Related papers: Theory of Gel Formation
As was shown in an earlier paper [1], solids dispersed in a drying drop migrate to the (pinned) contact line. This migration is caused by outward flows driven by the loss of the solvent due to evaporation and by geometrical constraint that…
Three-dimensional, time-dependent direct simulations of step emulsification micro-devices highlight two essential mechanisms for droplet formation: first, the onset of an adverse pressure gradient driving a back-flow of the continuous phase…
We present some recent theory and simulation results addressing the phenomena of colloidal gelation at both high and low volume fractions, in the presence of short-range attractive interactions. We discuss the ability of mode-coupling…
Drag reduction, or, what is the same, mean velocity increase in a turbulent flow at a fixed pressure drop through the addition of tiny amounts (several parts per million) of high molecular weight polymers (Thoms effect), is known already…
First, using the method of the soliton-solution, the fermion probability density equation, which corresponds to the Dirac equation, is derived. Next, we extend the chaos theory, in which the period bifurcation is equivalent to the particle…
In the gelation theory it has been implicitly assumed that (I) a cyclic bond is a finite bond that returns to itself; (II) cyclic bonds distribute at random in network structures. In this paper these two assumptions are reexamined from a…
This paper represents a theoretical and an experimental study of the spreading dynamics of a liquid droplet, generated by a needle free deposition system called the liquid needle droplet deposition technique. This technique utilizes a…
Recently, maximal valence model has been proposed to model liquid-liquid phase transition induced by polymerization in sulfur. In this paper we present a simple generic model to describe liquid polyamorphism in single-component fluids using…
Results for the kinetics of vapor-liquid transitions, following temperature quenches with different densities, are presented from the molecular dynamics simulations of a Lennard-Jones system. For critical density, bicontinuous liquid and…
We develop a formalism for particle production in a field theory coupled to a strong time-dependent external source. An example of such a theory is the Color Glass Condensate. We derive a formula, in terms of cut vacuum-vacuum Feynman…
Nucleation and growth is studied in a system undergoing diffusion-controlled condensation under gradual changes in parameters, such as cooling. It is demonstrated that when Gibbs-Thompson effect becomes negligible, the system falls into a…
We propose a simple, self-consistent kinetic model for the evolution of a mixture of droplets and vapor expanding adiabatically in vacuum after rapid, almost isochoric heating. We study the evolution of the two-phase fluid at intermediate…
In this paper, we consider the formation of droplets in the dimer model on a triangular lattice. The droplets in the dimer model are superposition polygons formed as two overlapping configurations of dimers: constant and movable. We…
Based on classical nucleation theory, we propose a couple of theoretical models for the nucleation of polymer crystallization, i.e. one for a single chain system (Model S) and the other for a multi-chain system (Model M). In these models,…
Despite the absence of consensus on a theory of the transition from supercooled liquids to glasses, the experimental observations suggest that a detail-independent theory should exist.
An analysis of glass formation for polymer melts that are diluted by structured molecular additives is derived by using the generalized entropy theory, which involves a combination of the Adam-Gibbs model and the direct computation of the…
Granular elasticity, an elasticity theory useful for calculating static stress distribution in granular media, is generalized to the dynamic case by including the plastic contribution of the strain. A complete hydrodynamic theory is derived…
We introduce the algebraic entropy for endomorphisms of arbitrary abelian groups, appropriately modifying existing notions of entropy. The basic properties of the algebraic entropy are given, as well as various examples. The main result of…
We use the entropy production variational method to associate a one particle distribution function to the assumed known energy-momentum and entropy currents describing a relativistic conformal fluid. Assuming a simple form for the collision…
We study equilibrium droplets in two-phase systems at parameter values corresponding to phase coexistence. Specifically, we give a self-contained microscopic derivation of the Gibbs-Thomson formula for the deviation of the pressure and the…