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We present a statistical mechanics approximation scheme for the explicit treatment of spacer-mediated configurational correlations among the mesogenic units that form a dimer molecule. The approximation is applied to the description of the…
In the Ginzburg-Landau theory of superfluid $^{3}$He, the free energy is expressed as an expansion of invariants of a complex order parameter. Strong coupling effects, which increase with increasing pressure, are embodied in the set of…
We study a model for water with a tunable intra-molecular interaction $J_\sigma$, using mean field theory and off-lattice Monte Carlo simulations. For all $J_\sigma\geq 0$, the model displays a temperature of maximum density.For a finite…
Molecular dynamics simulations are used to examine the relationship between water-like anomalies and the liquid-liquid critical point in a family of model fluids with multi-Gaussian, core-softened pair interactions. The core-softened pair…
Kinetically constrained models (KCMs) have gained much interest as models that assign the origins of interesting dynamic properties of supercooled liquids to dynamical facilitation mechanisms that have been revealed in many expreiments and…
The statistical-mechanical study of the equilibrium properties of fluids, starting from the knowledge of the interparticle interaction potential, is essential to understand the role that microscopic interaction between individual particles…
Surface tension is a macroscopic manifestation of the cohesion of matter, and its value $\sigma_\infty$ is readily measured for a flat liquid-vapor interface. For interfaces with a small radius of curvature $R$, the surface tension might…
We present a study using molecular dynamics simulations based on the Fermi-Jagla potential model, which is the continuous version of the mono-atomic core-softened Jagla model [J. Y. Abraham, S. V. Buldyrev, and N. Giovambattista, J. Phys.…
We discuss a phenomenological method which allows to determine the singular asymptotic behaviours for a pure fluid at equilibrium, when the liquid-gas critical point and the tangent plane to the characteristic surface of this point are…
The response of inviscid incompressible unbounded fluid subject to a localized external perturbation is studed. The physically relevant hypotheses on the mode coupling mechanisma is justified by renormalization group method. The scaling…
An example of capillary phenomena commonly seen and often studied is a droplet of water hanging in air from a horizontal surface. A thin capillary surface interface between the liquid and gas develops tangential surface tension, which…
Compressing or cooling a fluid typically enhances its static interparticle correlations. However, there are notable exceptions. Isothermal compression can reduce the translational order of fluids that exhibit anomalous waterlike trends in…
In 1966 Pelofsky proposed an empirical linear correlation between the natural logarithm of the surface tension and the reciprocal viscosity, which seems to work adequately for a wide range of fluids. In particular, it has been shown that it…
The floating structure problem describes the interaction between surface water waves and a floating body, generally a boat or a wave energy converter. As shown by Lannes in [18] the equations for the fluid motion can be reduced to a set of…
We compare theoretical and simulation results for static and dynamic properties for a model of particles interacting via a spherically symmetric repulsive ramp potential. The model displays anomalies similar to those found in liquid water,…
Criticality in a fluid of dielectric constant D that exhibits Ising-type behavior is studied as additional electrostatic (i.e., ionic) interactions are turned on. An exploratory perturbative calculation is performed for small ionicity as…
In this paper we study the behavior of an incompressible viscous fluid moving between two very close surfaces also in motion. Using the asymptotic expansion method we formally justify two models, a lubrication model and a shallow water…
In a counter-ion only charged fluid, Coulomb coupling is quantified by a single dimensionless parameter. Yet, the theoretical treatment of moderately to strongly coupled charged fluids is a difficult task, central to the understanding of a…
The evolution of the interface separating a conduit of light, viscous fluid rising buoyantly through a heavy, more viscous, exterior fluid at small Reynolds numbers is governed by the interplay between nonlinearity and dispersion. Previous…
Experimental and modelling study is presented for the effect of a wide range of liquid viscosities on the droplet impact on a smooth solid surface at atmospheric pressure. A non-monotonic variation of threshold between droplet deposition…