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We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as…

Quantum Physics · Physics 2024-09-24 Felipe Isaule , Robert Bennett , Jörg B. Götte

Based on a simplest molecular orbital theory of H$_{2}^{+}$, a three-parameter model potential function is proposed to describe ground-state diatomic systems with closed-shell and/or S-type valence-shell constituents over a significantly…

Chemical Physics · Physics 2009-11-11 Rui-Hua Xie , Jiangbin Gong

In this study, we obtain the approximate analytical solutions of the radial Schrodinger equation for the New Generalized Morse-Like Potential in arbitrary dimensions by using the Nikiforov Uvarov Method. Energy eigenvalues and corresponding…

Quantum Physics · Physics 2020-12-07 C. M. Ekpo , Ephraim P. Inyang , P. O. Okoi , T. O. Magu , E. P. Agbo , K O Okorie , Etido P. Inyang

We obtain the exact energy spectrum of nonuniform mass particles for a collection of Hamiltonians in a three-dimensional approach to a quantum dot. By considering a set of generalized Schr\"odinger equations with different orderings between…

Mesoscale and Nanoscale Physics · Physics 2023-11-27 R. M. Lima , H. R. Christiansen

Accurate low and high-lying bound states of Tietz-Hua oscillator potential are presented. The radial Schr\"odinger equation is solved efficiently by means of the generalized pseudospectral method that enables optimal spatial discretization.…

Chemical Physics · Physics 2014-09-10 Amlan K. Roy

Using a suitable Laguerre basis set that ensures a tridiagonal matrix representation of the reference Hamiltonian, we were able to evaluate in closed form the matrix representation of the associated Hamiltonian for few exactly solvable 2D…

Quantum Physics · Physics 2011-10-06 S. M. Al-Marzoug , H. Bahlouli , M. S. Abdelmonem

The analytic solutions of the spatially-dependent mass Schrodinger equation of diatomic molecules with the centrifugal term l(l+1)/r2 for the generalized q-deformed Morse potential are obtained approximately by means of a parametric…

Quantum Physics · Physics 2015-05-13 Sameer Ikhdair

We present a new computational method for the determination of energy levels in four-particle systems like H$_2$, HD, and HeH$^+$ using explicitly correlated exponential basis functions and analytic integration formulas. In solving the…

Chemical Physics · Physics 2018-02-14 Krzysztof Pachucki , Jacek Komasa

We develop a computationally and numerically efficient method to calculate binding energies and corresponding wave functions of quantum mechanical three-body problems in low dimensions. Our approach exploits the tensor structure of the…

Computational Physics · Physics 2022-03-04 Jonas Thies , Moritz Travis Hof , Matthias Zimmermann , Maxim Efremov

We study the translational motions of homonuclear diatomic molecules prepared in their ${}^3\Sigma$ electronic states, deeply bound vibrational states, and rotational states of well-defined parity. The trapping potential arises due to the…

Mathematical Physics · Physics 2026-03-05 Yurij Yaremko , Maria Przybylska , Andrzej J. Maciejewski

While dealing in [1] with the supersymmetry of a tridiagonal Hamiltonian H, we have proved that its partner Hamiltonian H(+) also have a tridiagonal matrix representation in the same basis and that the polynomials associated with the…

Mathematical Physics · Physics 2017-04-05 Hashim A Yamani , Zouhair Mouayn

Using the effective rotational Hamiltonian method, we have conducted an analysis of the D218O ground and the first excited vibration state rotational energy levels. The analysis was based on the effective Hamiltonians represented in several…

Chemical Physics · Physics 2021-01-18 I. A. Vasilenko , O. V. Naumenko , E. R. Polovtseva , A. D. Bykov

In the present article, we introduce a model to investigate the energy spectrum of a relativistic rotor by considering the Klein-Gordon Hamiltonian. Rotational spectral lines are a signature of homonuclear and heteronuclear systems and play…

Quantum Physics · Physics 2007-05-23 Nagalakshmi A. Rao , B. A. Kagali

Using the technique of tridiagonal representation approach; for the first time, we extend this method to study quantum systems with literally perturbed Hamiltonians. Specifically, we consider a quantum system in a 3D spherical oscillator…

Quantum Physics · Physics 2022-12-12 Tunde Joseph Taiwo

A procedure for calculation of rotation-vibration states of medium sized molecules is presented. It combines the advantages of variational calculations and perturbation theory. The vibrational problem is solved by diagonalizing a…

Chemical Physics · Physics 2015-04-13 A. I. Pavlyuchko , S. N. Yurchenko , Jonathan Tennyson

In this paper, hyperspherical three-body model formalism has been applied for the calculation energies of the low-lying bound $^{1,3}$S (L=0)-states of neutral helium and helium like Coulombic three-body systems having nuclear charge (Z) in…

Atomic Physics · Physics 2015-11-19 Md. Abdul Khan

A very efficient large-order perturbation theory is formulated for the nuclear motion of a linear triatomic molecule. To demonstrate the method, all of the experimentally observed rotational energies, with values of $J$ almost up to 100,…

Chemical Physics · Physics 2009-10-30 Andrei A. Suvernev , David Z. Goodson

In this work, the bound state problem of some diatomic molecules in the Tietz-Wei potential with varying shapes is correctly solved by means of path integrals. Explicit path integration leads to the radial Green's function in closed form…

Quantum Physics · Physics 2019-12-02 A. Khodja , A. Kadja , F. Benamira , L. Guechi

We present a general mathematical procedure to handle interactions described by a Morse potential in the presence of a strong harmonic excitation. We account for permanent and field-induced terms and their gradients in the dipole moment…

Atomic Physics · Physics 2023-07-19 Sándor Varró , Szabolcs Hack , Gábor Paragi , Péter Földi , Imre F. Barna , Attila Czirják

The approximate bound state solutions of the Schrodinger equation with shifted Deng-Fan potential was obtained via proper quantization rule. The energy spectra for the homogenous diatomic molecules (H2, I2); the heterogeneous diatomic…

Quantum Physics · Physics 2018-06-04 O. J. Oluwadare , K. J. Oyewumi