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A method is suggested for estimation of structural properties of amorphous fullerene and its derivatives produced by vacuum annealing. The method is based on the fitting of the neutron or x-ray powder diffraction patterns for scattering…

Materials Science · Physics 2014-12-24 V. S. Neverov , P. A. Borisova , A. B. Kukushkin , V. V. Voloshinov

We have utilized neutron powder diffraction to probe the crystal structure of layered Na$_{x}$CoO$_{2}$ near the half doping composition of $x=$0.46 over the temperature range of 2 to 600K. Our measurements show evidence of a dynamic…

Strongly Correlated Electrons · Physics 2008-06-16 D. N. Argyriou , O. Prokhnenko , K. Kiefer , C. J. Milne

An experimental determination of the magnetic pair distribution function (mPDF) defined in an earlier paper (Frandsen, Yang, and Billinge. (2014) Acta Crystallogr. A, 70(1), 3-11) is presented for the first time. The mPDF was determined…

Materials Science · Physics 2015-05-05 Benjamin A. Frandsen , Simon J. L. Billinge

Equations for the reduced structure function and atomic pair distribution function (PDF) of a textured polycrystalline sample are formulated in terms of the orientational distribution function (ODF) and the structure function from a single…

Materials Science · Physics 2018-05-29 Zizhou Gong , Simon J. L. Billinge

The crystal structures of the NaxCoO2 phases based on three-layer NaCoO2, with x=0.32, x=0.51, x=0.60, x=0.75 and x=0.92, determined by powder neutron diffraction, are reported. The structures have triangular CoO2 layers interleaved by…

Strongly Correlated Electrons · Physics 2009-11-11 L. Viciu , J. W. G. Bos , H. W. Zandbergen , Q. Huang , M. L. Foo , S. Ishiwata , A. P. Ramirez , M. Lee , N. P. Ong , R. J. Cava

Using microemulsion methods, CoO-Pt core-shell nanoparticles (NPs), with diameters of nominally 4 nm, were synthesized and characterized by high-resolution transmission electron microscopy (HRTEM) and a suite of x-ray spectroscopies,…

Mesoscale and Nanoscale Physics · Physics 2014-03-25 Adriana Zelenakova , Vladimir Zelenak , Stefan Michalik , Jozef Kovac , Mark W. Meisel

Deciphering the three-dimensional atomic structure of solid-solid interfaces in core-shell nanomaterials is the key to understand their remarkable catalytical, optical and electronic properties. Here, we probe the three-dimensional atomic…

Materials Science · Physics 2023-06-21 Zezhou Li , Zhiheng Xie , Yao Zhang , Xilong Mu , Hai-jing Yin , Ya-wen Zhang , Colin Ophus , Jihan Zhou

The atomic pair distribution function (PDF) of stoichiometric LaMnO_3 has been measured. This has been fit with a structural model to extract the local Jahn-Teller distortion for an ideal Mn(3+)O_6 octahedron. These results are compared to…

Materials Science · Physics 2009-10-31 Th. Proffen , R. G. DiFrancesco , S. J. L. Billinge , E. L. Brosha , G. H. Kwei

We present local structural evidence supporting the presence of charge inhomogeneities in the CuO2 planes of underdoped La2-xSrxCuO4. High-resolution atomic pair distribution functions have been obtained from neutron powder diffraction data…

Superconductivity · Physics 2016-08-31 E. S. Bozin , G. H. Kwei , H. Takagi , S. J. L. Billinge

To unravel the origin of the dielectric anomaly at the antiferromagnetic ordering of magnetoelectric Bi$_2$Fe$_4$O$_9$ we performed neutron powder diffraction measurements across the N$\acute{\rm e}$el temperature, $T_{\rm N}$. Both local…

Materials Science · Physics 2016-08-03 I. -K. Jeong , N. Hur

NaV2O4 crystals were grown under high pressure using a NaCl flux, and the crystals were characterized with X-ray diffraction, electrical resistivity, heat capacity, and magnetization. The structure of NaV2O4 consists of double chains of…

Strongly Correlated Electrons · Physics 2009-11-13 K. Yamaura , M. Arai , A. Sato , A. B. Karki , D. P. Young , R. Movshovich , S. Okamoto , D. Mandrus , E. Takayama-Muromachi

Iron oxide nano particles with nominal Fe2O3 stoichiometry were synthesized by a wet, soft chemical method with the heat treatment temperatures from 250{\deg}C to 900{\deg}C in air. The variation in the structural properties of the nano…

Materials Science · Physics 2011-11-29 Debajeet K. Bora , Artur Braun , Selma Erat , Olga Safonova , Thomas Graule , Edwin C. Constable

The present study reports on the structure formation in thin epitaxial nickel-aluminum films (Ni1-xAlx; Al atomic fraction x up to x=0.24) grown on MgO(001) substrates by magnetron sputtering. Experimental and computational data demonstrate…

A new approach is presented to obtain candidate structures from atomic pair distribution function (PDF) data in a highly automated way. It fetches, from web-based structural databases, all the structures meeting the experimenter's search…

Materials Science · Physics 2020-05-07 Long Yang , Pavol Juhás , Maxwell W. Terban , Matthew G. Tucker , Simon J. L. Billinge

Aluminum alloys, the most widely utilized lightweight structural materials, predominantly depend on coherent complex-structured nano-plates to enhance their mechanical properties. Despite several decades of research, the atomic-scale…

Materials Science · Physics 2024-10-22 Junyuan Bai , Gaowu Qin , Xueyong Pang , Zhihao Zhao

Neutron and x-ray powder diffraction have been used to investigate the crystal structures of a sample of the newly-discovered superconducting sodium cobaltate deuterate compound with composition Na0.31(3)CoO2o1.25(2)D2O and its anhydrous…

Superconductivity · Physics 2009-11-10 J. D. Jorgensen , M. Avdeev , D. G. Hinks , J. C. Burley , S. Short

Atomic structure of a mono-dispersive hematite ($\alpha$-Fe$_2$O$_3$) nanocube $(0 1\bar1 2)$ surface was determined with synchrotron X-ray diffraction. The $\alpha$-Fe$_2$O$_3$ nanocubes were prepared through a hydrothermal process and a…

Mesoscale and Nanoscale Physics · Physics 2020-06-09 Chang-Yong Kim

The atomic structure and properties of nanoparticulate Fe2O3 are characterized starting from its smallest Fe2O3 building unit through (Fe2O3)n clusters to nanometer-sized Fe2O3 particles. This is achieved by combining global structure…

Materials Science · Physics 2024-05-30 Andreas Erlebach , Heinz-Dieter Kurland , Janet Grabow , Frank A. Müller , Marek Sierka

The structural properties of L-alanine amino acid in aqueous solution and in crystalline phase have been studied by means of density-functional electronic-structure and molecular dynamics simulations. The solvated zwitterionic structure of…

Biological Physics · Physics 2007-05-23 Ivan Degtyarenko , Karl J. Jalkanen , Andrey A. Gurtovenko , Risto M. Nieminen

The complex perovskite Ba2CoTeO6 (BCTO) has been synthesised, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder diffraction, electron microscopy and dielectric,…

Materials Science · Physics 2010-12-01 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter