vdW-WF method, the present DFT/vdW-WF2 approach, which…

Strongly Correlated Electrons · Physics 2015-06-03 A. Ambrosetti , P. L. Silvestrelli

Ubiquitous van der Waals (vdW) interactions play a subtle yet crucial role in determining the precise atomic arrangements in solids, particularly in molecular crystals where these weak forces are the primary link between constituent…

A density functional theory (DFT) that accounts for van der Waals (vdW) interactions in condensed matter, materials physics, chemistry, and biology is reviewed. The insights that led to the construction of the Rutgers-Chalmers van der Waals…

The DFT/vdW-QHO-WF method, recently developed to include the van der Waals (vdW) interactions in approximated Density Functional Theory (DFT) by combining the Quantum Harmonic Oscillator model with the Maximally Localized Wannier Function…

Materials Science · Physics 2015-06-18 Pier Luigi Silvestrelli

Although density functional theory (DFT) in principle includes even long-range interactions, standard implementations employ local or semi-local approximations of the interaction energy and fail at describing the van der Waals interactions.…

Soft Condensed Matter · Physics 2007-05-23 S. D. Chakarova , E. Schroder

The DFT/vdW-WF2s1 method based on the generation of localized Wannier functions, recently developed to include the van der Waals interactions in the Density Functional Theory and describe adsorption processes on metal surfaces by taking…

Chemical Physics · Physics 2016-04-06 Pier Luigi Silvestrelli , Alberto Ambrosetti

Proper inclusion of van der Waals (vdW) interactions in theoretical simulations based on standard density functional theory (DFT) is crucial to describe the physics and chemistry of systems such as organic and layered materials. Many…

Materials Science · Physics 2023-07-19 Jinwoo Park , Byung Deok Yu , Suklyun Hong

A new scheme for the computation of dispersive interactions from first principles is presented. This cost-effective approach relies on a Wannier function representation compatible with density function theory descriptions. This is an…

Materials Science · Physics 2025-02-04 Diem Thi-Xuan Dang , Dai-Nam Le , Lilia M. Woods

We investigate a recently developed approach [P. L. Silvestrelli, Phys. Rev. Lett. 100, 053002 (2008); J. Phys. Chem. A 113, 5224 (2009)] that uses maximally localized Wannier functions to evaluate the van der Waals contribution to the…

Materials Science · Physics 2012-06-12 Lampros Andrinopoulos , Nicholas D. M. Hine , Arash A. Mostofi

To understand sparse systems we must account for both strong local atom bonds and weak nonlocal van der Waals forces between atoms separated by empty space. A fully nonlocal functional form [H. Rydberg, B.I. Lundqvist, D.C. Langreth, and M.…

Materials Science · Physics 2009-11-10 H. Rydberg , M. Dion , N. Jacobson , E. Schroder , P. Hyldgaard , S. I. Simak , D. C. Langreth , B. I. Lundqvist

Noncovalent van der Waals (vdW) interactions are responsible for a wide range of phenomena in matter. Popular density-functional methods that treat vdW interactions use disparate physical models for these intricate forces, and as a result…

Materials Science · Physics 2020-04-15 Jan Hermann , Alexandre Tkatchenko

We present an approach for computing long-range van der Waals (vdW) interactions between complex molecular systems and arbitrarily shaped macroscopic bodies, melding atomistic treatments of electronic fluctuations based on density…

Mesoscale and Nanoscale Physics · Physics 2017-07-05 Prashanth S. Venkataram , Jan Hermann , Alexandre Tkatchenko , Alejandro W. Rodriguez

Density Functional Theory (DFT) is one of the most widely used methods for "ab initio" calculations of the structure of atoms, molecules, crystals, surfaces, and their interactions. Unfortunately, the customary introduction to DFT is often…

Physics Education · Physics 2010-12-07 Nathan Argaman , Guy Makov

The van der Waals density functional (vdW-DF) of Dion et al. [Phys. Rev. Lett. 92, 246401 (2004)] is a promising approach for including dispersion in approximate density functional theory exchange-correlation functionals. Indeed, an…

Materials Science · Physics 2013-01-30 Jiří Klimeš , David R. Bowler , Angelos Michaelides

We study the mutual interactions of simple, parallel polymers and nanotubes, and develop a scheme to include the van der Waals interactions in the framework of density functional theory (DFT) for these molecules at intermediate to…

Soft Condensed Matter · Physics 2007-05-23 Jesper Kleis , Per Hyldgaard , Elsebeth Schroder

A versatile method for combining density functional theory (DFT) in the local density approximation (LDA) with dynamical mean-field theory (DMFT) is presented. Starting from a general basis-independent formulation, we use Wannier functions…

Strongly Correlated Electrons · Physics 2009-11-11 F. Lechermann , A. Georges , A. Poteryaev , S. Biermann , M. Posternak , A. Yamasaki , O. K. Andersen

Using fourth-order perturbation theory, a general formula for the van der Waals potential of two neutral, unpolarized, ground-state atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is…

Quantum Physics · Physics 2007-05-23 Hassan Safari , Stefan Yoshi Buhmann , Dirk-Gunnar Welsch , Ho Trung Dung
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