Related papers: Capillary Rise of Liquids in Nanopores
Under ambient humidity, water spontaneously condenses in pores only a few nanometers in size, making nanoscale capillarity central to numerous natural phenomena and technological applications. At these dimensions, water may no longer be…
We report on the capillary-driven levelling of a topographical perturbation at the surface of a free-standing liquid nanofilm. The width of a stepped surface profile is found to evolve as the square root of time. The hydrodynamic model is…
When a macroscopic droplet spreads, a thin precursor film of liquid moves ahead of the advancing liquid-solid-vapor contact line. Whereas this phenomenon has been explored extensively for planar solid substrates, its presence in…
This work revisits capillary filling dynamics in the regime of nanometric to subnanometric channels. Using molecular dynamics simulations of water in carbon nanotubes, we show that for tube radii below one nanometer, both the filling…
Polymers are known to wet nanopores with high surface energy through an atomically thin precursor film followed by slower capillary filling. We present here light interference spectroscopy using a nanoporous membrane-based chip that allows…
We present a theoretical study of spontaneous imbibition of liquid 4He in silica aerogels focusing on the effect of porosity on the fluid dynamical behavior. We adopt a coarse-grained three-dimensional lattice-gas description like in…
Liquid in grooved capillaries, made by e.g. inserting a plate in a cylindrical tube, exhibits unusual spreading and flow properties. One example is capillary rise, where a long, upward tongue on top of the usual meniscus has been observed…
We revisit the classical problem of liquid imbibition in a single pore with spatially varying wettability. Starting from the Lucas-Washburn equation, we derive analytical solutions for the imbibition time (crossing time) in systems where…
By using the glassy (helium-)fluid model and boundary perturbation method, we can obtain the velocity fields (as well as the flow rate; up to the second order) inside the wavy-rough cylindrical nanopores which are of the same size as those…
Nanoporous materials provide high surface area per unit mass and are capable of fluids adsorption. While the measurements of overall amount of fluid adsorbed by a nanopororus sample are straightforward, probing the fluid spacial…
Thermodynamics and hydrodynamics of spontaneous and forced imbibition of liquid into conical capillaries are studied to assess the feasibility of a conical liquid diode. The analytical formulas for the Laplace pressure and the critical…
Fluid imbibition into porous media featuring nanopores is ubiquitous in applications such as oil recovery from unconventional reservoirs and material processing. While the imbibition of pure fluids has been extensively studied, the…
We describe the imbibition process from a point source into a homogeneous semi-infinite porous material. When body forces are negligible, the advance of the wetting front is driven by capillary pressure and resisted by viscous forces. With…
Capillary imbibition underpins many processes of fundamental and applied relevance in fluid mechanics. A limitation to the flow is the coupling to the confining solid, which induces friction forces. Our work proposes a general theoretical…
We consider theoretically liquid rise against gravity in capillaries with height-dependent cross-section. For a conical capillary made from a hydrophobic surface and dipped in a liquid reservoir, the equilibrium liquid height depends on the…
Optical birefringence and light absorption measurements reveal four regimes for the thermotropic behavior of a nematogen liquid (7CB) upon sequential filling of parallel-aligned capillaries of 12 nm diameter in a monolithic, mesoporous…
Traditional approaches to mathematically describe spontaneous imbibition are usually based on either macro-scale models, such as Richards equation, or simplified pore-scale models, such as the bundle of capillary tubes (BCTM) or…
Capillary-driven flow of fluids occurs frequently in nature and has a wide range of technological applications in the fields of industry, agriculture, medicine, biotechnology, and microfluidics. By using the Onsager variational principle,…
Liquids under confinement differ in behavior from their bulk counterparts and can acquire properties that are specific to the confined phase and linked to the nature and structure of the host matrix. While confined liquid water is not a new…
Thermodynamics of imbibition (intrusion and extrusion) in capillaries of double conical structures is theoretically studied using the classical capillary model. By extending the knowledge of the thermodynamics of a single conical capillary,…