English
Related papers

Related papers: Multipolar expansion of the electrostatic interact…

200 papers

Using a carefully justified development of Debye-Huckel theory for highly asymmetric electrolytes, one finds that a region of expanded phase instability, or miscibility gap, can appear for charge-stabilised colloidal suspensions at high…

Statistical Mechanics · Physics 2007-05-23 Patrick B. Warren

Electrostatic interactions play an important role in numerous self-assembly phenomena, including colloidal aggregation. Although colloids typically have a dielectric constant that differs from the surrounding solvent, the effective…

Soft Condensed Matter · Physics 2018-09-17 Kipton Barros , Erik Luijten

Long-ranged electrostatic interactions in electrolytes modify their contact angles on charged substrates in a scale and geometry dependent manner. For angles measured at scales smaller than the typical Debye screening length, the wetting…

Soft Condensed Matter · Physics 2009-11-07 Tom Chou

We evaluate the electrostatic interaction energy between two surfaces, one flat and the other slightly curved, in terms of the two-point autocorrelation functions for patch potentials on each one of them, and of a single function $\psi$…

High Energy Physics - Theory · Physics 2015-06-17 C. D. Fosco , F. C. Lombardo , F. D. Mazzitelli

We propose a mean-field analytical model to account for the observed asymmetry in the ability to form long-range attraction by the negatively charged colloidal particles and not their equivalently charged positive counterpart. We conjecture…

Soft Condensed Matter · Physics 2009-11-13 William Kung , Monica Olvera de la Cruz

Optical microscopy and multi-particle tracking are used to investigate the cross-correlated diffusion of quasi two-dimensional (2D) colloidal particles near an oil-water interface. It is shown that the effect of the interface on correlated…

Soft Condensed Matter · Physics 2015-06-15 Wei Zhang , Song Chen , Na Li , Jiazheng Zhang , Wei Chen

We apply a phenomenological theory of polar liquids to calculate the interaction energy between two plane surfaces at nm-distances. We show that depending on the properties of the surface-liquid interfaces, the interacting surfaces induce…

Soft Condensed Matter · Physics 2013-04-24 P. O. Fedichev , L. I. Menshikov

The contact value of the charge profile for nonsymmetrical electrolytes is presented as the sum of three contributions. One of them is the normal component of the Maxwell electrostatic stress tensor. The second one is the surface…

Statistical Mechanics · Physics 2009-11-13 M. Holovko , D. di Caprio

We study the electric-field induced capillary interaction of charged particles at a polar interface. The algebraic tails of the electrostatic pressure of each charge results in a deformation of the interface $u\sim \rho ^{-4}$. The…

Soft Condensed Matter · Physics 2014-02-10 Lionel Foret , Alois Würger

Interaction between two interpenetrating spherically symmetric charge distributions has been calculated. Limited range terms appear in addition to the Coulomb potential. Its strength increases and range decreases with reducing sizes of the…

Nuclear Theory · Physics 2009-03-20 A. Mukherji

The equilibrium phase behavior of a binary mixture of charged colloids and neutral, non-adsorbing polymers is studied within free-volume theory. A model mixture of charged hard-sphere macroions and ideal, coarse-grained, effective-sphere…

Soft Condensed Matter · Physics 2009-11-11 Alan R. Denton , Matthias Schmidt

We study a two-dimensional model of an active isotropic colloid whose propulsion is linked to the interactions between solute particles of the bath. The colloid catalyzes a chemical reaction in its vicinity, that yields a local phase…

Soft Condensed Matter · Physics 2022-12-07 Jeanne Decayeux , Marie Jardat , Pierre Illien , Vincent Dahirel

We studied the van der Waals interactions of two finite, solid, cylindrical rods at arbitrary angle and position with respect to each other. An analytic interpolative formula for the interaction potential energy is constructed, based on…

Soft Condensed Matter · Physics 2018-10-03 Jack A. Logan , Alexei V. Tkachenko

We report a numerical investigation of two colloids immersed in a critical solvent, with the aim of quantifying the effective colloid-colloid interaction potential. By turning on an attraction between the colloid and the solvent particles…

Soft Condensed Matter · Physics 2012-09-12 Nicoletta Gnan , Emanuela Zaccarelli , Francesco Sciortino

This article reviews the recent theoretical and experimental advances in the study of ultracold gases made of bosonic particles interacting via the long-range, anisotropic dipole-dipole interaction, in addition to the short-range and…

Quantum Gases · Physics 2009-11-20 T Lahaye , C Menotti , L Santos , M Lewenstein , T Pfau

The new free energy functional that describes general elastic interaction between colloidal particles and nematic liquid crystal has been proposed. It generalizes results of the paper \cite{lupe} on the case of arbitrary orientation of…

Soft Condensed Matter · Physics 2009-07-30 S. B. Chernyshuk , B. I. Lev

Porous mesophases, where well-defined particle-depleted 'void' spaces are present within a particle-rich background fluid, can be self-assembled from colloidal particles interacting via isotropic pair interactions with competing attractions…

Soft Condensed Matter · Physics 2017-02-16 Beth A. Lindquist , Sayantan Dutta , Ryan B. Jadrich , Delia J. Milliron , Thomas M. Truskett

We present a theory of effective electrostatic interactions in polydisperse suspensions of charged macroions, generalizing to mixtures a theory previously developed for monodisperse suspensions. Combining linear response theory with a…

Soft Condensed Matter · Physics 2013-08-20 Jun Kyung Chung , Alan R. Denton

At model water--vapor and water--solid interfaces, molecular ordering leads to charge oscillations and, thereby, to a spatially varying electrostatic potential. Atomistic simulations indicate that such ordering leads to an electric…

Chemical Physics · Physics 2025-12-12 David Fertig , Adrian L. Usler , Mathijs Janssen

Interparticle interactions and bulk properties of colloidal suspensions can be substantially modified by addition of nanoparticles. Extreme asymmetries in size and charge between colloidal particles and nanoparticles present severe…

Soft Condensed Matter · Physics 2018-01-03 Alan R. Denton