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Proton transfer rates and mechanisms are studied in mesoscopic, liquid-state, molecular clusters. The proton transfer occurs in a proton-ion complex solvated by polar molecules comprising the cluster environment. The rates and mechanisms of…

chem-ph · Physics 2019-08-15 Styliani Consta , Raymond Kapral

The stationary nonempirical simulations of Na+(H2O)n clusters with n in a range of 28 to 51 carried out at the density functional level with a hybrid B3LYP functional and the Born-Oppenheimer molecular dynamics modeling of the size selected…

Chemical Physics · Physics 2024-05-08 Yulia V. Novakovskaya

We have performed large-scale Lennard-Jones molecular dynamics simulations of homogeneous vapor-to-liquid nucleation, with $10^9$ atoms. This large number allows us to resolve extremely low nucleation rates, and also provides excellent…

Chemical Physics · Physics 2014-04-07 Raymond Angélil , Jürg Diemand , Kyoko K. Tanaka , Hidekazu Tanaka

The solvation structure of protons in aqueous media is highly relevant to electric properties and to proton transport in liquids and membranes. At ambient temperature, polar liquids display structural fluctuations on femto- to picosecond…

We consider homogeneous crystallisation rates in confocal microscopy experiments on colloidal nearly hard spheres at the single particle level. These we compare with Brownian dynamics simuations by carefully modelling the softness in the…

Soft Condensed Matter · Physics 2017-12-27 Jade Taffs , Stephen R. Williams , Hajime Tanaka , C. Patrick Royall

We studied by means of computer simulations the low temperature properties of two-dimensional parahydrogen clusters comprising between 7 and 30 molecules. Computed energetics is in quantitative agreement with that reported in the only…

Statistical Mechanics · Physics 2014-06-05 Saheed Idowu , Massimo Boninsegni

Thermal stability properties and the melting-like transition of Na_n, n=13-147, clusters are studied through microcanonical molecular dynamics simulations. The metallic bonding in the sodium clusters is mimicked by a many-body Gupta…

Atomic and Molecular Clusters · Physics 2007-05-23 Juan A. Reyes-Nava , Ignacio L. Garzon , Marcela R. Beltran , Karo Michaelian

The structural and dynamical properties of OCS molecules solvated in Helium clusters are studied using reptation quantum Monte Carlo, for cluster sizes n=3-20 He atoms. Computer simulations allow us to establish a relation between the…

Condensed Matter · Physics 2009-11-07 Saverio Moroni , Antonio Sarsa , Stefano Fantoni , Kevin E. Schmidt , Stefano Baroni

Two dimensional (2D) classical system of dipole particles confined by a quadratic potential is studied. For clusters of N < 81 particles ground state configurations and appropriate eigenfrequencies and eigenvectors for the normal modes are…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 A. I. Belousov , Yu. E. Lozovik

Perturbing fluids of neutrons and protons (nuclear matter) may lead, as the most catastrophic effect, to the rearrangement of the fluid into clusters of nucleons. A similar process may occur in a single atomic nucleus undergoing a violent…

Nuclear Theory · Physics 2018-05-23 P. Napolitani , M. Colonna , C. Mancini-Terracciano

We present results of computer simulations of a parahydrogen cluster of a thousand molecules, corresponding to approximately 4 nm in diameter, at temperatures between 1 K and 10 K. Examination of structural properties suggests that the…

Mesoscale and Nanoscale Physics · Physics 2019-07-19 Massimo Boninsegni

The structural, electronic, and vibrational thermodynamic properties of the (ZnO)$_n$ (n=2-16) clusters are studied using density functional - full potential computations. The results show, small clusters up to $n=9$ stabilize in the 2D…

Materials Science · Physics 2013-05-28 I. Abdolhosseini Sarsari , S. Javad Hashemifar , Hadi Salamati , Hadi Akbarzadeh

The process of protons transport in molecular water chains is of fundamental interest for many biological systems. Although many features of such systems can be analyzed using large-scale computational modeling, other features are better…

Biological Physics · Physics 2011-08-23 Artem Korzhimanov , Mattias Marklund , Tatiana Shutova , Goran Samuelsson

The structure of the excess proton in liquid water has been the subject of lively debate from both experimental and theoretical fronts for the last century. Fluctuations of the proton are typically interpreted in terms of limiting states…

Nuclei at both the neutron- and proton-drip lines are studied. In the cluster-core model, the halo-structure of all the observed and proposed cases of neutron- or proton-halos is investigated in terms of simple potential energy surfaces…

Nuclear Theory · Physics 2011-11-09 Raj K. Gupta , Sushil Kumar , M. Balasubramaniam , G. Munzenberg , Werner Scheid

In this paper, we consider $N$ clusters of pairs of particles sedimenting in a viscous fluid. The particles are assumed to be rigid spheres and inertia of both particles and fluid are neglected. The distance between each two particles…

Analysis of PDEs · Mathematics 2020-02-05 Amina Mecherbet

Water is often viewed as a collection of monomers interacting electrostatically with each other. We compare the water proton momentum distributions from recent neutron scattering data with those calculated from two electronic structure…

Chemical Physics · Physics 2015-05-27 C. J. Burnham , G. F. Reiter , T. Hayashi , S. Mukamel , R. L. Napoleon , T. Keyes

The charge and proton dynamics in hydrogen-bonded networks are investigated using ammonia as a model system. The fragmentation dynamics of medium-sized clusters (1-2 nm) upon single photon multi-ionization is studied, by analyzing the…

We present a microscopic analysis of the quantum solvation structures of para-H$_2$ around the OCS molecule when embedded in low temperature $^4$He droplets. The structures of clusters containing M=5 and 6 para-H$_2$ molecules are compared…

Condensed Matter · Physics 2009-11-10 Yongkyung Kwon , K. Birgitta Whaley

Context: Bouncing collisions of dust aggregates within the protoplanetary may have a significant impact on the growth process of planetesimals. Yet, the conditions that result in bouncing are not very well understood. Existing simulations…

Earth and Planetary Astrophysics · Physics 2013-10-17 Alexander Seizinger , Wilhelm Kley
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