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The dependence of the transport properties on the specific location of the Fermi level in molecular electronics devices is studied by using electrodes of different materials. The zero-bias transport properties are shown to depend…

Mesoscale and Nanoscale Physics · Physics 2008-12-06 V. M. García-Suárez , C. J. Lambert

Transistors, regardless of their size, rely on electrical gates to control the conductance between source and drain contacts. In atomic-scale transistors, this conductance is exquisitely sensitive to single electrons hopping via individual…

We present a systematic study of the ballistic electron conductance through sp and 3d transition metal atoms attached to copper and palladium crystalline electrodes. We employ the 'ab initio' screened Korringa-Kohn-Rostoker Green's function…

Materials Science · Physics 2007-05-23 Alexei Bagrets , Nikos Papanikolaou , Ingrid Mertig

We examine theoretically coherent electron transport through the single-molecule magnet Mn$_{12}$, bridged between Au(111) electrodes, using the non-equilibrium Green's function method and the density-functional theory. We analyze the…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Kyungwha Park , Salvador Barraza-Lopez , Victor M. Garcia-Suarez , Jaime Ferrer

Single-molecule transistors provide a unique experimental tool to investigate the coupling between charge transport and the molecular degrees of freedom in individual molecules. One interesting class of molecules for such experiments are…

Single-molecule junctions represent electromechanical systems at the edge of device miniaturization. Despite extensive studies on the interplay between mechanical manipulation and electron transport in molecular junctions, a thorough…

We study the interference of interacting electrons in toroidal single-wall carbon nanotubes coupled to metallic electrodes by tunnel junctions. The dc conductance shows resonant features as a function of the gate voltage and the magnetic…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Joerg Rollbuehler , Arkadi A. Odintsov

We present a theoretical study of the conductance and thermopower of single-molecule junctions based on C60 and C60-terminated molecules. We first analyze the transport properties of gold-C60-gold junctions and show that these junctions can…

Mesoscale and Nanoscale Physics · Physics 2012-06-08 S. Bilan , L. A. Zotti , F. Pauly , J. C. Cuevas

The electronic transport through a triple quantum dot molecule attached in parallel to leads in presence of a magnetic flux is studied. Analytical expressions of the linear conductance and density of states for the molecule in equilibrium…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 M. L. Ladrón de Guevara , P. A. Orellana

Electronic conduction through single molecules is affected by the molecular electronic structure as well as by other information that is extremely difficult to assess, such as bonding geometry and chemical environment. The lack of an…

Mesoscale and Nanoscale Physics · Physics 2009-05-21 Daniel R. Ward , Naomi J. Halas , Jacob W. Ciszek , James M. Tour , Yanpeng Wu , Peter Nordlander , Douglas Natelson

Molecular wires are essential components for future nanoscale electronics. However, the preparation of individual long conductive molecules is still a challenge. MMX metal-organic polymers are quasi-one-dimensional sequences of single…

Mesoscale and Nanoscale Physics · Physics 2019-10-08 Pablo Ares , Pilar Amo-Ochoa , Jose M. Soler , Juan Jose Palacios , Julio Gomez-Herrero , Felix Zamora

We present a theoretical study of electron transport through a molecule connected to two metallic nanocontacts. The system investigated is 1,4 benzene-dithiolate (BDT) chemically bonded to two Au contacts. The surface chemistry is modeled…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Eldon Emberly , George Kirczenow

We have fabricated a variety of novel molecular diodes based on self-assembled-monolayers (SAM) of solid-state mixture of molecular wires (1,4 benzene-dimethane-thiol), and molecular insulator spacers (1-pentanethiol) with different…

Materials Science · Physics 2009-11-11 V. Burtman , A. S. Ndobe , Z. V. Vardeny

Here, we present theoretical analysis of electron transport in polyaniline based (PANi) nanofibers assuming the metalic state of the material. To build up this theory we treat conducting polymers as a special kind of granular metals, and we…

Soft Condensed Matter · Physics 2012-08-27 Natalya A. Zimbovskaya , Alan T. Johnson, , Nicholas J. Pinto

The ability to control the conductance of single molecules will have a major impact in nanoscale electronics. Azobenzene, a molecule that changes conformation as a result of a trans/cis transition when exposed to radiation, could form the…

Mesoscale and Nanoscale Physics · Physics 2008-11-26 Miriam del Valle , Rafael Gutierrez , Carlos Tejedor , Gianaurelio Cuniberti

The present paper gives an elaborate theoretical description of a new molecular charge transport mechanism applying to a single molecule trapped between two macroscopic electrodes in a solid state device. It is shown by a Hubbard type model…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Per Hedegard , Thomas Bjornholm

The final performance of a molecular electronic device is determined by the chemical structure of the molecular wires used in its assembly. Molecular place-exchange was used to incorporate di-thioacetate terminated molecules into ordered…

The rational design of single molecule electrical components requires a deep and predictive understanding of structure-function relationships. Here we explore the relationship between chemical substituents and the conductance of…

We present a simple model of electrical transport through a metal-molecule-metal nanojunction that includes charging effects as well as aspects of the electronic structure of the molecule. The interplay of a large charging energy and an…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Matthias H. Hettler , Herbert Schoeller , Wolfgang Wenzel

We develop a theoretical approach to quantum transport through single conjugated organic molecules that accurately accounts for all molecular excited and ground states via a semi-empirical many-body molecular Hamiltonian. We then calculate…

Materials Science · Physics 2008-12-12 J. P. Bergfield , C. A. Stafford