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A novel implementation of the coupled-cluster singles and doubles (CCSD) approach is presented that is specifically tailored for the treatment of large, symmetric systems. It fully exploits Abelian point-group symmetry and the use of the…

Chemical Physics · Physics 2023-12-07 Tommaso Nottoli , Jürgen Gauss , Filippo Lipparini

Orbital relaxation of the core region is a primary source of error in the computation of core ionization and core excitation energies. Recently, Transition-Potential Coupled Cluster (TP-CC) methods have been used to explicitly treat orbital…

Chemical Physics · Physics 2025-03-17 Alexis A. A. Delgado , Devin A. Matthews

We calculate the electroweak and QCD corrections to W-W+ -> tt and ZZ -> tt. We also consider the interplay of these corrections with the effect of anomalous interactions that affect the massive weak bosons and the top. The results at the…

High Energy Physics - Phenomenology · Physics 2008-11-26 N. Bouayed , F. Boudjema

The successive ionization potentials (IPs) and electron affinities (EAs) for superheavy elements with $111 \leq Z \leq 114$, namely, Rg, Cn, Nh, and Fl are reexamined using the relativistic Fock-space coupled-cluster method with…

Similarity transformed equation-of-motion coupled cluster theory (STEOM-CC) is an alternative approach to equation-of-motion coupled cluster theory for excited states (EOMEE-CC) which uses a second similarity transformation of the…

Chemical Physics · Physics 2025-03-26 Megan Simons , Devin A. Matthews

Many quantum algorithms rely on a quality initial state for optimal performance. Preparing an initial state for specific applications can considerably reduce the cost of probabilistic algorithms such as the well studied quantum phase…

Quantum Physics · Physics 2024-12-10 Alexandre Fleury , James Brown , Erika Lloyd , Maritza Hernandez , Isaac H. Kim

A strong effort will be dedicated in the coming years to extend the reach of ab initio nuclear-structure calculations to heavy doubly open-shell nuclei. In order to do so, the most efficient strategies to incorporate dominant many-body…

Recently, it has been shown that the ground-state energy of a quantum many-body system can be written in terms of cumulants. In this paper we show that the energies of excited states can be expressed similarly. These representations are…

Condensed Matter · Physics 2007-05-23 T. Schork , P. Fulde

The problem of orbital relaxation in computational core-hole spectroscopies, including x-ray absorption and x-ray photoionization, has long plagued linear response approaches, including equation-of-motion coupled cluster with singles and…

Chemical Physics · Physics 2025-03-26 Megan E. Simons , Devin A. Matthews

The \textit{ab initio} approach is used to evaluate the excitation energies of the $2s2p \, ^{2S+1}P_J$ states from the ground state as well as the $2s2p \, ^3P_1 \rightarrow 2s2p \, ^3P_0$ and $2s2p \, ^3P_2 \rightarrow 2s2p \, ^3P_1$…

Atomic Physics · Physics 2024-11-05 A. V. Malyshev , Y. S. Kozhedub , V. M. Shabaev , I. I. Tupitsyn

In this work, we study many-body excitations of Bose-Einstein condensates (BECs) trapped in periodic one-dimensional optical lattices. In particular, we investigate the impact of quantum depletion onto the structure of the low-energy…

In this work, we investigate the possibility of improving multireference-driven coupled cluster (CC) approaches with an algorithm that iteratively combines complete active space (CAS) calculations with tailored CC and externally corrected…

Chemical Physics · Physics 2025-03-06 Robin Feldmann , Max Mörchen , Jakub Lang , Michał Lesiuk , Markus Reiher

A new method that accurately describes strongly correlated states and captures dynamical correlation is presented. It is derived as a modification of coupled-cluster theory with single and double excitations (CCSD) through consideration of…

Chemical Physics · Physics 2013-07-15 Daniel Kats , Frederick R. Manby

Contributions from high-order (non-perturbative triple and quadruple) cluster amplitudes to the dissociation energies, equilibrium distances, and vibrational constants for the ground states of van der Waals dimers Hg$_2$ and Cn$_2$ are…

Chemical Physics · Physics 2010-01-14 A. N. Petrov , N. S. Mosyagin , A. V. Titov , A. V. Zaitsevskii , E. A. Rykova

We employ \textit{ab initio} methods of quantum chemistry to investigate spin-1/2 fermions interacting via a two-body contact potential in a one-dimensional harmonic trap. The convergence of the total energy with the size of the…

We investigate ground state properties of singly charged chlorine (Cl$^-$) and gold (Au$^-$) negative ions by employing four-component relativistic many-body methods. In our approach, we attach an electron to the respective outer orbitals…

Atomic Physics · Physics 2021-01-08 B. K. Sahoo

Previous studies of $(d,p)$ reactions in three-body (proton, neutron, nuclear core) systems revealed a nontrivial effect of the core excitation: the transfer cross section cannot be factorized into the spectroscopic factor and the…

Nuclear Theory · Physics 2019-03-27 A. Deltuva

Energy levels, wavelengths, magnetic-dipole and electric-quadrupole transition rates between the low-lying states are evaluated for W$^{51+}$ to W$^{54+}$ ions with $3d^n$ (n = 2 to 5) electronic configurations using an approach combining…

Atomic Physics · Physics 2018-01-10 M. S. Safronova , U. I. Safronova , S. G. Porsev , M. G. Kozlov , Yu. Ralchenko

We present a detailed study of the Flambaum-Ginges radiative potential method which enables the accurate inclusion of quantum electrodynamics (QED) radiative corrections in a simple manner in atoms, ions, and molecules over the range…

Atomic Physics · Physics 2016-05-18 J. S. M. Ginges , J. C. Berengut

We investigate different types of collective excitations in a quantum dot containing finite number of electrons at zero magnetic field. To estimate the excitation energies analytically we follow the energy weighted sum-rule approach. We…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Subhasis Sinha
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