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The controlled creation and manipulation of defects in 2D materials has become increasingly popular as a means to design and tune new material functionalities. However, defect characterization by direct atomic imaging is often severely…

Materials Science · Physics 2023-12-06 Dana O. Byrne , Jim Ciston , Frances I. Allen

The use of simple, fast and economic experimental tools to characterize low-dimensional materials is an important step in the process of democratizing the use of such materials in laboratories around the world. Raman spectroscopy has arisen…

A novel form of amorphous carbon with sp-sp2 hybridization has been recently produced by supersonic cluster beam deposition showing the presence in the film of both polyynic and cumulenic species [L. Ravagnan et al. Phys. Rev. Lett. 98,…

Graphene is the two-dimensional (2d) building block for carbon allotropes of every other dimensionality. It can be stacked into 3d graphite, rolled into 1d nanotubes, or wrapped into 0d fullerenes. Its recent discovery in free state has…

Constraining the complex refractive indices, optical properties and size of brown carbon (BrC) aerosols is a vital endeavor for improving climate models and satellite retrieval algorithms. Smoldering wildfires are the largest source of…

Graphene is an atomically thin two-dimensional material demonstrating strong optical nonlinearities including harmonics generation, four wave mixing, Kerr and other nonlinear effects. In this paper we theoretically analyze the optical…

Mesoscale and Nanoscale Physics · Physics 2018-04-26 N. A. Savostianova , S. A. Mikhailov

Thanks to high sensitivity and angular resolution and broad spectral coverage, SPICA will offer a unique opportunity to better characterize the nature of polycyclic aromatic hydrocarbons (PAHs) and very small grains (VSGs), to better use…

Astrophysics of Galaxies · Physics 2015-05-14 O. Berne , C. Joblin , G. Mulas , A. G. G. M. Tielens , J. R. Goicoechea

The theoretical framework, which is built from the first-principles results, is successfully developed for investigating emergent two-dimensional (2D) materials, as it is clearly illustrated by carbon substitution in silicene. Computer…

Computational Physics · Physics 2019-12-03 Hai-Duong Pham , Shih-Yang Lin , Godfrey Gumbs , Nguyen Duy Khanh , Ming-Fa Lin

The electronic properties of two-dimensional (2D) materials depend sensitively on the underlying atomic arrangement down to the monolayer level. Here we present a novel strategy for the determination of the band gap and complex dielectric…

Graphdiynes (GDYs) as two-dimensional carbon structures based on sp2 hybridized aromatic rings connected by sp-hybridized acetylenic linear links are gathering an increasing popularity, both for their peculiar properties and for the…

Materials Science · Physics 2021-08-03 Patrick Serafini , Alberto Milani , Matteo Tommasini , Carlo E. Bottani , Carlo S. Casari

Molecular contamination of a grazing incidence collector for extreme ultraviolet (EUV) lithography was experimentally studied. A carbon film was found to have grown under irradiation from a pulsed tin plasma discharge. Our studies show that…

Materials Science · Physics 2015-06-18 A Dolgov , D Lopaev , C J Lee , E Zoethout , V. Medvedev , O Yakushev , F Bijkerk

Two-dimensional (2D) crystals, such as graphene and transition metal dichalcogenides (TMDs), present a collection of unique and complementary optoelectronic properties. Assembling different 2D materials in vertical heterostructures enables…

Raman imaging on the edges of single layer micromechanical cleavage graphene (MCG) was carried out. The intensity of disorder-induced Raman feature (D band at ~1350 cm-1) was found to be correlated to the edge chirality: it is stronger at…

Materials Science · Physics 2009-11-13 YuMeng You , ZhenHua Ni , Ting Yu , ZeXiang Shen

Photoelectron diffraction (PED) is a powerful and essential experimental technique for resolving the structure of surfaces with sub-angstrom resolution. In the high energy regime, researchers in angle-resolved photoemission spectroscopy…

The double-resonance (DR) Raman process is a signature of all sp2 carbon material and provide fundamental information of the electronic structure and phonon dispersion in graphene, carbon nanotubes and different graphite-type materials. We…

Materials Science · Physics 2020-10-27 Sergio L. L. M. Ramos , Marcos A. Pimenta , Ana Champi

Rhombohedral graphite (RG) shows strong correlations in its topological flat band and is pivotal for exploring emergent, correlated electronic phenomena. One key advantage is the enhancement of electronic interactions with the increase in…

The physical processes occurring in the presence of disorder: point defects, grain boundaries, etc. may have detrimental effects on the electronic properties of graphene. Here we present an approach to reveal the grain structure of graphene…

Oxygen molecules are found to exhibit non-negligible reactivity with graphene under strong light irradiation in the presence of water. The reaction is triggered by the laser Raman spectroscopy measurement itself, and the D band (ca. 1340…

Materials Science · Physics 2013-11-15 Nobuhiko Mitoma , Ryo Nouchi , Katsumi Tanigaki

We study how the substrate temperature influences the structural properties of carbon films deposited by PVD (physical vapor deposition) techniques. We adapted a heating system inside the deposition chamber, with temperatures up to…

The optical properties of dielectric plates coated with gapped graphene are investigated on the basis of first principles of quantum electrodynamics. The reflection coefficients and reflectivities of graphene-coated plates are expressed in…

Materials Science · Physics 2017-01-27 G. L. Klimchitskaya , V. M. Mostepanenko