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We show that colloidal molecular crystal states interacting with a periodic substrate, such as an optical trap array, and a rotating external field can undergo a rapid pattern switching in which the orientation of the crystal changes. In…

Soft Condensed Matter · Physics 2015-05-13 C. Reichhardt , C. J. Olson Reichhardt

We report a theoretical study of the optical centrifuge acceleration of an asymmetric top molecule interacting with an electric static field by solving the time-dependent Schr\"odinger equation in the rigid rotor approximation. A detailed…

Chemical Physics · Physics 2018-02-14 Juan J. Omiste

The generation of unidirectional motion has been a long-standing challenge in engineering of molecular motors. Here, a mechanism driving the rotation is presented based on electron current through helical orbitals on a $\pi$-bonded carbon…

Chemical Physics · Physics 2026-03-11 Štěpán Marek , Wulf Wulfhekel , Ferdinand Evers , Richard Korytár

Freezing of charged colloids on square or triangular two-dimensional periodic substrates has been recently shown to realize a rich variety of orientational orders. We propose a theoretical framework to analyze the corresponding structures.…

Statistical Mechanics · Physics 2009-11-10 R. Agra , F. van Wijland , E. Trizac

Using molecular dynamics simulation with an angle-dependent Lennard-Jones potential, we study orientational glass with quadrupolar symmetry in mixtures of elliptic particles and circular impurities in two dimensions. With a mild aspect…

Soft Condensed Matter · Physics 2015-07-24 Kyohei Takae , Akira Onuki

We consider ultracold atoms trapped in a toroidal trap with an azimuthal lattice for utility as a macroscopic simulator of quantum optics phenomena. We examine the dynamics induced by the adiabatic introduction of the lattice that serves to…

Quantum Gases · Physics 2021-02-03 Caelan Brooks , Allison Brattley , Kunal K. Das

A new perspective on how to manipulate molecules by means of very strong laser pulses is emerging with insights from the so-called light-induced potentials, which are the adiabatic potential energy surfaces of molecules severely distorted…

Chemical Physics · Physics 2016-03-03 Bo Y. Chang , Ignacio R. Sola , Seokmin Shin

We report the observation of macroscopic field-free orientation, i.e. more than 73 % of CO molecules pointing in the same direction. This is achieved through an all-optical scheme operating at high particle densities ($>10^{17}$cm$^{-3}$)…

Chemical Physics · Physics 2014-07-09 P. M. Kraus , D. Baykusheva , H. J. Wörner

We study bosonic atoms in small optical lattices by exact diagonalization and observe a striking similarity to the superfluid to Mott insulator transition in macroscopic systems. The momentum distribution, the formation of an energy gap,…

Other Condensed Matter · Physics 2008-04-14 Dirk-Sören Lühmann , Kai Bongs , Klaus Sengstock , Daniela Pfannkuche

Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…

Atomic Physics · Physics 2014-12-01 Rosa Glöckner , Alexander Prehn , Gerhard Rempe , Martin Zeppenfeld

We study the dynamics of a supersonic molecular beam in a low-finesse optical cavity and demonstrate that most molecules in the beam can be decelerated to zero central velocity by the intracavity optical field in a process analogous to…

Atomic Physics · Physics 2014-10-20 Zhihao Lan , Yongkai Zhao , Peter F. Barker , Weiping Lu

Two-dimensional colloidal suspensions exposed to periodic external fields exhibit a variety of molecular crystalline phases. There two or more colloids assemble at lattice sites of potential minima to build new structural entities, referred…

Soft Condensed Matter · Physics 2009-11-11 Andreja Sarlah , Erwin Frey , Thomas Franosch

In solids, crystal field splitting refers to the lifting of atomic orbital degeneracy by the surrounding ions through the static electric field. Similarly, we show that the degenerated $d$ orbitals, which were derived in the harmonic…

Strongly Correlated Electrons · Physics 2018-12-18 Hua Chen , X. C. Xie

We consider the propagation of slow light with an orbital angular momentum (OAM) in a moving atomic medium. We have derived a general equation of motion and applied it in analysing propagation of slow light with an OAM in a rotating medium,…

Other Condensed Matter · Physics 2009-11-13 J. Ruseckas , G. Juzeliunas , P. Ohberg , S. M. Barnett

Rotation of atoms in a lattice is studied using a Hubbard model. It is found that the atoms are still contained in the trap even when the rotation frequency is larger than the trapping frequency. This is very different from the behavior in…

Quantum Physics · Physics 2007-05-23 T. Wang , S. Yelin

A dielectric material's response to light is macroscopically described by electric displacement fields due to polarization and susceptibility, but the atomistic origin is light-cycle-driven motion of electron densities in the restoring…

The strong coupling between intense laser fields and valence electrons in molecules causes a distortion of the potential energy hypersurfaces which determine the motion of nuclei in a molecule and influences possible reaction pathways. The…

Intermolecular correlations in liquid acetonitrile (CH3CN) have been revisited by calculating orientational correlation functions. In the present approach, hydrogen atoms are included, so that a concept applicable for molecules of (nearly)…

Chemical Physics · Physics 2019-06-12 Szilvia Pothoczki , László Pusztai

Ultra-cold RbCs molecules in high-lying vibrational levels of the a$^3\Sigma^+$ ground electronic state are confined in an optical trap. Inelastic collision rates of these molecules with both Rb and Cs atoms are determined for individual…

Roughness and orientational order in thin films of anisotropic particles are investigated using kinetic Monte Carlo simulations on a cubic lattice. Anisotropic next-neighbor interactions between the lattice particles were chosen to mimic…

Soft Condensed Matter · Physics 2022-09-08 Eelco Empting , Nicolas Bader , Martin Oettel