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We present a multiscale modeling of the infrared optical properties of the rubrene crystal. The results are in very good agreement with the experimental data that point to nonmonotonic features in the optical conductivity spectrum and small…

Materials Science · Physics 2015-01-05 Yuan Li , Yuanping Yi , Veaceslav Coropceanu , Jean-Luc Brédas

We establish a universal theory to understand quasiparticle Hall effects and transverse charge-carrier transport in organic semiconductors. The simulations are applied to organic crystals inspired by rubrene and cover multiple transport…

Materials Science · Physics 2024-08-21 Michel Panhans , Frank Ortmann

We present an overview of recent studies of the charge transport in the field effect transistors on the surface of single crystals of organic low-molecular-weight materials. We first discuss in detail the technological progress that has…

Other Condensed Matter · Physics 2009-11-10 R. W. I. de Boer , M. E. Gershenson , A. F. Morpurgo , V. Podzorov

The novel technique based on air-gap transistor stamps enabled realization of the intrinsic (not dominated by static disorder) transport of the electric-field-induced charge carriers on the surface of rubrene crystals over a wide…

Materials Science · Physics 2009-11-10 V. Podzorov , E. Menard , A. Borissov , V. Kiryukhin , J. A. Rogers , M. E. Gershenson

The field-effect mobility of hole polarons in $\alpha$-sexithiophene, measured in thin film transistors, was shown to be well fitted by Holstein's small polaron theory. Unfortunately, Holstein's formulation is based on an integral that does…

Condensed Matter · Physics 2009-10-30 M. W. Wu , E. M. Conwell

We present a novel theory of charge-carrier mobilities in organic molecular crystals of high purity. Our approach is based on Holstein's original concept of small-polaron bands but generalized with respect to the inclusion of nonlocal…

Soft Condensed Matter · Physics 2007-05-23 K. Hannewald , P. A. Bobbert

The transport properties of organic light-emitting diodes in which the emissive layer is composed of conjugated polymers in the liquid-crystalline phase have been investigated. We have performed simulations of the current transient response…

Condensed Matter · Physics 2009-11-07 S. J. Martin , A. Kambili , A. B. Walker

Single-crystal organic field-effect transistors (OFETs) based on p-channel molecular semiconductors have led to breakthrough carrier mobilities and to the observation of band-like transport. These results represent the limit in our quest…

Materials Science · Physics 2012-02-10 Nikolas A. Minder , Shimpei Ono , Zhihua Chen , Antonio Facchetti , Alberto F. Morpurgo

In materials with strong electron-phonon ($e$-ph) interactions, the electrons carry a phonon cloud during their motion, forming quasiparticles known as polarons. Predicting charge transport and its temperature dependence in the polaron…

Materials Science · Physics 2019-12-03 Jin-Jian Zhou , Marco Bernardi

The photo-induced electron and hole transfer across the semiconductor-dielectric interface in trap dominated p-type organic field-effect transistors (OFETs) has been investigated. It has been observed that the transfer of electrons into the…

Materials Science · Physics 2015-06-25 M. F. Calhoun , C. Hsieh , V. Podzorov

Molecular organic materials offer the promise of novel electronic devices but also present challenges for understanding charge transport in narrow band systems. Low temperature studies elucidate fundamental transport processes. We report…

Materials Science · Physics 2009-11-10 V. Y. Butko , J. C. Lashley , A. P. Ramirez

We report the observation of ambipolar transport in field-effect transistors fabricated on single crystals of Copper- and Iron-Phthalocyanine, using gold as a high work-function metal for the fabrication of source and drain electrodes. In…

Other Condensed Matter · Physics 2009-11-11 R. W. I. de Boer , A. F. Stassen , M. F. Craciun , C. L. Mulder , A. Molinari , S. Rogge , A. F. Morpurgo

Quasicrystals are assumed to be electronically stabilized by a Hume-Rothery type mechanism. This explains most of the peculiar properties of quasicrystals. The stabilization is investigated by electronic transport properties, as they depend…

Materials Science · Physics 2007-05-23 Roland Haberkern

The performance of organic semiconductor devices is linked to highly-ordered nanostructures of self-assembled molecules and polymers. We employ many-body perturbation theory and study the excited states in bulk compolymers. We discover that…

Materials Science · Physics 2020-06-02 Guorong Weng , Vojtěch Vlček

We explore polaronic quantum transport in three-dimensional models of disordered organic crystals with strong coupling between electronic and vibrational degrees of freedom. By studying the polaron dynamics in a static disorder environment,…

Materials Science · Physics 2015-06-03 Frank Ortmann , Stephan Roche

In polarizable materials, electronic charge carriers interact with the surrounding ions, leading to quasiparticle behaviour. The resulting polarons play a central role in many materials properties including electrical transport, optical…

The transport properties of high-performance thin-film transistors (TFT) made with a regio-regular poly(thiophene) semiconductor (PQT-12) are reported. The room-temperature field-effect mobility of the devices varied between 0.004 cm2/V s…

Materials Science · Physics 2009-11-10 A. Salleo , T. W. Chen , A. R. Voelkel , Y. Wu , P. Liu , B. S. Ong , R. A. Street

Research on organic thin-film transistors tends to focus on improvements in device performance, but very little is understood about the ultimate limits of these devices, the microscopic physical mechanisms responsible for their limitations,…

Materials Science · Physics 2013-02-15 Ignacio Gutiérrez Lezama , Alberto F. Morpurgo

Hall effect is detected in organic field-effect transistors, using appropriately shaped rubrene (C42H28) single crystals. It turned out that inverse Hall coefficient, having a positive sign, is close to the amount of electric-field induced…

Materials Science · Physics 2009-11-11 J. Takeya , K. Tsukagoshi , Y. Aoyagi , T. Takenobu , Y. Iwasa

Organic semiconductors based on small conjugated molecules generally behave as insulators when undoped, but the hetero-interfaces of two such materials can show electrical conductivity as large as in a metal. Although charge transfer is…

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