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A Density Matrix Functional theory is constructed semi-empirically for the two-level Lipkin model. This theory, based on natural orbitals and occupation numbers, is shown to provide a good description for the ground state energy of the…

Nuclear Theory · Physics 2009-01-21 Denis Lacroix

A density-matrix formalism is developed based on the one-particle density-matrix of a single-determinantal reference-state. The v-representable problem does not appear in the proposed method, nor the need to introduce functionals defined by…

Chemical Physics · Physics 2009-11-10 James P. Finley

We performed a benchmark study on a series of dihydrogen bond complexes and constructed a set of reference bond distances and interaction energies. The test set was employed to assess the performance of several wave-function correlated and…

Chemical Physics · Physics 2015-01-22 E. Fabiano , L. A. Constantin , F. Della Sala

Density functional theory is the workhorse of modern electronic structure calculations, with wide-ranging applications in chemistry, physics, materials science, and machine learning. At its heart lies the exchange-correlation functional, a…

Chemical Physics · Physics 2026-02-20 Fabien Tran , Susi Lehtola , Stefano Pittalis , Miguel A. L. Marques

An overview is given of the methods for treating complicated problems without small parameters, when the standard perturbation theory based on the existence of small parameters becomes useless. Such complicated problems are typical of…

High Energy Physics - Phenomenology · Physics 2011-07-19 V. I. Yukalov , E. P. Yukalova

We introduce a density functional formalism to study the ground-state properties of strongly-correlated dipolar and ionic ultracold bosonic and fermionic gases, based on the self-consistent combination of the weak and the strong coupling…

Calculating perturbation response properties of materials from first principles provides a vital link between theory and experiment, but is bottlenecked by the high computational cost. Here a general framework is proposed to perform density…

Computational Physics · Physics 2024-03-01 He Li , Zechen Tang , Jingheng Fu , Wen-Han Dong , Nianlong Zou , Xiaoxun Gong , Wenhui Duan , Yong Xu

The density of an atom in a state of well-defined angular momentum has a specific finite spherical harmonic content, without and with interactions. Approximate single-particle schemes, such as the Hartree, Hartree-Fock, and Local Density…

Materials Science · Physics 2009-02-05 H. A. Fertig , W. Kohn

Nuclear density functional theory (DFT) is the only microscopic, global approach to the structure of atomic nuclei. It is used in numerous applications, from determining the limits of stability to gaining a deep understanding of the…

Nuclear Theory · Physics 2015-02-06 Nicolas Schunck , Jordan D. McDonnell , Jason Sarich , Stefan M. Wild , Dave Higdon

Using a central limit theorem for arrays of interacting quantum systems, we give analytical expressions for the density of states and the partition function at finite temperature of such a system, which are valid in the limit of infinite…

Statistical Mechanics · Physics 2009-11-10 Michael Hartmann , Guenter Mahler , Ortwin Hess

We present a general multi-component density functional theory in which electrons and nuclei are treated completely quantum mechanically, without the use of a Born-Oppenheimer approximation. The two fundamental quantities in terms of which…

Materials Science · Physics 2007-05-23 Thomas Kreibich , Robert van Leeuwen , E. K. U. Gross

Predicting the mean-field Hamiltonian matrix in density functional theory is a fundamental formulation to leverage machine learning for solving molecular science problems. Yet, its applicability is limited by insufficient labeled data for…

Machine Learning · Computer Science 2024-06-06 He Zhang , Chang Liu , Zun Wang , Xinran Wei , Siyuan Liu , Nanning Zheng , Bin Shao , Tie-Yan Liu

We analyze here in details the probability to find a given number of particles in a finite volume inside a normal or superfluid finite system. This probability, also known as counting statistics, is obtained using projection operator…

Nuclear Theory · Physics 2020-01-22 Denis Lacroix , Sakir Ayik

A new variational method for studying the equilibrium states of an interacting particles system has been proposed. The statistical description of the system is realized by means of a density matrix. This method is used for description of…

General Physics · Physics 2014-12-19 Boris Bondarev

Density functional theory (DFT) is an incredible success story. The low computational cost, combined with useful (but not yet chemical) accuracy, has made DFT a standard technique in most branches of chemistry and materials science.…

Chemical Physics · Physics 2015-06-03 Kieron Burke

We derive a multiconfigurational time-dependent Hartree theory for systems with particle conversion. In such systems particles of one kind can convert to another kind and the total number of particles varies in time. The theory thus extends…

Quantum Physics · Physics 2009-02-07 Ofir E. Alon , Alexej I. Streltsov , Lorenz S. Cederbaum

Symmetry properties of densities and mean fields appearing in the nuclear Density Functional Theory with pairing are studied. We consider energy functionals that depend only on local densities and their derivatives. The most important…

Nuclear Theory · Physics 2010-04-06 S. G. Rohozinski , J. Dobaczewski , W. Nazarewicz

The aim of this thesis is to systematically and consistently study strongly coupled bosonic and fermionic conformal field theories using the large quantum number expansion. The idea behind it is to study sectors of conformal field theories…

High Energy Physics - Theory · Physics 2023-05-10 Ioannis Kalogerakis

Hyperuniform particle arrangements are characterized by a local number variance that grows more slowly than the volume of the observation window. We generalize this concept to describe particle systems in which particles carry weights:…

Statistical Mechanics · Physics 2026-03-04 Salvatore Torquato , Jaeuk Kim , Michael A. Klatt , Roberto Car , Paul J. Steinhardt

We present a derivation of a recently proposed theory for the time dependence of density fluctuations in stationary states of strongly interacting, athermal, self-propelled particles. The derivation consists of two steps. First, we start…

Soft Condensed Matter · Physics 2016-01-13 Grzegorz Szamel
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