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From microactuators to biological tissues, non-porous materials with the ability to strongly expand when in contact with a solvent are ubiquitous. Consequently, the swelling of polymer systems such as hydrogel has received recently much…

Soft Condensed Matter · Physics 2024-11-04 George T. Fortune , Merlin A. Etzold , Julien R. Landel , Stuart B. Dalziel

Condensation and frost formation degrade the heat transfer performance of air-conditioners and refrigerators. Yet, the frost formation mechanism has not been fully understood. In the present study, we numerically investigated H2O droplets…

Mesoscale and Nanoscale Physics · Physics 2021-04-27 Yoshitaka Ueki , Yuta Tsutsumi , Masahiko Shibahara

The majority of hydrogen in the interstellar medium (ISM) is in atomic form. The transition from atoms to molecules and, in particular, the formation of the H$_2$ molecule, is a key step in cosmic structure formation en route to stars.…

Astrophysics of Galaxies · Physics 2018-10-31 Pei Zuo , Di Li , J. E. G. Peek , Qiang Chang , Xia Zhang , Nicholas chapman , Paul F. Goldsmith , Zhi-Yu Zhang

Understanding the molecular content of galaxies is a critical problem in star formation and galactic evolution. Here we present a new method, based on a Stromgren-type analysis, to calculate the amount of HI that surrounds a molecular cloud…

Astrophysics of Galaxies · Physics 2015-05-13 Christopher F. McKee , Mark R. Krumholz

Context. It is generally agreed that hydrogenation reactions dominate chemistry on grain surfaces in cold, dense molecular cores, saturating the molecules present in ice mantles. Aims. We present a study of the low temperature reactivity of…

Solar and Stellar Astrophysics · Physics 2015-04-15 J. A. Noble , P. Theule , E. Congiu , F. Dulieu , M. Bonnin , A. Bassas , F. Duvernay , G. Danger , T. Chiavassa

The adsorption properties of isolated H$_{2}$O molecule on stoichiometric and reduced (with on-surface oxygen vacancy) ceria(1111) surfaces at low coverage are theoretically investigated by using density-functional-theory+\emph{U}…

Materials Science · Physics 2012-02-10 Shuang-Xi Wang , Ping Zhang , Shu-Shen Li

Molecular cooling is essential for studying the formation of sub-structure of dissipative dark-matter halos that may host compact objects such as black holes. Here, we analyze the reaction rates relevant for the formation, dissociation, and…

Cosmology and Nongalactic Astrophysics · Physics 2022-08-09 Michael Ryan , James Gurian , Sarah Shandera , Donghui Jeong

Astrochemical surface reactions are thought to be responsible for the formation of complex organic molecules, which are of potential importance for the origin of life. In a situation, when the chemical composition of dust surfaces is not…

Chemical Physics · Physics 2022-11-09 Thomas K. Henning , Serge A. Krasnokutski

Molecular hydrogen in silicon has been studied by path-integral molecular dynamics simulations in the canonical ensemble. Finite-temperature properties of these point defects were analyzed in the range from 300 to 900 K. Interatomic…

Materials Science · Physics 2009-07-31 Carlos P. Herrero , Rafael Ramirez

We present results of classical dynamics calculations, performed to study the photodissociation of water in crystalline and amorphous ice surfaces at a surface temperature of 10 K. Dissociation in the top six monolayers is considered.…

Astrophysics · Physics 2009-11-11 Stefan Andersson , Ayman Al-Halabi , Geert-Jan Kroes , Ewine F. van Dishoeck

The process of formation for an ice crystal with elaborate, symmetrical patterns from the water vapor is usually complicated and the corresponding mechanism is still not clear. Here, we experimentally constructed the 3D tubular ice crystals…

Applied Physics · Physics 2020-11-03 Xiaolu Zhu , Zheng Wang

Solid state astrochemical reaction pathways have the potential to link the formation of small nitrogen-bearing species, like NH3 and HNCO, and prebiotic molecules, specifically amino acids. To date, the chemical origin of such small…

Astrophysics of Galaxies · Physics 2017-05-26 Gleb Fedoseev , Sergio Ioppolo , Dongfeng Zhao , Thanja Lamberts , Harold Linnartz

This study focuses on the formation of two molecules of astrobiological importance - glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH) - by surface hydrogenation of CO molecules. Our experiments aim at simulating the CO…

Astrophysics of Galaxies · Physics 2017-05-26 Gleb Fedoseev , Herma M. Cuppen , Sergio Ioppolo , Thanja Lamberts , Harold Linnartz

Context. The abundances of many observed compounds in interstellar molecular clouds still lack an explanation, despite extensive research that includes both gas and solid (dust-grain surface) phase reactions. Aims. We aim to qualitatively…

Astrophysics of Galaxies · Physics 2012-07-12 Juris Kalvans , Ivar Shmeld

Two different types of experiments were performed. In the first experiment, we studied the low-temperature condensation of vaporized graphite inside bulk liquid helium, while in the second experiment, we studied the condensation of single…

Atomic and Molecular Clusters · Physics 2018-05-07 S. A. Krasnokutski , M. Goulart , E. B. Gordon , A. Ritsch , C. Jäger , M. Rastogi , W. Salvenmoser , Th. Henning , P. Scheier

The key kinetic barrier to dolomite formation is related to the surface Mg2+-H2O complex, which hinders binding of surface Mg2+ ions to the CO3 2- ions in solution. It has been proposed that this reaction can be catalyzed by dissolved…

Geophysics · Physics 2016-08-12 Zhizhang Shen , Yun Liu , Philip E. Brown , Izabela Szlufarska , Huifang Xu

We present a simplified chemical and thermal model designed to allow computationally efficient study of the thermal evolution of metal-poor gas within large numerical simulations. Our main simplification is the neglect of the molecular…

Astrophysics · Physics 2009-06-23 S. C. O. Glover , A. -K. Jappsen

Motivated by the observed connection between molecular hydrogen (H2) and star formation, we present a method for tracking the non-equilibrium abundance and cooling processes of H2 and H2-based star formation in Smoothed Particle…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-05 Charlotte Christensen , Thomas Quinn , Fabio Governato , Adrienne Stilp , Sijing Shen , James Wadsley

New ternary Mg-Ni-Mn intermetallics have been successfully synthesized by High Energy Ball Milling (HEBM) and have been studied as possible materials for efficient hydrogen storage applications. The microstructures of the as-cast and milled…

The formation of CO2 in quiescent regions of molecular clouds is not yet fully understood, despite CO2 having an abundance of around 10-34 % H2O. We present a study of the formation of CO2 via the non-energetic route CO + OH on non-porous…

Solar and Stellar Astrophysics · Physics 2011-07-05 Jennifer Anna Noble , François Dulieu , Emanuele Congiu , Helen Jane Fraser