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Related papers: Comments on Violations of the Second Law

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Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Second law of thermodynamics is applied to a few electronic processes. It is seen that the second law of thermodynamics holds good for all except one mentioned here. The classical approach, based on exact equivalence of emission and…

General Physics · Physics 2007-05-23 R. C. Gupta , Ruchi Gupta , Sanjay Gupta

Claims of exceptions to the second law of thermodynamics are generally met with extreme skepticism that is quite reasonable given the great confidence placed in the second law. But what specifically is the basis for that confidence? The…

Statistical Mechanics · Physics 2009-11-07 Todd L. Duncan

Fluctuation theorems specify the non-zero probability to observe negative entropy production, contrary to a naive expectation from the second law of thermodynamics. For closed particle trajectories in a fluid, Stokes theorem can be used to…

Statistical Mechanics · Physics 2022-07-06 Benoît Mahault , Evelyn Tang , Ramin Golestanian

We establish the fluctuation theorem in the presence of information exchange between a nonequilibrium system and other degrees of freedom such as an observer and a feedback controller, where the amount of information exchange is added to…

Statistical Mechanics · Physics 2015-06-05 Takahiro Sagawa , Masahito Ueda

The second law of thermodynamics imposes an increase of macroscopic entropy with time in an isolated system. Microscopically, however, the entropy production can be negative for a single, microscopic realization of a thermodynamic process.…

Solar and Stellar Astrophysics · Physics 2018-12-07 Andrei Gorobets , Svetlana Berdyugina

Heat, work and entropy production: the statistical distribution of such quantities are constrained by the fluctuation theorems (FT), which reveal crucial properties about the nature of non-equilibrium dynamics. In this paper we report…

Quantum Physics · Physics 2021-10-15 K. Khan , J. Sales Araújo , W. F. Magalhães , G. H. Aguilar , B. de Lima Bernardo

The fluctuation theorem is the fundamental equality in nonequilibrium thermodynamics that is used to derive many important thermodynamic relations, such as the second law of thermodynamics and the Jarzynski equality. Recently, the…

Statistical Mechanics · Physics 2019-09-16 Yoshihiko Hasegawa , Tan Van Vu

The Trajectory Class Fluctuation Theorem (TCFT) substantially strengthens the Second Law of Thermodynamics -- that, in point of fact, can be a rather weak bound on resource fluxes. Practically, it improves empirical estimates of free…

Statistical Mechanics · Physics 2024-04-30 Gregory Wimsatt , Alexander B. Boyd , James P. Crutchfield

The Integral Fluctuation Theorem for entropy production (IFT) is among the few equalities that are known to be valid for physical systems arbitrarily driven far from equilibrium. Microscopically, it can be understood as an inherent symmetry…

Statistical Mechanics · Physics 2023-06-21 Francesco Coghi , Lorenzo Buffoni , Stefano Gherardini

Evidence implies that basic laws of thermodynamics must be tested by experiments. In this paper, an experiment is designed to measure the entropy of a system with at least one known (measurable) equation of state, especially the gas…

General Physics · Physics 2007-05-23 Bin Zhou

Turbulent flows are out-of-equilibrium because the energy supply at large scales and its dissipation by viscosity at small scales create a net transfer of energy among all scales. Here, the energy cascade is approximated by a combined…

Fluid Dynamics · Physics 2021-01-11 Amilcare Porporato , Milad Hooshyar , Andrew D Bragg , Gabriel Katul

Statistical mechanics descriptions of the second law of thermodynamics generally imply point-like particles driven by a dissipative overall mechanism for their simultaneous time-evolution. As the number of involved particles grows larger,…

General Physics · Physics 2016-02-16 Hans R. Moser

Nonequilibrium thermodynamics of a general second-order stochastic system is investigated. We prove that at steady state, under inversion of velocities, the condition of time-reversibility over the phase space is equivalent to the…

Statistical Mechanics · Physics 2015-10-28 Hao Ge

We prove that, in general, the first law of black hole thermodynamics, $\delta Q=T\delta S$, is violated in $f(T)$ gravity. As a result, it is possible that there exists entropy production, which implies that the black hole thermodynamics…

High Energy Physics - Theory · Physics 2015-05-28 Rong-Xin Miao , Miao Li , Yan-Gang Miao

In textbooks on statistical mechanics, one finds often arguments based on classical mechanics, phase space and ergodicity in order to justify the second law of thermodynamics. However, the basic equations of motion of classical mechanics…

Statistical Mechanics · Physics 2014-08-28 Barbara Drossel

We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…

Statistical Mechanics · Physics 2017-09-13 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

The second law of thermodynamics states that entropy production cannot be negative. Recent developments concerning uncertainty relations in stochastic thermodynamics, such as thermodynamic uncertainty relations and speed limits, have…

Statistical Mechanics · Physics 2023-10-09 Tomohiro Nishiyama , Yoshihiko Hasegawa

The second law of thermodynamics states that for a thermally isolated system entropy never decreases. Most physical processes we observe in nature involve variations of macroscopic quantities over spatial and temporal scales much larger…

High Energy Physics - Theory · Physics 2017-02-20 Paolo Glorioso , Hong Liu

Thermodynamics is usually formulated on the presumption that the observer has complete information about the system he/she deals with: no parasitic current, exact evaluation of the forces that drive the system. For example, the acclaimed…

Statistical Mechanics · Physics 2017-12-15 Matteo Polettini , Massimiliano Esposito