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The quadratic Jahn-Teller effect of C$_{60}^{n-}$ ($n=$ 1-5) is investigated from the first principles. Employing the density functional theory calculations with hybrid functional, the quadratic vibronic coupling constants of C$_{60}^-$…

Strongly Correlated Electrons · Physics 2018-07-03 Dan Liu , Yasuyuki Niwa , Naoya Iwahara , Tohru Sato , Liviu F. Chibotaru

We propose an effective model on the basis of a $j$-$j$ coupling scheme to describe local $f$-electron states for realistic values of Coulomb interaction $U$ and spin-orbit coupling $\lambda$, for future development of microscopic theory of…

Strongly Correlated Electrons · Physics 2015-06-25 Takashi Hotta , Hisatomo Harima

Variational calculations of ground-state properties of $^4$He, $^{16}$O, and $^{40}$Ca are carried out employing realistic phenomenological two- and three-nucleon potentials. The trial wave function includes two- and three-body correlations…

Nuclear Theory · Physics 2017-09-04 D. Lonardoni , A. Lovato , Steven C. Pieper , R. B. Wiringa

The Jahn-Teller effect is one of the most fundamental phenomena important not only for physics, but also for chemistry and material science. Solving the Jahn-Teller problem and taking into account strong electron correlations we show that…

Strongly Correlated Electrons · Physics 2020-08-26 S. V. Streltsov , D. I. Khomskii

We analyze the stability of excitonic ground states in the two-band Hubbard model with additional electron-phonon and Hund's rule couplings using a combination of mean-field and variational cluster approaches. We show that both the…

Strongly Correlated Electrons · Physics 2015-09-04 Tatsuya Kaneko , Bernd Zenker , Holger Fehske , Yukinori Ohta

Vibronic coupling parameters for C$_{60}^{+}$ were derived via DFT calculations with hybrid B3LYP and CAM-B3LYP functional, based on which the static Jahn-Teller effect were analyzed. The global minima of adiabatic potential energy surface…

Chemical Physics · Physics 2020-07-06 Zhishuo Huang , Dan Liu

The Holstein model has been widely accepted as a model comprising electrons interacting with phonons; analysis of this model's ground states was accomplished two decades ago. However, the results were obtained without completely taking…

Mathematical Physics · Physics 2016-05-10 Tadahiro Miyao

We study the influence of the lattice structure, the Jahn-Teller effect and the Hund's rule coupling on a metal-insulator transition in AnC60 (A= K, Rb). The difference in lattice structure favors A3C60 (fcc) being a metal and A4C60 (bct)…

Strongly Correlated Electrons · Physics 2009-10-31 J. E. Han , E. Koch , O. Gunnarsson

We study the effect of symmetry-breaking perturbations in the multiorbital Hubbard model coupled to anisotropic Jahn-Teller phonons, which is relevant for the description of fulleride superconductors. This system is often approximated by a…

Superconductivity · Physics 2026-01-29 Natsuki Okada , Tatsuya Miki , Yusuke Nomura , Philipp Werner , Shintaro Hoshino

A simple, yet accurate solution of the electron-phonon coupling problem in C_{60} is presented. The basic idea behind it is to be found in the parametrization of the ground state electronic density of the system calculated making use of…

Condensed Matter · Physics 2009-10-31 N. Breda , R. A. Broglia , G. Colo` , H. E. Roman , F. Alasia , G. Onida , V. Ponomarev , E. Vigezzi

Studying the nature and consequences of electron-phonon interaction in manganites is an area of intense ongoing research. Here, in an attempt to model charge and orbital ordering in manganites displaying C-type antiferromaganetism, we study…

Strongly Correlated Electrons · Physics 2015-01-27 Ravindra Pankaj , Sudhakar Yarlagadda

We investigate the effect of the experimentally observed Jahn-Teller distortion of the oxygen octahedra in LaTiO3 on the magnetic exchange. We present a localized model for the effective hopping between nearest-neighbor Ti ions and the…

Strongly Correlated Electrons · Physics 2009-11-10 Robert Schmitz , Ora Entin-Wohlman , Amnon Aharony , A. Brooks Harris , Erwin Mueller-Hartmann

The electronic structure of C_(4N+2) carbon rings exhibits competing many-body effects of Huckel aromaticity, second-order Jahn-Teller and Peierls instability at large sizes. This leads to possible ground state structures with aromatic,…

Atomic and Molecular Clusters · Physics 2009-11-06 Tommaso Torelli , Lubos Mitas

The benzene cation (C6H6+) has a doublet (e_{1g}) ground state in hexagonal ring (D_{6h}) geometry. Therefore a Jahn-Teller (JT) distortion will lower the energy. The present theoretical study yields a model Huckel-type Hamiltonian that…

Condensed Matter · Physics 2009-11-07 Vasili Perebeinos , Philip B. Allen , Mark Pederson

We investigate the two-orbital periodic Anderson model, where the local orbital fluctuations of f-electrons couple with a two-fold degenerate Jahn-Teller phonon, by using the dynamical mean-field theory. It is found that the heavy fermion…

Strongly Correlated Electrons · Physics 2013-03-05 Keisuke Mitsumoto , Yoshiaki Ono

The Jahn-Teller effect explains distortions and non-degenerate energy levels in molecular and solid-state physics via a coupling of effective spins to collective bosons. Here we propose and theoretically analyze the quantum simulation of a…

Quantum Physics · Physics 2012-01-19 Diego Porras , Peter A. Ivanov , Ferdinand Schmidt-Kaler

A realistic modeling of manganites should include the Coulomb repulsion between $e_g$ electrons, the Hund's rule coupling to $t_{2g}$ spins, and Jahn-Teller phonons. Solving such a model by dynamical mean field theory, we report large…

Strongly Correlated Electrons · Physics 2009-11-11 Y. -F. Yang , K. Held

Using a controlled analytic treatment, we derive a model that generically describes cooperative strong electron-phonon interaction (EPI) in one-band and two-band Jahn-Teller (JT) systems. The model involves a {\em next-nearest-neighbor}…

Strongly Correlated Electrons · Physics 2008-03-04 Sudhakar Yarlagadda

We employ the Gutzwiller variational approach to investigate the interplay of Coulomb interaction and spin-orbit coupling in a three-orbital Hubbard model. Already in the paramagnetic phase we find a substantial renormalization of the…

Strongly Correlated Electrons · Physics 2016-07-20 Jörg Bünemann , Thorben Linneweber , Ute Löw , Frithjof B. Anders , Florian Gebhard

The properties of a dilute electron gas, coupled to the lattice degrees of freedom, are studied and compared with the properties of an electron gas at half-filling, where spinless fermions with two orbitals per lattice site are considered.…

Strongly Correlated Electrons · Physics 2007-05-23 D. Schneider , K. -H. Höck , K. Ziegler