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The dissipation generated during a quasistatic thermodynamic process can be characterised by introducing a metric on the space of Gibbs states, in such a way that minimally-dissipating protocols correspond to geodesic trajectories. Here, we…

Quantum Physics · Physics 2019-10-25 Matteo Scandi , Martí Perarnau-Llobet

When long-range interactions are present the usual definition of temperature implies that two systems in thermal equilibrium can be at different temperatures. This local temperature has physical significance, if the sub-systems cease to…

General Relativity and Quantum Cosmology · Physics 2007-05-23 Daniel K. L. Oi , Jonathan Oppenheim

To describe the nonequilibrium states of the system, a new thermodynamic parameter - system lifetime - is introduced. Statistical distributions that describe the behavior of energy and lifetime are recorded. Entropy and obtained…

Statistical Mechanics · Physics 2019-10-14 V. V. Ryazanov

In the scientific and engineering literature, the second law of thermodynamics is expressed in terms of the behavior of entropy in reversible and irreversible processes. According to the prevailing statistical mechanics interpretation the…

Quantum Physics · Physics 2007-05-23 Elias P. Gyftopoulos , Gian Paolo Beretta

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…

Statistical Mechanics · Physics 2015-05-14 J. M. Deutsch

This review presents the effective temperature notion as defined from the deviations from the equilibrium fluctuation-dissipation theorem in out of equilibrium systems with slow dynamics. The thermodynamic meaning of this quantity is…

Statistical Mechanics · Physics 2015-05-28 Leticia F. Cugliandolo

Heat flow between a large ``bath'' and a smaller system brings them progressively closer to thermal equilibrium while increasing their entropy. Deviations from this trend are fluctuations involving a small fraction of a statistical ensemble…

Quantum Physics · Physics 2008-04-15 Noam Erez , Goren Gordon , Mathias Nest , Gershon Kurizki

The linear response to temperature changes is derived for systems with overdamped stochastic dynamics. Holding both in transient and steady state conditions, the results allow to compute nonequilibrium thermal susceptibilities from…

Statistical Mechanics · Physics 2016-04-11 Gianmaria Falasco , Marco Baiesi

The notion of mean temperature is crucial for a number of fields including climate science, fluid dynamics and biophysics. However, so far its correct thermodynamic foundation is lacking or even believed to be impossible. A physically…

Statistical Mechanics · Physics 2022-09-02 A. E. Allahverdyan , S. G. Gevorkian , Yu. A. Dyakov , Pao-Kuan Wang

The concept of temperature is one of the key ideas in describing the thermodynamical properties of a physical system. In classical statistical mechanics of ideal gases, the notion of temperature can be described in two different ways, the…

Statistical Mechanics · Physics 2007-11-12 Krishna R. Narayanan , Arun R. Srinivasa

We review the general aspects of the concept of temperature in equilibrium and non-equilibrium statistical mechanics. Although temperature is an old and well-established notion, it still presents controversial facets. After a short…

Statistical Mechanics · Physics 2017-11-13 A. Puglisi , A. Sarracino , A. Vulpiani

Non-equilibrium states of a thermodynamic statistical system are investigated using the thermodynamic parameter of the system lifetime, first-passage time, the time before degeneration of the system under influence of fluctuations.…

Statistical Mechanics · Physics 2020-03-19 V. V. Ryazanov

Quantifying irreversibility of a system using finite information constitutes a major challenge in stochastic thermodynamics. We introduce an observable that measures the time-reversal asymmetry between two states after a given time lag. Our…

Statistical Mechanics · Physics 2023-12-18 Shiling Liang , Simone Pigolotti

Understanding thermodynamics and statistical mechanics in the full general relativistic context is an open problem. I give tentative definitions of equilibrium state, mean values, mean geometry, entropy and temperature, which reduce to the…

General Relativity and Quantum Cosmology · Physics 2013-05-01 Carlo Rovelli

The thermodynamics is studied with the thermodynamic parameter of the lifetime, first-passage time, generalizing the equilibrium thermodynamics. Various ways of describing several stationary nonequilibrium states in the system are…

Statistical Mechanics · Physics 2019-10-21 V. V. Ryazanov

An unresolved problem in physics is how the thermodynamic arrow of time arises from an underlying time reversible dynamics. We contribute to this issue by developing a measure of time-symmetry breaking, and by using the work fluctuation…

Statistical Mechanics · Physics 2008-11-26 Edward H. Feng , Gavin E. Crooks

We consider stationary driven systems in contact with a thermal equilibrium bath. There is a constant (Joule) heat dissipated from the steady system to the environment as long as all parameters are unchanged. As a natural generalization…

Statistical Mechanics · Physics 2020-01-29 Christian Maes , Karel Netocny

The length-scale dependence of the dynamic entropy is studied in a molecular dynamics simulation of a binary Lennard-Jones liquid above the mode-coupling critical temperature $T_c$. A number of methods exist for estimating the entropy of…

Soft Condensed Matter · Physics 2009-10-31 Paolo Allegrini , Jack F. Douglas , Sharon C. Glotzer

A definition of the thermodynamic entropy based on the time-dependent probability distribution of the macroscopic variables is developed. When a constraint in a composite system is released, the probability distribution for the new…

Statistical Mechanics · Physics 2016-11-23 Robert H. Swendsen