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We present a method for the direct evaluation of the difference between the free energies of two crystalline structures, of different symmetry. The method rests on a Monte Carlo procedure which allows one to sample along a path, through…

Statistical Mechanics · Physics 2009-10-30 A. D. Bruce , N. B. Wilding , G. J. Ackland

A free-energy functional for a crystal that contains both the symmetry conserved and symmetry broken parts of the direct pair correlation function is developed. The free-energy functional is used to investigate the crystallization of fluids…

Soft Condensed Matter · Physics 2015-05-13 Swarn Lata Singh , Yashwant Singh

The interfacial free energy between a crystal and a fluid, {\gamma} cf, is a highly relevant parameter in phenomena such as wetting or crystal nucleation and growth. Due to the difficulty of measuring {\gamma} cf experimentally, computer…

Statistical Mechanics · Physics 2015-06-23 J. R. Espinosa , C. Vega , E. Sanz

We use numerical simulations to investigate the hydrodynamic behavior of the interface between nematic (N) and isotropic (I) phases of a confined active liquid crystal. At low activities, a stable interface with constant shape and velocity…

Soft Condensed Matter · Physics 2021-02-25 Rodrigo C. V. Coelho , Nuno A. M. Araújo , Margarida M. Telo da Gama

The contribution of the smectic-nematic interface to the surface energy of a nematic liquid crystal sample is analyzed. By means of a simple model it is shown that the surface energy depends on the thickness of the region over which the…

Condensed Matter · Physics 2009-10-31 L. R. Evangelista , S. Fontanini , L. C. Malacarne , R. S. Mendes

We propose several linear, fully decoupled numerical schemes with first- and second-order temporal accuracy for a novel Q-tensor-based two-phase hydrodynamic model describing the coupling of active nematic liquid crystal solutions with…

Numerical Analysis · Mathematics 2026-05-26 Xuelong Gu , Guanghua Ji , Qi Wang

In the mean field approximation, we evaluate the temperature dependence of the anchoring energy strength of a nematic liquid crystal in contact with a solid substrate due to thermal fluctuations. Our study is limited to the weak anchoring…

Soft Condensed Matter · Physics 2009-10-31 G. Barbero , A. K. Zvezdin

This article re-examines a classic question in liquid-crystal physics: What are the elastic modes of a nematic liquid crystal? The analysis uses a recent mathematical construction, which breaks the director gradient tensor into four…

Soft Condensed Matter · Physics 2019-03-04 Jonathan V. Selinger

This paper outlines an energy-minimization finite-element approach to the computational modeling of equilibrium configurations for nematic liquid crystals under free elastic effects. The method targets minimization of the system free energy…

Numerical Analysis · Mathematics 2014-02-17 J. H. Adler , T. J. Atherton , D. B. Emerson , S. P. MacLachlan

The phase field crystal (PFC) method has emerged as a promising technique for modeling materials with atomistic resolution on mesoscopic time scales. The approach is numerically much more efficient than classical density functional theory…

Materials Science · Physics 2015-05-18 Michael Greenwood , Nikolas Provatas , Jörg Rottler

Active nematics are influenced by alignment angle singularities called topological defects. The localization of these defects is of major interest for biological applications. The total distortion of alignment angles due to defects is…

Fluid Dynamics · Physics 2024-05-28 Hiroyuki Miyoshi , Hiroki Miyazako , Takaaki Nara

The effective potential formalism is applied to glass forming liquids, choosing a coupling potential such that the "order parameter", conjugated to the coupling strength, is the mean square displacement of the particles from their position…

Disordered Systems and Neural Networks · Physics 2007-05-23 Antonio de Candia

We compute effective energies of thin bilayer structures composed by soft nematic elastic-liquid crystals in various geometrical regimes and functional configurations. Our focus is on order-strain interaction in elastic foundations composed…

Analysis of PDEs · Mathematics 2021-03-12 Pierluigi Cesana , Andres A Leon Baldelli

Anisotropic fluids appear in a diverse array of systems, from liquid-crystal displays to bacterial swarms, and are characterized by orientational order. Large colloidal particles immersed in such environments disturb the medium's…

Soft Condensed Matter · Physics 2025-01-03 Thomas G. J. Chandler , Saverio E. Spagnolie

We carry out umbrella sampling Monte Carlo simulations to evaluate the free energy surface of the ST2 model of water as a function two order parameters, the density and a bond-orientational order parameter. We approximate the long-range…

Statistical Mechanics · Physics 2013-01-18 Peter H. Poole , Richard K. Bowles , Ivan Saika-Voivod , Francesco Sciortino

We consider a Landau-de Gennes model for a polydisperse, inhomogeneous suspension of colloidal inclusions in a nematic host, in the dilute regime. We study the homogenised limit and compute the effective free energy of the composite…

Analysis of PDEs · Mathematics 2019-10-09 Giacomo Canevari , Arghir Zarnescu

We have written expressions for the free energy of a cholesteric liquid crystal in an approximation using the elasticity constants K_1, K_2, K_3 and the energy variation and the corresponding energy and energy gradient along the direction…

Soft Condensed Matter · Physics 2022-05-09 I M Tambovtsev , I S Lobanov

The ground state of twist-bend nematic liquid crystals is a heliconical molecular arrangement in which the nematic director precesses uniformly about an axis, making a fixed angle with it. Both precession senses are allowed in the ground…

Soft Condensed Matter · Physics 2014-04-15 Epifanio G. Virga

We analytically derive the effective layer elastic energy of smectic-A and smectic-C liquid crystals by adiabatic elimination of the orientational degree of freedom from the generalized Chen-Lubensky model. In the smectic-A phase, the…

Soft Condensed Matter · Physics 2007-11-13 Hiroto Ogawa

We consider nematic liquid crystals in a bounded, convex polyhedron described by a director field n(r) subject to tangent boundary conditions. We derive lower bounds for the one-constant elastic energy in terms of topological invariants.…

Mathematical Physics · Physics 2009-11-10 A Majumdar , JM Robbins , M Zyskin