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An ab initio approach to the calculation of excitonic effects in the optical absorption spectra of semiconductors and insulators is formulated. It starts from a quasiparticle bandstructure calculation and is based on the relevant…

Condensed Matter · Physics 2016-08-31 Stefan Albrecht , Lucia Reining , Rodolfo Del Sole , Giovanni Onida

We present an ab initio description of optical and shallow-core x-ray absorption spectroscopies in a unified formalism based on the pseudopotential plane-wave method at the level of the Bethe-Salpeter equation (BSE) within Green's functions…

Materials Science · Physics 2023-06-07 M. Laura Urquiza , Matteo Gatti , Francesco Sottile

We delineate an ab initio approach for obtaining x-ray absorption spectra as provided by many-body perturbation theory, together with its realization within an all-electron framework. Employing the Bethe-Salpeter equation, we address…

Materials Science · Physics 2017-09-08 Claudia Draxl , Caterina Cocchi

We propose a new formalism and an effective computational framework to study self-trapped excitons (STE) in insulators and semiconductors from first principles. Using the many-body Bethe-Salpeter equation in combination with perturbation…

Materials Science · Physics 2023-11-22 Yunfei Bai , Yaxian Wang , Sheng Meng

We present an approach to calculate the optical absorption spectra that combines the quasiparticle self-consistent GW method [Phys. Rev. B, 76 165106 (2007)] for the electronic structure with the solution of the ladder approximation to the…

Materials Science · Physics 2018-03-21 Brian Cunningham , Pooya Azarhoosh , Dimitar Pashov , Myrta Gruening , Mark van Schilfgaarde

We present accurate optical spectra of semiconductors and insulators within a pure Kohn-Sham time-dependent density-functional approach. In particular, we show that the onset of the absorption is well reproduced when comparing to…

Materials Science · Physics 2020-03-18 Sarah Cavo , J. A. Berger , Pina Romaniello

Absorption spectra, exciton energy levels and wave functions for solid Ne and Ar have been calculated from first principles using many-body techniques. Electronic band structures of Ne and Ar were calculated using the GW approximation.…

Other Condensed Matter · Physics 2009-11-10 S. Galamic-Mulaomerovic , C. H. Patterson

We present ab initio absorption spectra of six three-dimensional semiconductors and insulators calculated using Gaussian-based periodic equation-of-motion coupled-cluster theory with single and double excitations (EOM-CCSD). The spectra are…

Chemical Physics · Physics 2021-07-13 Xiao Wang , Timothy C. Berkelbach

We present a computational approach for exciton calculations in two-dimensional (2D) materials within the Bethe-Salpeter equation (BSE) framework, employing an atomistic description with point-like orbitals. Unlike widespread efficient…

Mesoscale and Nanoscale Physics · Physics 2026-03-12 P. Ninhos , A. J. Uría-Álvarez , C. Tserkezis , N. A. Mortensen , J. J. Palacios

Here we describe an efficient numerical implementation of the Bethe-Salpeter equation to obtain the excitonic spectrum of semiconductors. This is done on the electronic structure calculated either at the simplest tight-binding level or…

An ab initio approach is presented for studying the collective excitations in excitonic insulators, charge/spin density waves and superconductors. We derive the Bethe-Salpeter-Equation for the particle-hole excitations in the quasiparticle…

Materials Science · Physics 2026-01-09 Fengyuan Xuan , Jiexi Song , Zhiyuan Sun

We calculate, as a function of temperature and conduction band electron density, the optical absorption of a weakly n-doped, idealized semiconductor quantum well. In particular, we focus on the absorption band due to the formation of a…

Strongly Correlated Electrons · Physics 2009-11-07 F. X. Bronold

Excitons, namely neutral excitations in a system of electrons arising from the electron-hole interaction, are often essential to explain optical measurements in materials. They are governed by the Bethe-Salpeter equation, which can be cast…

Strongly Correlated Electrons · Physics 2024-10-29 M. A. García-Blázquez , J. J. Palacios

The possible mismatch between the theoretical and experimental absorption of the edge peaks in semiconductors in a magnetic field background may arise due to the approximation scheme used to analytically calculate the absorption…

Quantum Physics · Physics 2009-02-26 Pulak Ranjan Giri , S. K. Chakrabarti

Excitonic effects in optical spectra and electron-hole pair excitations are described by solutions of the Bethe-Salpeter equation (BSE) that accounts for the Coulomb interaction of excited electron-hole pairs. Although for the computation…

Other Condensed Matter · Physics 2008-08-20 F. Fuchs , C. Rödl , A. Schleife , F. Bechstedt

A major obstacle for computing optical spectra of solids is the lack of reliable approximations for capturing excitonic effects within time-dependent density-functional theory. We show that the trustful prediction of strongly bound…

Bethe-Salpeter equation is solved for bound state composed of two fermions mediated by pion exchange force of the pseudovector coupling. Expanding the amplitude by gamma matrices the one-dimensional integral equation is derived. It…

Nuclear Theory · Physics 2013-06-20 Susumu Kinpara

In this work we present a new procedure to compute optical spectra including excitonic effects and approximated quasiparticle corrections with reduced computational effort. The excitonic effects on optical spectra are included by solving…

Materials Science · Physics 2020-08-26 Filipe Matusalem , Marcelo Marques , Ivan Guilhon , Lara K. Teles

We present a method to compute optical spectra and exciton binding energies of molecules and solids based on the solution of the Bethe-Salpeter equation (BSE) and the calculation of the screened Coulomb interaction in finite field. The…

Materials Science · Physics 2019-06-19 Ngoc Linh Nguyen , He Ma , Marco Govoni , Francois Gygi , Giulia Galli

We present an efficient implementation of the Bethe-Salpeter equation (BSE) method for obtaining core-level spectra including x-ray absorption (XAS), x-ray emission (XES), and both resonant and non-resonant inelastic x-ray scattering…

Computational Physics · Physics 2016-01-29 K. Gilmore , John Vinson , E. L. Shirley , D. Prendergast , C. D. Pemmaraju , J. J. Kas , F. D. Vila , J. J. Rehr
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