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Recently we have reported the direct observation of two-dimensional (2D) Ca-Cl crystals on reduced graphene oxide (rGO) membranes, in which the calcium ions are only about monovalent (i.e. ~+1) and metallic rather than insulating properties…
Calcium carbonate plays a crucial role in the global carbon cycle, and its phase diagram has always been of significant scientific interest. In this study, we used molecular dynamics (MD) to investigate several structural phase transitions…
Hydrogen-based direct reduction offers a sustainable pathway to decarbonize the metal production industry. However, stable metal oxides, like Cr$_2$O$_3$, are notoriously difficult to reduce, requiring extremely high temperatures (above…
Fe-Cr binary alloys serve as simplified model systems to study irradiation damage relevant to fusion structural materials. Here, Fe-3%Cr and Fe-5%Cr samples were irradiated with 4 MeV Fe ions under a dose rate of 4x10^5 dpa/s across a…
Herein we report on the synthesis of a metastable (Cr,Y)2AlC MAX phase solid solution by co-sputtering from a composite Cr-Al-C and elemental Y target, at room temperature, followed by annealing. While direct high-temperature synthesis…
The atmospheric reaction of H$_2$S with Cl has been reinvestigated to check if, as previously suggested, only explicit dynamical computations can lead to an accurate evaluation of the reaction rate because of strong recrossing effects and…
Chiral molecules are characterized by a specific optical rotation angle. An experimental method was presented to dissect the temperature dependence of the optical rotation angle with the molecular chirality of D-alanine, L-alanine and…
The energy dependence of the rates of the reactions between He$^+$ and ammonia (NY$_3$, Y= {H,D}), forming NY$_2^+$, Y and He as well as NY$^+$, Y$_2$ and He, and the corresponding product branching ratios have been measured at low…
Phase transformations are widely studied using continuous-heating experiments. In isothermal studies, their kinetics are often described using the Johnson-Mehl-Avrami-Kolmogorov (JMAK) rate equation. For continuous-heating studies, the same…
Motivated by the challenge of identifying intruder ions in a cold ion crystal, we investigate calorimetry from emitted fluorescence light. Under continuous Doppler cooling, the ion crystal reaches a temperature equilibrium with a fixed…
The coupled valence and spin state transition (VSST) taking place in (Pr0.7Sm0.3)0.7Ca0.3CoO3 was investigated by soft x-ray absorption spectroscopy (XAS) experiments carried out at the Pr-M4,5, Co-L2,3, and O-1s edges. This VSST is found…
Temperature behavior of the Bi+ center emission, excitation bands and luminescence decay law in KAlCl4 crystal are investigated. Abrupt changes of the monocation optical properties are observed at phase transitions of the host. The observed…
Ce3+ is known to show broad optical emission peaking in the green spectral range. For the stabilization of 3-valent cerium in ceramic phosphors such as calcium scandate CaSc2O4, often co-doping with sodium for charge compensation is…
In the endeavour of developing quantum memories, Er$^{3+}$:CaWO$_4$ has emerged as a promising rare-earth ion-doped (REID) crystal platform due to its long optical coherence times and compatibility with the 1550 nm telecommunications band.…
Our aim is to determine the dominant processes and timescales for the ionisation equilibrium of calcium under solar chromospheric conditions. The study is based on numerical simulations with the RADYN code, which includes hydrodynamics,…
Utilizing a simplified quantum model approach, the low-energy inelastic collision processes between yttrium atoms (ions) and hydrogen atoms have been studied. Rate coefficients corresponding to the mutual neutralization, ion-pair formation,…
Calcium vanadate CaV$_2$O$_4$ has a crystal structure of quasi-one-dimensional zigzag chains composed of orbital-active V$^{3+}$ ions and undergoes successive structural and antiferromagnetic phase transitions at $T_s\sim 140$ K and $T_N…
This paper focuses on the spectroscopic properties of Cr4+:YAG transparent ceramic. Absorption, excitation, and emission spectra were measured over a temperature range from 5K to 300K. Low-temperature absorption spectra reveal sharp and…
We investigate the temperature dependence of the Casimir-Polder interaction in the electrostatic limit. This unusual phenomenon relies on the coupling between a virtual atomic transition and a thermal excitation of surface polariton modes.…
We present a theoretical study of the impact of oxygen diffusion in oxide crystals on metal dopants ionic state and the conduction type under dynamic changes. The slow changes under thermal equilibrium are provided in a companion, Part I…