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Related papers: Intermolecular Forces and the Glass Transition

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An extension of the relativistic density functional approach to the equation of state for strongly interacting matter is suggested which generalizes a recently developed modified excluded-volume mechanism to the case of temperature and…

Nuclear Theory · Physics 2018-02-16 Stefan Typel , David Blaschke

A model of low-temperature polar liquids is constructed that accounts for configurational heat capacity, entropy, and the effect of a strong electric field on the glass transition. The model is based on Pad{\'e}-truncated perturbation…

Soft Condensed Matter · Physics 2016-08-03 D. V. Matyushov

As in the preceding paper we aim at identifying the effective theory that describes the fluctuations of the local overlap with an equilibrium reference configuration close to a putative thermodynamic glass transition. We focus here on the…

Statistical Mechanics · Physics 2018-11-21 G. Biroli , C. Cammarota , G. Tarjus , M. Tarzia

We study the interplay of superfluidity and glassy ordering of hard core bosons with random, frustrating interactions. This is motivated by bosonic systems such as amorphous supersolid, disordered superconductors with preformed pairs, and…

Disordered Systems and Neural Networks · Physics 2013-05-30 Xiaoquan Yu , Markus Mueller

We compute the temperature-dependent barrier for alpha-relaxations in several liquids, without adjustable parameters, using experimentally determined elastic, structural, and calorimetric data. We employ the random first order…

Disordered Systems and Neural Networks · Physics 2013-10-17 Pyotr Rabochiy , Peter G. Wolynes , Vassiliy Lubchenko

The description of molecular motion by macroscopic hydrodynamics has a long and continuing history. The Stokes-Einstein relation between the diffusion coefficient of a solute and the solvent viscosity predicted using macroscopic continuum…

Disordered Systems and Neural Networks · Physics 2007-05-23 Xiaoyu Xia , Peter G. Wolynes

We give evidence of a clear structural signature of the glass transition, in terms of a static correlation length with the same dependence on the system size which is typical of critical phenomena. Our approach is to introduce an external,…

Statistical Mechanics · Physics 2010-06-25 Majid Mosayebi , Emanuela Del Gado , Patrick Ilg , Hans Christian Ottinger

In this paper and in the companion one we address the problem of identifying the effective theory that describes the statistics of the fluctuations of what is thought to be the relevant order parameter for glassy systems---the overlap field…

Statistical Mechanics · Physics 2018-11-21 G. Biroli , C. Cammarota , G. Tarjus , M. Tarzia

A model glass is considered with one type of fast ($\beta$-type) of processes, and one type of slow processes ($\alpha$-type). On time-scales where the fast ones are in equilibrium, the slow ones have a dynamics that resembles the one of…

Statistical Mechanics · Physics 2009-11-07 Luca Leuzzi , Theo M. Nieuwenhuizen

The routine transformation of a liquid, as it is cooled rapidly, resulting in glass formation, is remarkably complex. A theoretical explanation of the dynamics associated with this process has remained one of the major unsolved problems in…

Disordered Systems and Neural Networks · Physics 2014-12-17 T. R. Kirkpatrick , D. Thirumalai

We propose that glass-forming liquids are intrinsically under the influences of both fluctuating interactions and random fields well-known in the field of spin systems. This is due to the frustration between the isotropic and anisotropic…

Disordered Systems and Neural Networks · Physics 2009-10-30 Hajime Tanaka

A unified treatment of structural relaxation in a deeply supercooled glassy liquid is developed which extends the existing mode coupling theory (MCT) by incorporating the effects of activated events by using the concepts from the random…

Disordered Systems and Neural Networks · Physics 2007-05-23 Sarika Maitra Bhattacharyya , Biman Bagchi , Peter G. Wolynes

The understanding of thermodynamic glass transition has been hindered by the lack of proper models beyond mean-field theories. Here, we propose a three-dimensional lattice glass model on a simple cubic lattice that exhibits the typical…

Statistical Mechanics · Physics 2020-08-07 Yoshihiko Nishikawa , Koji Hukushima

In supercooled liquids, at a temperature between the glass transition temperature Tg and the melting point Tm, thermodynamic properties remain continuous, while dynamic behavior exhibits anomalies. The origin of such thermodynamics-dynamic…

Soft Condensed Matter · Physics 2025-06-17 X. R. Tian , D. M. Zhang , B. Zhang , D. Y. Sun , X. G. Gong

We study the microstructural glass transitions in diblock-copolymer melts using a thermodynamic replica approach. Our approach performs an expansion in terms of the natural smallness parameter -- the inverse of the scaled degree of…

Soft Condensed Matter · Physics 2009-11-11 C. -Z. Zhang , Z. -G. Wang

Experimental nuclear level densities at excitation energies below the neutron threshold follow closely a constant-temperature shape. This dependence is unexpected and poorly understood. In this work, a fundamental explanation of the…

Nuclear Theory · Physics 2015-10-06 L. G. Moretto , A. C. Larsen , F. Giacoppo , M. Guttormsen , S. Siem , A. V. Voinov

A microscopically motivated theory of glassy dynamics based on an underlying random first order transition is developed to explain the magnitude of free energy barriers for glassy relaxation. A variety of empirical correlations embodied in…

Disordered Systems and Neural Networks · Physics 2009-10-31 Xiaoyu Xia , Peter G. Wolynes

The remarkable strength of glasses is examined using the random first order transition theory of the glass transition. The theory predicts that strength depends on elastic modulus but also on the configurational energy frozen in when the…

Disordered Systems and Neural Networks · Physics 2015-06-05 Apiwat Wisitsorasak , Peter G. Wolynes

The Random First Order Transition (RFOT) theory of glasses provides a unified framework for explaining the observed correlations of the kinetic and thermodynamic behaviors of glass-forming liquids having a wide variety of chemical…

Soft Condensed Matter · Physics 2025-07-29 M. H. Brown , P. G. Wolynes

When a liquid is cooled below its melting temperature, if crystallization is avoided, it forms a glass. This phenomenon, called glass transition, is characterized by a marked increase of viscosity, about 14 orders of magnitude, in a narrow…

Disordered Systems and Neural Networks · Physics 2008-08-23 Simone Capaccioli , Giancarlo Ruocco , Francesco Zamponi