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The particle-particle random phase approximation (pp-RPA) has been shown to be capable of describing double, Rydberg, and charge transfer excitations, for which the conventional time-dependent density functional theory (TDDFT) might not be…

Computational Physics · Physics 2017-04-26 Jianfeng Lu , Haizhao Yang

Electronic correlation energies from the random-phase approximation converge slowly with respect to the plane wave basis set size. We study the conditions, under which a short-range local density functional can be used to account for the…

Materials Science · Physics 2023-07-18 Stefan Riemelmoser , Merzuk Kaltak , Georg Kresse

We present an approximation scheme of the nonperturbative renormalization group that preserves the momentum dependence of correlation functions. This approximation scheme can be seen as a simple improvement of the local potential…

Statistical Mechanics · Physics 2018-05-24 Félix Rose , Nicolas Dupuis

The action of the long-range residual force on the expectation value of observables in the nuclear ground states is evaluated by finding optimal values for the coefficients of the canonical transformation which connects the phonon vacuum…

Nuclear Theory · Physics 2015-06-12 S. Mishev

We establish existence and uniqueness of the solution to the Dyson equation for the density-density response function in time-dependent density functional theory (TDDFT) in the random phase approximation (RPA). We show that the poles of the…

Mathematical Physics · Physics 2025-02-04 Thiago Carvalho Corso , Mi-Song Dupuy , Gero Friesecke

We use a continued fraction approximation to calculate the RPA response function of nuclear matter. The convergence of the approximation is assessed by comparing with the numerically exact response function obtained with a typical effective…

Nuclear Theory · Physics 2008-11-26 Jérôme Margueron , J. Navarro , Nguyen Van Giai , P. Schuck

The fully self-consistent Random Phase Approximation (RPA) is constructed within the Unitary Correlation Operator Method (UCOM), which describes the dominant interaction-induced short-range central and tensor correlations by a unitary…

Nuclear Theory · Physics 2009-11-11 N. Paar , P. Papakonstantinou , R. Roth , H. Hergert

Range-separated methods combining a short-range density functional with long-range random phase approximations RPAs with or without exchange response kernel are tested on rare-gas dimers and the S22 benchmark set of weakly interacting…

Chemical Physics · Physics 2014-04-10 Wuming Zhu , Julien Toulouse , Andreas Savin , János G. Angyán

We study the reliability of the constrained random phase approximation (cRPA) method for the calculation of low-energy effective Hamiltonians by considering multi-orbital lattice models with one strongly correlated "target" band and two…

Strongly Correlated Electrons · Physics 2015-07-24 Hiroshi Shinaoka , Matthias Troyer , Philipp Werner

Time dependent quantum systems are the subject of intense inquiry, in mathematics, science, and engineering, particularly at the atomic and molecular levels. In 1984, Runge and Gross introduced time dependent density functional theory…

Analysis of PDEs · Mathematics 2021-02-24 Joseph W. Jerome

We calculate the ground-state expectation value of scalar observables in the matrix formulation of the random phase approximation (RPA). Our expression, derived using the quasiboson approximation, is a straightforward generalization of the…

Nuclear Theory · Physics 2009-11-07 Calvin W. Johnson , Ionel Stetcu

The electron density, its gradient, and the Kohn-Sham orbital kinetic energy density are the local ingredients of a meta-generalized gradient approximation (meta-GGA). We construct a meta-GGA density functional for the exchange-correlation…

Materials Science · Physics 2009-02-20 Jianmin Tao , John P. Perdew , Viktor N. Staroverov , Gustavo E. Scuseria

In approximate Kohn-Sham density-functional theory, self-interaction manifests itself as the dependence of the energy of an orbital on its fractional occupation. This unphysical behavior translates into qualitative and quantitative errors…

Materials Science · Physics 2010-09-28 Ismaila Dabo , Andrea Ferretti , Nicolas Poilvert , Yanli Li , Nicola Marzari , Matteo Cococcioni

The effects of the correlations in the ground state of $^{16}$O on the octupole and dipole excitations are studied using the extended random phase approximation (ERPA) derived from the time-dependent density-matrix theory. It is found that…

Nuclear Theory · Physics 2015-06-15 Mitsuru Tohyama

A microscopic formalism is developed that includes the coupling to two particle-hole phonons in the particle-hole propagator by extending the dressed random phase approximation (DRPA) equation for a finite system. The resulting formalism is…

Nuclear Theory · Physics 2016-09-08 C. Barbieri , W. H. Dickhoff

Density functional calculations on atoms are often used for determining accurate initial guesses as well as generating various types of pseudopotential approximations and efficient atomic-orbital basis sets for polyatomic calculations. To…

Computational Physics · Physics 2023-10-30 Susi Lehtola

Elucidating the impact of strong electronic interactions on the collective excitations of metallic systems has been of longstanding interest, mainly due to the inadequacy of the random phase approximation (RPA) in the strongly correlated…

Strongly Correlated Electrons · Physics 2024-09-25 Loïc Philoxene , Vu Hung Dao , Raymond Frésard

We examine to which extent correlated realistic nucleon-nucleon interactions, derived within the Unitary Correlation Operator Method (UCOM), can describe nuclear collective motion in the framework of first-order random-phase approximation…

Nuclear Theory · Physics 2008-11-26 P. Papakonstantinou , R. Roth , N. Paar

We derive analytical expressions for chemical potentials within the random phase approximation (RPA), equivalently the $GW$ energy functional evaluated using non interacting Green's functions ($G_s$). The chemical potential is obtained…

Chemical Physics · Physics 2026-03-20 Jiachen Li , Weitao Yang

A model is developed, based on the density functional perturbation theory and the inverse Kohn-Sham method, that can be used to improve relativistic nuclear energy density functionals towards an exact but unknown Kohn-Sham…

Nuclear Theory · Physics 2021-04-28 Giacomo Accorto , Tomoya Naito , Haozhao Liang , Tamara Niksic , Dario Vretenar