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Based on a recently established formalism (U. Ebert, J. Stat. Phys. 82, 183 (1996)) we analyze the diffusive motion of a long polymer in a quenched random medium. The medium is modeled by a frozen semidilute polymer system. In the framework…

Statistical Mechanics · Physics 2015-06-25 Stefan Mueller

A microscopic theory for cation diffusion in polymer electrolytes is presented. Based on a thorough analysis of molecular dynamics simulations on PEO with LiBF$_4$ the mechanisms of cation dynamics are characterised. Cation jumps between…

Soft Condensed Matter · Physics 2009-11-13 A. Maitra , A. Heuer

Molecular dynamics simulations were conducted to investigate the dynamic properties of melts of nonconcatenated ring polymers and compared to melts of linear polymers. The longest rings were composed of N=1600 monomers per chain which…

Soft Condensed Matter · Physics 2011-05-02 Jonathan D. Halverson , Won Bo Lee , Gary S. Grest , Alexander Y. Grosberg , Kurt Kremer

A polymer model given in terms of beads, interacting through Hookean springs and hydrodynamic forces, is studied. Brownian dynamics description of this bead-spring polymer model is extended to multiple resolutions. Using this multiscale…

Chemical Physics · Physics 2018-06-13 Edward Rolls , Radek Erban

We study the asymptotic behavior of a self-interacting one-dimensional Brownian polymer first introduced by Durrett and Rogers [Probab. Theory Related Fields 92 (1992) 337--349]. The polymer describes a stochastic process with a drift which…

Probability · Mathematics 2012-06-11 Pierre Tarrès , Bálint Tóth , Benedek Valkó

The scaling form of the whole distribution P(D) of the random diffusion coefficient D(x) in a model of classically diffusing particles is investigated. The renormalization group approach above the lower critical dimension d=0 is applied to…

Condensed Matter · Physics 2009-10-22 Yan-Chr Tsai , Yonathan Shapir

Dynamical polydispersity in single-particle properties, for example a fluctuating particle size, shape, charge density, etc., is intrinsic to responsive colloids (RCs), such as biomacromolecules or microgels, but is typically not resolved…

Soft Condensed Matter · Physics 2021-05-26 Upayan Baul , Joachim Dzubiella

The interdiffusion of a solvent into a polymer melt has been studied using large scale molecular dynamics and Monte Carlo simulation techniques. The solvent concentration profile and weight gain by the polymer have been measured as a…

Soft Condensed Matter · Physics 2009-11-10 Mesfin Tsige , Gary S. Grest

In this paper, we employ Molecular Dynamics computer simulations to study and compare the statics and dynamics of linear and circular (ring) polymer chains in entangled solutions of different densities. While we confirm that linear chain…

Soft Condensed Matter · Physics 2016-02-17 Negar Nahali , Angelo Rosa

Diffusion and rectification of Brownian particles powered by a rotating wheel are numerically investigated in a two-dimensional channel. The nonequilibrium driving comes from the rotating wheel, which can break thermodynamical equilibrium…

Statistical Mechanics · Physics 2017-07-24 Bao-quan Ai

Self-assembled linear structures like giant cylindrical micelles or discotic molecules in solution stacked in flexible columns are systems reminiscent of polydisperse polymer solutions.These supramolecular polymers have an equilibrium…

Soft Condensed Matter · Physics 2015-06-25 C-C Huang , H. Xu , F. Crevel , J. Wittmer , J. -P. Ryckaert

We study the mean velocity and diffusion constant in three related models of molecular Brownian ratchets. Brownian ratchets can be used to describe translocation of biopolymers like DNA through nanopores in cells in the presence of…

Statistical Mechanics · Physics 2018-08-08 Matthias Uhl , Udo Seifert

Measurements of protein motion in living cells and membranes consistently report transient anomalous diffusion (subdiffusion) which converges back to a Brownian motion with reduced diffusion coefficient at long times, after the anomalous…

Quantitative Methods · Quantitative Biology 2015-06-05 Hédi Soula , Bertrand Caré , Guillaume Beslon , Hugues Berry

We study the dynamics of a polymer or a D-dimensional elastic manifold diffusing and convected in a non-potential static random flow (the ``randomly driven polymer model''). We find that short-range (SR) disorder is relevant for d < 4 for…

Condensed Matter · Physics 2009-07-10 Kay Joerg Wiese , Pierre Le Doussal

Langevin simulations provide an effective way to study collective effects of Brownian particles immersed in a two-dimensional periodic potential. In this paper, we concentrate essentially on the behaviour of the tracer (DTr) and bulk (DB)…

Statistical Mechanics · Physics 2015-05-13 S. Zayzoune , M. Mazroui , Y. Boughaleb , A. Kara

We present extensive molecular dynamics simulations of the motion of a single linear rigid molecule in a two-dimensional random array of fixed obstacles. The diffusion constant for the center of mass translation, $D_{\rm CM}$, and for…

Soft Condensed Matter · Physics 2009-11-10 Angel J. Moreno , Walter Kob

Irreversible diffusion limited cluster aggregation (DLCA) of hard spheres was simulated using Brownian cluster dynamics. Bound spheres were allowed to move freely within a specified range, but no bond breaking was allowed. The structure and…

Soft Condensed Matter · Physics 2009-03-25 Sujin Babu , Jean-Christophe Gimel , Taco Nicolai

The aim of this paper is to compare results from lattice-Boltzmann and Brownian dynamics simulations of linear chain molecules. We have systematically varied the parameters that may affect the accuracy of the lattice-Boltzmann simulations,…

Computational Physics · Physics 2015-05-13 Anthony J. C. Ladd , Rahul Kekre , Jason E. Butler

We use Brownian dynamics (BD) simulations and single molecule experiments to investigate the influence of topological constraints and hydrodynamic interactions on the dynamics and rheology of solutions of ring-linear polymer blends at the…

Soft Condensed Matter · Physics 2021-07-07 Charles D. Young , Yuecheng Zhou , Charles M. Schroeder , Charles E. Sing

The interplay between concentration, flow, hydrodynamic interactions (HI), and topological interactions governing semidilute polymer dynamics in strong flows are challenging to characterize. Brownian dynamics (BD) simulations are…

Fluid Dynamics · Physics 2019-10-23 Charles D. Young , Charles E. Sing