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The finite-size effect on the antiferromagnetic (AF) transition and electronic configuration of iron has been observed in LiFePO4. Determination of the scaling behavior of the AF transition temperature (TN) versus the particle-size…

Materials Science · Physics 2012-10-29 G. J. Shu , M. W. Wu , F. C. Chou

We report exchange bias (EB) in single-phase CoO nanoparticles, where two magnetic phases naturally emerge as the crystallite size decreases from 34.6 to 10.8 nm. The N\'eel temperature (TN) associated with antiferromagnetic ordering…

Mesoscale and Nanoscale Physics · Physics 2024-04-15 Vikash Sharma , Sudip Pal , Divya Sharma , Dinesh Kumar Shukla , Ram Janay Chaudhary , Gunadhor Singh Okram

In this paper we report an investigation on the ferromagnetic state and the nature of ferromagnetic transition of nanoparticles of $\mathrm{La_{0.67}Ca_{0.33}MnO_3}$ using magnetic measurements and neutron diffraction. The investigation was…

Strongly Correlated Electrons · Physics 2011-01-04 Tapati Sarkar , A. K. Raychaudhuri , A. K. Bera , S. M. Yusuf

We report detailed studies on magnetic properties of Co3O4 nanoparticles of average size 12.5 nm. Temperature and field dependence of magnetization, wait time dependence of magnetic relaxation (aging), memory effects and temperature…

Mesoscale and Nanoscale Physics · Physics 2010-09-03 Vijay Bisht , K. P. Rajeev

In transition metal oxides, quantum confinement arising from a large surface to volume ratio often gives rise to novel physico-chemical properties at nanoscale. Their size dependent properties have potential applications in diverse areas,…

Thermal activation tends to destroy the magnetic stability of small magnetic nanoparticles, with crucial implications in ultra-high density recording among other applications. Here we demonstrate that low blocking temperature ferromagnetic…

Mesoscale and Nanoscale Physics · Physics 2015-07-15 Jose A. De Toro , Daniel P. Marques , Pablo Muniz , Vassil Skumryev , Jordi Sort , Dominique Givord , Josep Nogues

We report results of a comprehensive study of the phase transition at T_N (~643 K) as a function of particle size in multiferroic BiFeO3 system. We employed electrical, thermal, and temperature dependent X-ray diffraction (XRD) studies in…

Large magnetocaloric effect has been observed in Mn3O4 around its ferrimagnetic transition at TN = 42.75 K. Field-induced isothermal entropy changes (\DeltaS) were derived from both magnetic and calorimetric techniques. The maximum…

Materials Science · Physics 2011-03-04 S. Thota , F. Guillou , V. Hardy , A. Wahl , W. Prellier , J. Kumar

The latent heat (L) associated with the orbital order-disorder transition at T_JT is found to depend significantly on the average particle size (d) of LaMnO3. It rises slowly with the decrease in d down to ~100 nm and then jumps by more…

Strongly Correlated Electrons · Physics 2007-05-23 Nandini Das , Parthasarathi Mondal , Dipten Bhattacharya

We report detailed studies on non-equilibrium magnetic behavior of antiferromagnetic Co_3O_4 nanoparticles. Temperature and field dependence of magnetization, wait time dependence of magnetic relaxation (aging), memory effects and…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Vijay Bisht , K. P. Rajeev

We report the particle size dependent magnetic behaviour in the antiferromagnetic spinel CoRh2O4. The nanoparticles were obtained by mechanical milling of bulk material, prepared under sintering method. The XRD spectra show that the samples…

Disordered Systems and Neural Networks · Physics 2007-05-23 R. N. Bhowmik , R. Nagarajan , R. Ranganathan

A giant magnetocaloric effect across the ferromagnetic (FM) to paramagnetic (PM) phase transition was observed in chemically synthesized Co2FeAl Heusler alloy nanoparticles with a mean diameter of 16 nm. In our previous report, we have…

Strongly Correlated Electrons · Physics 2021-06-15 Aquil Ahmad , Srimanta Mitra , S. K. Srivastava , A. K. Das

Nd_0.5 Ca_0.5 MnO_3 (NCMO) nanoparticles (average diameter ~ 20 and 40 nm) are synthesized by polymeric precursor sol-gel method and characterized by X- ray diffraction, transmission electron microscopy (TEM), selective area electron…

Strongly Correlated Electrons · Physics 2009-11-11 S. S. Rao , S. V. Bhat

We report a systematic study on the structural and magnetic properties of Co_{x}Fe_{3-x}O_{4} magnetic nanoparticles with sizes between $5$ to $25$ nm, prepared by thermal decomposition of Fe(acac)_{3} and Co(acac)_{2}. The large…

Materials Science · Physics 2015-11-24 T. E. Torres , E. Lima , A. Mayoral , A. Ibarra , C. Marquina , M. R. Ibarra , G. F. Goya

The scaling of antiferromagnetic ordering temperature of corundum-type chromia films have been investigated. N\'eel temperature $T_N$ was determined from the effect of perpendicular exchange-bias on the magnetization of a weakly-coupled…

Mesoscale and Nanoscale Physics · Physics 2017-01-05 Satya Prakash Pati , Muftah Al-Mahdawi , Shujun Ye , Yohei Shiokawa , Tomohiro Nozaki , Masashi Sahashi

Materials with negative thermal expansion (NTE), which contract upon heating, are of great interest both technically and fundamentally. Here, we report giant NTE covering room temperature in mechanically milled antiperovksite GaNxMn3…

The microscopic origin of the high Neel temperature (T_N) observed experimentally in SrTcO_3 has been examined using a combination of ab-initio electronic structure calculations and mean-field solutions of a multiband Hubbard model. The…

Strongly Correlated Electrons · Physics 2011-12-26 S. Middey , Ashis Kumar Nandy , Priya Mahadevan , D. D. Sarma

We study the Neel temperature of quasi one-dimensional S=1/2 antiferromagnets containing non-magnetic impurities. We first consider the temperature dependence of the staggered susceptibility of finite chains with open boundary conditions,…

Strongly Correlated Electrons · Physics 2009-11-07 Sebastian Eggert , Ian Affleck , Matthew D. P. Horton

Spinel chromites ACr$_2$O$_4$ with inherent magnetic geometrical frustration usually exhibit a noncollinear ferrimagnetic ground state when A are magnetic ions, with possibly crystallite-size dependent intriguing magnetic features. Here, we…

Materials Science · Physics 2023-05-30 Mohamed A. Kassem , Abdulaziz Abu El-Fadl , Ahmed M. Nashaat , Hiroyuki Nakamura

8~nm epsilon-Fe2O3 nanoparticles exhibit a spin reorientation transition that begins at 150 K which is a hallmark of this unique iron-oxide polymorph. We find that the change from the high to low temperature magnetic structures has been…

Mesoscale and Nanoscale Physics · Physics 2019-10-02 Richard Jones , Rachel Nickel , Palash K. Manna , J. Hilman , Johan van Lierop
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