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The isomerism of molecules in the interstellar medium and the mechanisms behind it are essential questions in the chemistry of organic molecules in space. In particular, for the simple formic and thioformic acids, the low temperatures found…

The temperature dependence of hydrogen (H) desorption from Si(100) H-terminated surfaces by a scanning tunneling microscope (STM) is reported for negative sample bias. It is found that the STM induced H desorption rate ($R$) decreases…

Materials Science · Physics 2009-10-31 C. Thirstrup , M. Sakurai , T. Nakayama , K. Stokbro

In this study used is an approach based on measurements of the total energy distribution (TED) of field emitted electrons in order to examine the properties of Pd (133) from the aspect of both hydrogen adsorption and surface hydrides…

Other Condensed Matter · Physics 2009-11-13 A. Tomaszewska , Z. M. Stepien

We describe the phase diagram of amorphous solid water by performing molecular dynamics simulations. Our simulations follow different paths in the phase diagram: isothermal compression/decompression, isochoric cooling/heating and isobaric…

Soft Condensed Matter · Physics 2009-11-11 Nicolas Giovambattista , H. Eugene Stanley , Francesco Sciortino

We report on the frozen-spin polarized hydrogen--deuteride (HD) targets for photoproduction experiments at SPring-8/LEPS. Pure HD gas with a small amount of ortho-H2 (~0.1%) was liquefied and solidified by liquid helium. The temperature of…

Instrumentation and Detectors · Physics 2020-09-11 T. Ohta , M. Fujiwara , T. Hotta , I. Ide , K. Ishizaki , H. Kohri , Y. Yanai , M. Yosoi

Solid O2 has been proposed as a possible reservoir for oxygen in dense clouds through freeze-out processes. The aim of this work is to characterize quantitatively the physical processes that are involved in the desorption kinetics of CO-O2…

Astrophysics · Physics 2009-11-13 K. Acharyya , G. W. Fuchs , H. J. Fraser , E. F. van Dishoeck , H. Linnartz

We report the detection of H2 in a zabs= 0.0963 Damped Lyman-{\alpha} (DLA) system towards zem = 0.4716 QSO J1619+3342. This DLA has log N(H I) = 20.55 (0.10), 18.13 < log N(H2) < 18.40, [S/H] = -0.62 (0.13), [Fe/S] = -1.00 (0.17) and the…

Astrophysics of Galaxies · Physics 2015-06-22 Raghunathan Srianand , Hadi Rahmani , Sowgat Muzahid , Vijay Mohan

We investigate the propagation of a shock wave into a warm neutral medium and cold neutral medium by one-dimensional hydrodynamic calculations with detailed treatment of thermal and chemical processes. Our main result shows that thermal…

Astrophysics · Physics 2009-10-31 Hiroshi Koyama , Shu-Ichiro Inutsuka

A new mechanism to form a magnetic pressure supported, high temperature corona above the photosphere of an accretion disk is explored using three dimensional radiation magneto-hydrodynamic (MHD) simulations. The thermal properties of the…

High Energy Astrophysical Phenomena · Physics 2015-06-18 Yan-Fei Jiang , James M. Stone , Shane W. Davis

Molecular dynamics calculations have been performed to study the ultraviolet photodissociation of D2O in an amorphous D2O ice surface at 10-90 K, in order to investigate the influence of isotope effects on the photodesorption processes. As…

Chemical Physics · Physics 2011-05-06 C. Arasa , S. Andersson , H. M. Cuppen , E. F. van Dishoeck , G. J. Kroes

In the interstellar clouds, molecular hydrogens are formed from atomic hydrogen on grain surfaces. An atomic hydrogen hops around till it finds another one with which it combines. This necessarily implies that the average recombination…

Astrophysics · Physics 2009-11-13 Sandip Kumar Chakrabarti , Ankan Das , Kinsuk Acharyya , Sonali Chakrabarti

At the few-atom-thick limit, transition metal dichalcogenides (TMDs) exhibit a host of attractive electronic optical, and structural properties. The possibility to pattern these properties has a great impact on applied and fundamental…

The effect of surface atom vibrations for H$_2$ scattering from a Cu(111) surface at different temperatures is being investigated for hydrogen molecules in their rovibrational ground state ($v$=0, $j$=0). We assume weakly correlated…

Other Condensed Matter · Physics 2021-05-04 Joy Dutta , Souvik Mandal , Satrajit Adhikari , Paul Spiering , Jörg Meyer , Mark F. Somers

Existence of strongly bound water molecules on silicate surfaces, above the desorption temperature of water ice, has been first predicted by computational studies and recently demonstrated by laboratory experiments. Such trapped water may…

Astrophysics of Galaxies · Physics 2024-02-22 Alexey Potapov , Cornelia Jäger , Harald Mutschke , Thomas Henning

In this work we investigate the effects of the environment on the X-ray photoelectron spectra of hydrogen chloride and the chloride ions adsorbed on ice surfaces, as well as of chloride ions in water droplets. In our approach, we combine a…

Chemical Physics · Physics 2023-09-18 Richard A. Opoku , Céline Toubin , André Severo Pereira Gomes

Amorphous hydrogenated silicon (a-Si:H) is an important material for surface defect passivation of photovoltaic silicon (Si) wafers in order to reduce their recombination losses. The material is however unstable with regards to hydrogen (H)…

This work was carried out with using the Caltech Submillimeter Observatory and presents the observational study of HDS and D2S towards a sample of Class 0 sources, and dense cores. We report the first detection of doubly deuterated hydrogen…

Astrophysics · Physics 2009-11-10 C. Vastel , T. G. Phillips , C. Ceccarelli , J. Pearson

Molecular clouds are the cold regions of the Milky Way where stars form. They are enriched by rather complex molecules. Many of these molecules are believed to be synthesized on the icy surfaces of the interstellar submicron-sized dust…

Astrophysics of Galaxies · Physics 2020-07-08 Stefano Pantaleone , Joan Enrique-Romero , Cecilia Ceccarelli , Piero Ugliengo , Nadia Balucani , Albert Rimola

The surface processes on interstellar dust grains have an important role in the chemical evolution in molecular clouds. Hydrogenation reactions on ice surfaces have been extensively investigated and are known to proceed at low temperatures…

Astrophysics of Galaxies · Physics 2021-01-11 Masashi Tsuge , Hiroshi Hidaka , Akira Kouchi , Naoki Watanabe

The knowledge of the binding energy of molecules on astrophysically relevant ices can help to obtain an estimate of the desorption rate, i.e. the molecules residence time on the surface. This represents an important parameter for…

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