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Several commonly observed physical and biological systems are arranged in shapes that closely resemble an honeycomb cluster, that is, a tessellation of the plane by regular hexagons. Although these shapes are not always the direct product…

Optimization and Control · Mathematics 2025-01-10 Marco Caroccia , Kenneth DeMason , Francesco Maggi

In the present work, the low-lying structures of 20 different-sized water clusters are extensively searched using the artificial bee colony algorithm with TIP4P classical force field. To obtain the lowest equilibrium geometries, we select…

Atomic and Molecular Clusters · Physics 2024-11-04 Vishwa K. Bhatt , Sajeev S. Chacko , Nitinkumar M. Bijewar , Balasaheb J. Nagare

Icosahedral Au clusters with three and four shells of atoms are found to deviate significantly from the commonly assumed Mackay structures. By introducing additional atoms in the surface shell and creating a vacancy in the center of the…

Computational Physics · Physics 2022-04-01 Jan Kloppenburg , Andreas Pedersen , Kari Laasonen , Miguel A. Caro , Hannes Jónsson

We describe a new family of icosahedral structures for lead clusters. In general, structures in this family contain a Mackay icosahedral core with a reconstructed two-shell outer-layer. This family includes the anti-Mackay icosahedra, which…

Condensed Matter · Physics 2009-11-07 Shaun C. Hendy , Jonathan P. K. Doye

Since the discovery of chemically peculiar stars in globular clusters in the last century, the study of multiple populations has become increasingly important, given that chemical inhomogeneity is found in almost all globular clusters.…

Electronic structures of 13-atom Rh clusters with three possible high-symmetry geometries are studied using the discrete-variational local-spin-density-functional method. The ground state is found to be the icosahedral structure, and a…

Condensed Matter · Physics 2007-05-23 Yang Jinlong , F. Toigo , Wang Kelin , Zhang Manhong

Context Mixed-metal clusters have long been studied because of their peculiar properties and how they change with cluster size, composition and charge state and their potential roles in catalysis. The characterization of these clusters is…

Chemical Physics · Physics 2024-04-30 Paulo H. Acioli

We report a collection of lowest-energy structures of hydrocarbon molecules C_{m}H_{n} (m=1-18; n=0-2m+2). The structures are examined within a wide hydrogen chemical potential range. The genetic algorithm combined with Brenner's empirical…

Mesoscale and Nanoscale Physics · Physics 2011-08-24 Y. X. Yao , C. Rareshide , T. L. Chan , C. Z. Wang , K. M. Ho

The zero-temperature phase diagram of binary mixtures of particles interacting via a screened Coulomb pair potential is calculated as a function of composition and charge ratio. The potential energy obtained by a Lekner summation is…

Soft Condensed Matter · Physics 2009-11-13 Lahcen Assoud , Rene Messina , Hartmut Loewen

The putative ground-state structures of 13-atom Cu and Ag clusters have been studied using ${\it ab \: initio}$ molecular-dynamics (AIMD) simulations based on the density-functional theory (DFT). An ensemble of low-energy configurations,…

Disordered Systems and Neural Networks · Physics 2019-10-02 Dil K. Limbu , Michael U. Madueke , Raymond Atta-Fynn , David A. Drabold , Parthapratim Biswas

We consider a binary Lennard-Jones glassformer whose super-Arrhenius dynamics are correlated with the formation of particles organized into icosahedra under simple steady state shear. We recast this glassformer as an effective system of…

Soft Condensed Matter · Physics 2017-12-27 Rhiannon Pinney , Tanniemola B. Liverpool , C. Patrick Royall

The influence of quadrupolar interactions on the structure of small clusters is investigated by adding a point quadrupole of variable strength to the Lennard-Jones potential. Competition arises between sheet-like arrangements of the…

Soft Condensed Matter · Physics 2009-11-13 Mark A. Miller , James J. Shepherd , David J. Wales

We use the ``isoconfigurational ensemble'' [Phys. Rev. Lett. {\bf 93}, 135701 (2004)] to analyze both dynamical and structural properties in simulations of a glass forming molecular liquid. We show that spatially correlated clusters of low…

Materials Science · Physics 2009-11-11 Gurpreet S. Matharoo , M. S. Gulam Razul , Peter H. Poole

During the solidification of Al-Sm metallic glasses the evolution of the supercooled liquid atomic structure has been identified with an increasing population of icosahedral-like clusters with increasing Sm concentration. These clusters…

Computational Physics · Physics 2016-08-04 G. B. Bokas , L. Zhao , J. H. Perepezko , I. Szlufarska

We report molecular dynamics calculations on two-component, cold (1.2 > T > 0.56 in natural units), three-dimensional Lennard-Jones fluids. Our system was small (7813 A, 7812 B particles), dense (N/V = 1.30), and distinctly finite (L \times…

Soft Condensed Matter · Physics 2009-11-11 Paul C. Whitford , George D. J. Phillies

Using density functional theory (DFT) and quantum Monte Carlo (QMC) calculations we show that the B12Hn and B12Fn (n = 0-4) quasi-planar structures are energetically more favorable than the corresponding icosahedral clusters. Moreover, we…

Mesoscale and Nanoscale Physics · Physics 2021-09-21 N. Gonzalez Szwacki , C. J. Tymczak

We use density functional theory to quantify finite size and shape effects for gold nanoclusters. We concentrate on the computation of binding energy as a function of bond length for icosahedral and cuboctohedral clusters. We find that the…

Mesoscale and Nanoscale Physics · Physics 2009-12-31 Michael McGuigan , J. W. Davenport

We determined the structures of silicon clusters in the 11-14 atom size range using the tight-binding molecular dynamics method. These calculations reveal that \Si{11} is an icosahedron with one missing cap, \Si{12} is a complete…

chem-ph · Physics 2016-08-31 Jun Pan , Atul Bahel , Mushti V. Ramakrishna

The atomic structure of the supercooled liquid has often been discussed as a key source of glass formation in metals. The presence of icosahedrally-coordinated clusters and their tendency to form networks have been identified as one…

Materials Science · Physics 2013-10-30 Logan Ward , Dan Miracle , Wolfgang Windl , Oleg Senkov , Katharine Flores

A local and medium range atomic structure model for the face centred icosahedral (fci) Mg25Y11Zn64 alloy has been established in a sphere of r = 27 A. The model was refined by least squares techniques using the atomic pair distribution…

Materials Science · Physics 2007-05-23 S. Bruehne , E. Uhrig , C. Gross , W. Assmus , A. S. Masadeh , S. J. L. Billinge