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Although not as wide, and popular, as that of quantum mechanics, the investigation of fundamental aspects of statistical mechanics constitutes an important research field in the building of modern physics. Besides the interest for itself,…

Statistical Mechanics · Physics 2025-05-23 Marco Baldovin , Giacomo Gradenigo , Angelo Vulpiani , Nino Zanghì

In systems with long-range interactions, since energy is a non-additive quantity, ensemble inequivalence can arise: it is possible that different statistical ensembles lead to different equilibrium descriptions, even in the thermodynamic…

Statistical Mechanics · Physics 2018-09-05 Marco Baldovin

We present general and rigorous results showing that the microcanonical and canonical ensembles are equivalent at all three levels of description considered in statistical mechanics - namely, thermodynamics, equilibrium macrostates, and…

Statistical Mechanics · Physics 2015-05-15 Hugo Touchette

Calculating thermodynamic potentials and observables efficiently and accurately is key for the application of statistical mechanics simulations to materials science. However, naive Monte Carlo approaches, on which such calculations are…

Statistical Mechanics · Physics 2021-07-15 James Damewood , Daniel Schwalbe-Koda , Rafael Gomez-Bombarelli

It has been proved for a class of mean-field and long-range systems that the concavity of the thermodynamic entropy determines whether the microcanonical and canonical ensembles are equivalent at the level of their equilibrium states, i.e.,…

Statistical Mechanics · Physics 2011-11-29 Hugo Touchette

This paper does three things: It proves a central limit theorem for novel permutation statistics (for example, the number of descents plus the number of descents in the inverse). It provides a clear illustration of a new approach to proving…

Probability · Mathematics 2016-10-28 Sourav Chatterjee , Persi Diaconis

It is shown, that the only reason for possibility of using microcanonical ensemble is that there are probabilistic processes in microworld, that are not described by quantum mechanic. On a simple example it is demonstrated, that canonical…

Quantum Physics · Physics 2011-06-09 V. A. Skrebnev

We demonstrate the equilibration of isolated macroscopic quantum systems, prepared in non-equilibrium mixed states with significant population of many energy levels, and observed by instruments with a reasonably bound working range compared…

Statistical Mechanics · Physics 2009-11-13 Peter Reimann

A great many observables seen in intermediate energy heavy ion collisions can be explained on the basis of statistical equilibrium. Calculations based on statistical equilibrium can be implemented in microcanonical ensemble (energy and…

Nuclear Theory · Physics 2009-11-10 C. B. Das , S. Das Gupta , W. G. Lynch , A. Z. Mekjian , M. B. Tsang

We consider a system weakly interacting with a bath as a thermodynamic setting to establish a quantum foundation of statistical physics. It is shown that even if the composite system is initially in an arbitrary nonequilibrium pure quantum…

Quantum Physics · Physics 2010-04-28 Jaeyoon Cho , M. S. Kim

The effect of imposing a constraint on a fluctuating scalar order parameter field in a system of finite volume is studied within statistical field theory. The canonical ensemble, corresponding to a fixed total integrated order parameter, is…

Statistical Mechanics · Physics 2017-08-17 Markus Gross , Andrea Gambassi , S. Dietrich

Focusing on isolated macroscopic systems, described either in terms of a quantum mechanical or a classical model, our two key questions are: In how far does an initial ensemble (usually far from equilibrium and largely unknown in detail)…

Statistical Mechanics · Physics 2013-11-13 Peter Reimann , Mykhaylo Evstigneev

Classical physics is approached from quantum mechanics in the macroscopic limit. The technical device to achieve this goal is the quantum version of the central limit theorem, derived for an observable at a given time and for the…

Quantum Physics · Physics 2021-09-01 Janos Polonyi

Throughout quantum mechanics there is statistical balance, in the collective response of an ensemble of systems to differing measurement types. Statistical balance is a core feature of quantum mechanics, underlying quantum mechanical…

Quantum Physics · Physics 2022-10-31 Brian Drummond

We discuss a property of our recently introduced generalized canonical ensemble (J. Stat. Phys. 119 (2005) 1283). We show that this ensemble can be used to transform metastable or unstable (nonequilibrium) states of the standard canonical…

Statistical Mechanics · Physics 2016-08-31 H. Touchette , M. Costeniuc , R. S. Ellis , B. Turkington

A self-consistent thermodynamic framework is presented for power-law canonical distributions based on the generalized central limit theorem by extending the discussion given by Khinchin for deriving Gibbsian canonical ensemble theory. The…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , A. K. Rajagopal

Quantum machine learning witnesses an increasing amount of quantum algorithms for data-driven decision making, a problem with potential applications ranging from automated image recognition to medical diagnosis. Many of those algorithms are…

Quantum Physics · Physics 2017-04-10 Maria Schuld , Francesco Petruccione

The angular bispectrum of spherical random fields has recently gained an enormous importance, especially in connection with statistical inference on cosmological data. In this paper, we provide expressions for its moments of arbitrary order…

Probability · Mathematics 2008-06-05 D. Marinucci

We propose a definition of microcanonical and canonical statistical ensembles based on the concept of density of states. This definition applies both to the classical and the quantum case. For the microcanonical case this allows for a…

Statistical Mechanics · Physics 2016-11-23 Vadim Kostrykin , Robert Schrader

The Legendre transformation is a crucial tool in theoretical physics, known for its symmetry, especially when applied to multivariate functions. In statistical mechanics, ensembles represent the central focus. Leveraging the dimensionless…

Statistical Mechanics · Physics 2024-04-04 Jingxu Wu , Chenjia Li , Zhenzhou Lei , Tuerdi Wumaier , Congyu Li , Yan Wang , Zekun Wang