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A new perovskite KOsO3 has been stabilized under high-pressure and high temperature conditions. It is cubic at 500 K (Pm-3m) and undergoes subsequent phase transitions to tetragonal at 320 K (P4/mmm) and rhombohedral (R-3m) at 230 K as…

Ferroelectricity is observed in orthorhombic $HoMnO_3$ and $YMnO_3$ at the magnetic lock-in transitions into an E-type structure or an incommensurate phase with a temperature independent wave vector, respectively. In $HoMnO_3$ the…

Strongly Correlated Electrons · Physics 2011-11-09 B. Lorenz , Y. Q. Wang , C. W. Chu

The complex perovskite Pb2CoTeO6 (PCTO) has been prepared as polycrystalline powders by solid state reaction route, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder…

Materials Science · Physics 2010-12-01 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter

Erbium orthochromite, ErCrO3, is a distorted-perovskite which has antiferromagnetic ground state below 10 K while Cr3+ magnetic moments order at 133 K. The temperature dependence of magnetization is studied across different magnetic phases…

Strongly Correlated Electrons · Physics 2015-01-29 Brajesh Tiwari , M Krishna Surendra , M. S. Ramachandra Rao

The crystal and magnetic structures of the orthorhombic e-Fe2O3 have been studied by simultaneous Rietveld refinement of X-ray and neutron powder diffraction data in combination with Mossbauer spectroscopy, as well as magnetisation and heat…

The ground state properties of the pure perovskite compounds PrMnO$_3$ and NdMnO$_3$ were investigated by magnetization, magnetic AC susceptibility and specific heat measurements. A strongly anisotropic behavior has been detected for…

Condensed Matter · Physics 2007-05-23 J. Hemberger , M. Brando , R. Wehn , V. Yu. Ivanov , A. A. Mukhin , A. M. Balbashov , A. Loidl

We studied the magnetic properties of bulk LaCrO3; a GdFeO3-type distorted perovskite, with a predominant antiferromagnetic phase transition at ~ 290 K. The bulk LaCrO3 exhibits intrinsic weak ferromagnetism at room temperature, which may…

Strongly Correlated Electrons · Physics 2014-03-18 Brajesh Tiwari , A. Dixit , R Naik , G. Lawes , M. S. Ramachandra Rao

Structural behaviour of PbMn$_{7}$O$_{12}$ has been studied by high resolution synchrotron X-ray powder diffraction. This material belongs to a family of quadruple perovskite manganites that exhibit an incommensurate structural modulation…

Strongly Correlated Electrons · Physics 2021-05-05 R. D. Johnson , D. D. Khalyavin , P. Manuel , A. A. Belik

Detailed structural measurements were conducted on a new perovskite, ScMnO3, and on orthorhombic LuMnO3. Complementary density functional theory (DFT) calculations were carried out, and predict that ScMnO3 possesses E-phase magnetic order…

Strongly Correlated Electrons · Physics 2015-06-19 T. Yu , T. A. Tyson , H. Y. Chen , A. M. M. Abeykoon , Y. -S. Chen , K. H. Ahn

KCrF3 represents another prototypical orbital-ordered perovskite, where Cr2+ possesses the same electronic configuration of 3d4 as that of strongly Jahn-Teller distorted Mn3+ in many CMR manganites. The crystal and magnetic structures of…

Strongly Correlated Electrons · Physics 2013-09-30 Y. Xiao , Y. Su , H. -F. Li , C. M. N. Kumar , R. Mittal , J. Persson , A. Senyshyn , K. Gross , Th. Brueckel

A complex magnetic order of the multiferroic compound Co3TeO6 has been revealed by neutron powder diffraction studies on ceramics and crushed single crystals. The compound adopts a monoclinic structure (s.g. C2/c) in the studied temperature…

Materials Science · Physics 2011-11-28 S. A. Ivanov , R. Tellgren , C. Ritter , P. Nordblad , R. Mathieu , G. Andre , N. V. Golubko , E. D. Politova , M. Weil

The magnetic susceptibility, crystal and magnetic structures, and electronic structure of double perovskite Sr2ScOsO6 are reported. Using both neutron and x-ray powder diffraction we find that the crystal structure is monoclinic P21/n from…

Strongly Correlated Electrons · Physics 2015-04-06 A. E. Taylor , R. Morrow , D. J. Singh , S. Calder , M. D. Lumsden , P. M. Woodward , A. D. Christianson

We use ab initio electronic structure calculations in combination with Monte Carlo simulations to investigate the magnetic and ferroelectric properties of bulk orthorhombic HoMnO$_3$ and ErMnO$_3$. Our goals are to explain the…

Materials Science · Physics 2018-12-12 Natalya S. Fedorova , Amadé Bortis , Christoph Findler , Nicola A. Spaldin

We use resonant and non-resonant X-ray diffraction measurements in combination with first-principles electronic structure calculations and Monte Carlo simulations to study the relationship between crystal structure and multiferroic orders…

We have studied the crystal and magnetic structures of the magnetoelectric materials RMn2O5 (R = Tb, Ho, Dy) using neutron diffraction as a function of temperature. All three materials display incommensurate antiferromagnetic ordering below…

Strongly Correlated Electrons · Physics 2009-11-11 G. R. Blake , L. C. Chapon , P. G. Radaelli , S. Park , N. Hur , S-W. Cheong , J. Rodriguez-Carvajal

The rare-earth perovskite TbScO$_3$ has been widely used as a substrate for the growth of epitaxial ferroelectric and multiferroic thin films, while its detailed low-temperature magnetic properties were rarely reported. In this paper, we…

Magnetic structures of metastable perovskites ScCrO3, InCrO3 and TlCrO3, stabilized under high-pressure and high-temperature conditions, have been studied by neutron powder diffraction. Similar to the other orthochromites LnCrO3…

Strongly Correlated Electrons · Physics 2021-01-13 Lei Ding , Pascal Manuel , Dmitry D. Khalyavin , Fabio Orlandi , Yu Kumagai , Fumiyasu Oba , Wei Yi , Alexei A. Belik

In the orthorhombic manganites o-RMnO3, where R is a heavy rare earth (R = Gd-Yb), the Mn3+ sublattice is known to undergo two magnetic transitions. The low temperature phase has an antiferromagnetic structure (collinear or elliptical),…

Strongly Correlated Electrons · Physics 2018-01-17 Mathieu Duttine , Alain Wattiaux , Felix Balima , Claudia Decorse , Hicham Moutaabbid , Pierre Bonville

The structural phase transformation in the La2/3Ba1/3MnO3 perovskite manganite was studied by ultrasound, neutron diffraction and electron microscopy techniques. Minima of the velocity and maxima of the decrement of the ultrasound point out…

Materials Science · Physics 2007-05-23 A. B. Beznosov , E. L. Fertman , P. P. Pal-Val , L. N. Pal-Val , C. Ritter , M. Rossell , D. D. Khalyavin

We performed magnetic susceptibility and neutron powder diffraction experiments on the ternary compound Pr5Ru3Al2. It belongs to the noncentrosymmetric and nonmirrorsymmetric cubic I213 space group. The previously reported ferromagnetic…

Strongly Correlated Electrons · Physics 2016-06-09 Koya Makino , Daisuke Okuyama , Maxim Avdeev , Taku J Sato
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