Related papers: Vibrational instability, two-level systems and Bos…
We show that a {\em vibrational instability} of the spectrum of weakly interacting quasi-local harmonic modes creates the maximum in the inelastic scattering intensity in glasses, the Boson peak. The instability, limited by anharmonicity,…
Implications of reduction procedures applied to the low energy part of the vibrational density of states in glasses and supercooled liquids are considered by advancing a detailed comparison between the excess - over the Debye limit -…
The inelastic scattering intensities of glasses and amorphous materials has a maximum at a low frequency, the so called Boson peak. Under applied hydrostatic pressure, $P$, the Boson peak frequency, $\omega_{\rm b}$, is shifted upwards. We…
The Boson peak is believed to be the key to the fundamental understanding of the anomalous thermodynamic properties of glasses, notably the anomalous peak in the heat capacity at low temperatures; it is believed to be due to an excess of…
The boson peak (BP) is an excess of vibrational states over the Debye law appearing at terahertz frequencies. It is found in all glasses and marks the crossover between the long-wavelength behavior, where the solid can be considered as an…
Glasses are amorphous solids, in the sense that they display elastic behaviour. In crystals, elasticity is associated with phonons, quantized sound-wave excitations. Phonon-like excitations exist also in glasses at very high frequencies…
The dynamics of a soft sphere model glass, studied by molecular dynamics, is investigated. The vibrational density of states divided by $\omega^2$ shows a pronounced boson peak. Its shape is in agreement with the universal form derived for…
We consider a system of coupled classical harmonic oscillators with spatially fluctuating nearest-neighbor force constants on a simple cubic lattice. The model is solved both by numerically diagonalizing the Hamiltonian and by applying the…
Boson peak, the excess low energy excitations in the terahertz regime, is one of the most unique features of disordered systems and has been linked to many anomalous properties of glass materials. The nature and structural origin of the…
The excess low-frequency vibrational spectrum, called boson peak, and non-affine elastic response are the most important particularities of glasses. Herein, the vibrational and mechanical properties of polymeric glasses are examined by…
We perform molecular-dynamics simulations of the vibrational and the elasto-plastic properties of polymeric glasses and crystals and corresponding atomic systems. We evidence that the elastic scaling of the density of states in the…
A theory for the vibrational dynamics in disordered solids [W. Schirmacher, Europhys. Lett. {\bf 73}, 892 (2006)], based on the random spatial variation of the shear modulus, has been applied to determine the wavevector ($k$) dependence of…
The density of vibrational states $g(\omega)$ of an amorphous system is studied by using the random-matrix theory. Taking into account the most important correlations between elements of the random matrix of the system, equations for the…
Glasses have a large excess of low-frequency vibrational modes in comparison with continuous elastic body, the so-called Boson Peak, which appears to correlate with several crucial properties of glasses, such as transport or fragility. I…
The scaling behavior of the so-called boson peak in glass-formers and its relation to the elastic properties of the system remains a source of controversy. Here, the boson peak in a binary reactive mixture is measured by Raman scattering…
Despite the presence of topological disorder, phonons seem to exist also in glasses at very high frequencies (THz) and they remarkably persist into the supercooled liquid. A universal feature of such a systems is the Boson peak, an excess…
Ultra-stable glasses prepared from the physical vapor deposition of organic molecules present a very low density of two-level states, the kind of glass defects that determine their peculiar low temperature thermal properties. Numerical…
Many attempts to explain the Boson peak in the vibrational spectra of glasses consider models of a lattice of harmonic oscillators connected by spring constants of varying strength and randomly distributed. However, in real glasses one…
Glasses have a large excess of low-frequency vibrational modes in comparison with most crystalline solids. We show that such a feature is a necessary consequence of the weak connectivity of the solid, and that the frequency of modes in…
A hallmark of structural glasses and other disordered solids is the emergence of excess low-frequency vibrations, on top of the Debye spectrum $D_{\rm Debye}(\omega)$ of phonons ($\omega$ denotes the vibrational frequency), which exist in…