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We have studied the thermodynamics of isolated homopolymer chains of varying stiffness using a lattice model. A complex phase behaviour is found; phases include chain-folded `crystalline' structures, the disordered globule and the coil. It…

Soft Condensed Matter · Physics 2008-02-03 Jonathan Doye , Richard Sear , Daan Frenkel

In this paper we study a model describing a copolymer in a micro-emulsion. The copolymer consists of a random concatenation of hydrophobic and hydrophilic monomers, the micro-emulsion consists of large blocks of oil and water arranged in a…

Probability · Mathematics 2016-10-03 Frank den Hollander , Nicolas Pétrélis

Molecular Dynamic and Monte Carlo studies are performed in a family of core-softened (CS) potential, composed by two length scales: a repulsive shoulder at short distances and the another a variable scale, that can be repulsive or strongly…

Soft Condensed Matter · Physics 2017-01-04 L. Pinheiro , A. P. Furlan , L. B. Krott , A. Diehl , M. C. Barbosa

Poly-N-isopropylacrylamide (PNIPAM) is a thermoresponsive polymer, an essential building block of a large family of soft smart materials. In neat water it undergoes upon heating at $\approx$305K a phase transition from swollen to collapsed…

Chemical Physics · Physics 2018-06-15 Vladimir Palivec , Denis Zadrazil , Jan Heyda

A polymer folding model on the square lattice is constructed with attractive contact interactions of strength 1/c^2, 0<c<1. The corresponding model on a dynamical random lattice, with freely fluctuating co-ordination number at each vertex,…

Condensed Matter · Physics 2016-08-31 S. Dalley

We present a Monte Carlo simulation study of the phase behavior of two-dimensional classical particles repelling each other through an isotropic Gaussian potential. As in the analogous three-dimensional case, a reentrant-melting transition…

Soft Condensed Matter · Physics 2011-10-26 S. Prestipino , F. Saija , P. V. Giaquinta

Processes on different length scales affect the dynamics of chain molecules. In this work, we focus on structures on the scale of a monomer and investigate polyolefins, i.e. hydrocarbon chains with different small scale architectures. We…

Soft Condensed Matter · Physics 2009-10-31 Jutta Luettmer-Strathmann

Investigating thermodynamic properties of liquid-solid transitions of flexible homopolymers with elastic bonds by means of multicanonical Monte Carlo simulations, we find crystalline conformations that resemble ground-state structures of…

Soft Condensed Matter · Physics 2010-02-11 Stefan Schnabel , Thomas Vogel , Michael Bachmann , Wolfhard Janke

The time-dependent response of polystyrene and poly(methyl methacrylate) is studied in isothermal long-term shear creep tests at small strains and various temperatures in the vicinity of the glass transition point. A micromechanical model…

Soft Condensed Matter · Physics 2007-05-23 Aleksey D. Drozdov , Joachim Kaschta

There are strong evidences that the melting in two dimensions depends crucially on the form and range of the interaction potentials between particles. We study with Monte Carlo simulations the phase diagram and the melting of a monolayer of…

Statistical Mechanics · Physics 2013-01-09 Martial Mazars

By means of Metropolis Monte Carlo simulations of a coarse-grained model for flexible polymers, we investigate how the integrated autocorrelation times of different energetic and structural quantities depend on the temperature. We show…

Computational Physics · Physics 2014-08-19 Kai Qi , Michael Bachmann

This paper reviews recent Monte Carlo simulation studies of the glassy behavior in thin polymer films. The simulations employ a version of the bond-fluctuation lattice model, in which the glass transition is driven by the competition…

Soft Condensed Matter · Physics 2007-05-23 C. Mischler , J. Baschnagel , K. Binder

In this paper the percolation of monomers on a square lattice is studied as the particles interact with either repulsive or attractive energies. By means of a finite-size scaling analysis, the critical exponents and the scaling collapsing…

Statistical Mechanics · Physics 2009-11-13 M. Cecilia Gimenez , Felix Nieto , Antonio J. Ramirez-Pastor

The coil-globule transition has been studied for A-B copolymer chains both by means of lattice Monte Carlo simulations using bond fluctuation algorithm and by a numerical self-consistent field method. Copolymer chains of fixed length with A…

A directed polymer is considered on a flat substrate with randomly located parallel ridges. It prefers to lie inside wide regions between the ridges. When the transversel width $W=\exp(\lambda L^{1/3})$ is exponential in the longitudinal…

Disordered Systems and Neural Networks · Physics 2009-10-30 Th. M. Nieuwenhuizen

We study numerically a monodisperse model of interacting classical particles predicted to exhibit a static liquid-glass transition. Using a dynamical Monte Carlo method we show that the model does not freeze into a glassy phase at low…

Disordered Systems and Neural Networks · Physics 2011-11-10 Charlotte Gils , Helmut G. Katzgraber , Matthias Troyer

We consider a system of clusters made of elementary building blocks, monomers, and evolving via collisions between diffusing monomers and immobile composite clusters. In our model, the cluster-monomer collision can lead to the attachment of…

Statistical Mechanics · Physics 2017-10-25 P. L. Krapivsky , W. Otieno , N. V. Brilliantov

The coil-globule transition of an energy polydisperse chain, a model heteropolymer system where the number of monomer species is as large as the total number of monomers, is studied by means of computer simulations. In this study, we…

Soft Condensed Matter · Physics 2022-07-21 Thoudam Vilip Singh , Lenin S. Shagolsem

We investigate the lattice Coulomb glass model in three dimensions via Monte Carlo simulations. No evidence for an equilibrium glass phase is found down to very low temperatures, although the correlation length increases rapidly near T=0. A…

Disordered Systems and Neural Networks · Physics 2009-07-27 Martin Goethe , Matteo Palassini

We study the temperature dependence of static and dynamic responses of Coulomb interacting particles in two-dimensional traps across the thermal crossover from an amorphous solid- to liquid-like behaviors. While static correlations, that…

Disordered Systems and Neural Networks · Physics 2017-10-11 Biswarup Ash , J. Chakrabarti , Amit Ghosal
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