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In bipartite quantum systems commutation relations between the Hamiltonian of each subsystem and the interaction impose fundamental constraints on the dynamics of each partition. Here we investigate work, heat and entropy production in…

Quantum Physics · Physics 2015-07-03 Hoda Hossein-Nejad , Edward J. O'Reilly , Alexandra Olaya-Castro

The separation of internal energy into heat and work in quantum thermodynamics is a controversial issue for a long time, and we revisit and solve this problem in this work. It is shown that the Hamiltonian plays dual roles for a quantum…

Quantum Physics · Physics 2025-01-03 Tao Zhou , Jiangyang Pu , Xiaohua Wu

It is possible to extract work from a quantum-mechanical system whose dynamics is governed by a time-dependent cyclic Hamiltonian. An energy bath is required to operate such a quantum engine in place of the heat bath used to run a…

Quantum Physics · Physics 2009-11-07 C. M. Bender , D. C. Brody , B. K. Meister

Accurately describing work extraction from a quantum system is a central objective for the extension of thermodynamics to individual quantum systems. The concepts of work and heat are surprisingly subtle when generalizations are made to…

Quantum Physics · Physics 2015-03-30 Felix C. Binder , Sai Vinjanampathy , Kavan Modi , John Goold

Considering an entropy-based division of energy transferred into heat and work, we develop an alternative theoretical framework for the thermodynamic analysis of two-level systems. When comparing these results with those obtained under the…

Quantum Physics · Physics 2021-04-14 Andrés Vallejo , Alejandro Romanelli , Raúl Donangelo

In this paper, unambiguous redefinitions of heat and work are presented for quantum thermodynamic systems. We will use genuine reasoning based on which Clausius originally defined work and heat in establishing thermodynamics. The change in…

Quantum Physics · Physics 2023-03-15 B. Ahmadi , S. Salimi , A. S. Khorashad

Several prior attempts to formulate the Laws of Thermodynamics for a small region within a larger quantum system have led to inconsistencies and unexplained infinities. The entropy and external work, in particular, require careful analysis…

Quantum Physics · Physics 2025-06-26 Parth Kumar , Charles A. Stafford

We introduce an ergotropy-based formulation of quantum thermodynamics, which provides a strong connection between average heat and von Neumann entropy. By adopting this formulation, we can reinterpret the infinitesimal average heat in terms…

Quantum Physics · Physics 2025-11-26 J. M. Z. Choquehuanca , P. A. C. Obando , M. S. Sarandy , F. M. de Paula

Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this…

Quantum Physics · Physics 2025-12-02 J. M. Z. Choquehuanca

Given the evolution of an arbitrary open quantum system, we formulate a general and unambiguous method to separate the internal energy change of the system into an entropy-related contribution and a part causing no entropy change,…

Quantum Physics · Physics 2022-10-26 S. Alipour , A. T. Rezakhani , A. Chenu , A. del Campo , T. Ala-Nissila

We present a new proposal for distinguishing heat from work based on a control-theoretic observability decomposition. We derive a Hermitian operator representing instantaneous dissipation of observable energy, and suggest a generalization…

Quantum Physics · Physics 2024-03-28 William Rupush , Oscar Grånäs

How should one define thermodynamic quantities (internal energy, work, heat, etc.) for quantum systems coupled to their environments strongly? We examine three (classically equivalent) definitions of a quantum system's internal energy under…

Despite the increasing interest, the research field which studies the concepts of work and heat at quantum level has suffered from two main drawbacks: first, the difficulty to properly define and measure the work, heat and internal energy…

Quantum Physics · Physics 2021-07-07 Paolo Solinas , Mirko Amico , Nino Zanghì

We discuss the possibility of defining an emergent local temperature in extended quantum many-body systems evolving out of equilibrium. For the most simple case of free-fermionic systems, we give an explicit formula for the effective…

Statistical Mechanics · Physics 2023-03-06 M. Coppola , D. Karevski

In this thesis, we focus on the energetic analysis within autonomous quantum systems. To this aim, we propose a novel and general formalism for a dynamic description of the energy exchanges between interacting subsystems. From the Schmidt…

Quantum Physics · Physics 2022-11-15 André Hernandes Alves Malavazi

The long-time dynamics of quantum systems, typically, but not always, results in a thermal steady state. The microscopic processes that lead to or circumvent this fate are of interest, since everyday experience tells us that not all spatial…

Statistical Mechanics · Physics 2024-05-13 Ken K. W. Ma , Hitesh J. Changlani

Recent advances in quantum thermodynamics have been focusing on ever more elementary systems of interest, approaching the limit of a single qubit, with correlations, strong coupling and non-equilibrium environments coming into play. Under…

Quantum Physics · Physics 2023-10-17 Luis Rodrigo Torres Neves , Frederico Brito

We consider continuously monitored quantum systems and introduce definitions of work and heat along individual quantum trajectories that are valid for coherent superpositions of energy eigenstates. We use these quantities to extend the…

Quantum Physics · Physics 2016-03-22 Jose Joaquin Alonso , Eric Lutz , Alessandro Romito

How to rigorously define thermodynamic quantities such as heat, work, and internal energy in open quantum systems driven far from equilibrium remains a significant open question in quantum thermodynamics. Heat is a quantity whose…

Mesoscale and Nanoscale Physics · Physics 2023-07-18 Parth Kumar , Charles A. Stafford

Quantum open systems evolve according to completely positive, trace preserving maps acting on the density operator, which can equivalently be unraveled in term of so-called quantum trajectories. These stochastic sequences of pure states…

Quantum Physics · Physics 2019-05-01 Cyril Elouard , Hamed Mohammady
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