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We study the interactions between two negatively charged macroscopic surfaces confining positive counterions. A density-functional approach is introduced which, besides the usual mean-field interactions, takes into account the correlations…

Soft Condensed Matter · Physics 2015-06-25 A. Diehl , M. N. Tamashiro , Marcia C. Barbosa , Yan Levin

In mixtures of colloids and nonadsorbing polyelectrolytes, a Donnan potential arises across the region between surfaces that are depleted of polyelectrolyte and the rest of the system. This Donnan potential tends to shift the…

Soft Condensed Matter · Physics 2022-10-27 Jasper Landman , Max P. M. Schelling , Remco Tuinier , Mark Vis

We study the effective electrostatic interactions between a pair of charged colloidal particles without salt ions while the system is confined in two dimensions. In particular we use a simplified model to elucidate the effects of rotational…

Soft Condensed Matter · Physics 2010-09-09 Chi-Lun Lee , Sio-Kit Ng

The electrostatic interaction between colloidal particles trapped at the interface between two immiscible electrolyte solutions is studied in the limit of small inter-particle distances. Within an appropriate model exact analytic…

Soft Condensed Matter · Physics 2014-05-07 Arghya Majee , Markus Bier , S. Dietrich

We present an overview of our understanding of electrostatic interactions between charged macromolecular surfaces mediated by mobile counter- and coions. The dichotomy between the weak and the strong coupling regimes is described in detail…

Soft Condensed Matter · Physics 2016-12-21 Ali Naji , Matej Kanduc , Roland R. Netz , Rudolf Podgornik

In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using mean-field approach accounting for solvent polarization and non-uniform size effect. Applying a…

Soft Condensed Matter · Physics 2022-02-11 Jun-Sik Sin

We examine the force between two charged surfaces immersed in aqueous mixtures having a coexistence curve. For a homogeneous water-poor phase, as the distance between the surfaces is decreased, a water-rich phase condenses at a distance…

Statistical Mechanics · Physics 2015-05-27 Sela Samin , Yoav Tsori

Using molecular dynamic simulations we study a system of particles interacting through a continuous core-softened potentials consisting of a hard core, a shoulder at closest distances and an attractive well at further distance. We obtain…

Statistical Mechanics · Physics 2010-06-02 Jonathas Nunes da Silva , Evy Salcedo , Alan Barros de Oliveira , Marcia C. Barbosa

Electrostatic interactions provide a convenient way to modulate interactions between nanoparticles, colloids, and biomolecules because they can be adjusted by the solution pH or salt concentration. While the presence of salt provides an…

Soft Condensed Matter · Physics 2019-09-04 Sawyer S. Hopkins , Amitabha Chakrabarti , Jeremy D. Schmit

We calculate the interaction potential between two colloids immersed in an aqueous mixture containing salt near or above the critical temperature. We find an attractive interaction far from the coexistence curve due to the combination of…

Soft Condensed Matter · Physics 2015-06-03 Sela Samin , Yoav Tsori

The electrostatic double layer force is key to determining the stability and self-assembly of charged colloids and many other soft matter systems. Fully understanding the attractive force between two like-charged surfaces remains a great…

Soft Condensed Matter · Physics 2024-02-27 Nikhil R. Agrawal , Ravtej Kaur , Carlo Carraro , Rui Wang

We study the interaction between two neutral plane-parallel dielectric bodies in the presence of a highly asymmetric ionic fluid, containing multivalent as well as monovalent (salt) ions. Image charge interactions, due to dielectric…

Soft Condensed Matter · Physics 2015-06-11 Matej Kanduc , Ali Naji , Jan Forsman , Rudolf Podgornik

We develop an efficient Ewald method of molecular dynamics simulation for calculating the electrostatic interactions among charged and polar particles between parallel metallic plates, where we may apply an electric field with an arbitrary…

Soft Condensed Matter · Physics 2013-10-01 Kyohei Takae , Akira Onuki

We study the effective interaction between differently charged polyelectrolyte-colloid complexes in electrolyte solutions via Monte Carlo simulations. These complexes are formed when short and flexible polyelectrolyte chains adsorb onto…

Soft Condensed Matter · Physics 2010-05-05 D. Truzzolillo , F. Bordi , F. Sciortino , S. Sennato

The subtle interplay between critical phenomena and electrostatics is investigated by considering the effective force acting on two parallel walls confining a near-critical binary liquid mixture with added salt. The ion-solvent coupling can…

Soft Condensed Matter · Physics 2011-09-13 Markus Bier , Andrea Gambassi , Martin Oettel , S. Dietrich

In this thesis, the electrostatic interaction between two chemically identical colloids, both carrying constant surface potential is studied in the limit of short inter-particle separation at the interface of two immiscible fluids. Using an…

Soft Condensed Matter · Physics 2020-01-01 Rick Bebon

We study the spatial and orientational distribution of rodlike counterions (such as mobile nanorods) as well as the effective interaction mediated by them between two plane-parallel surfaces that carry fixed (quenched) heterogeneous charge…

Soft Condensed Matter · Physics 2020-10-01 Ali Naji , Kasra Hejazi , Elnaz Mahgerefteh , Rudolf Podgornik

The structural diversity of the solute molecules involved in biomolecular processes necessitates the characterization of the forces between charged macromolecules beyond the point-ion description. From the field theoretic partition function…

Soft Condensed Matter · Physics 2023-06-22 Sahin Buyukdagli

The screened Coulomb interaction between uniformly charged flat plates is considered at very small plate separations for which the Debye layers are strongly overlapped, in the limit of small electrical potentials. If the plates are of…

Soft Condensed Matter · Physics 2017-02-06 Sandip Ghosal , John D. Sherwood

We apply a phenomenological theory of polar liquids to calculate the interaction energy between two plane surfaces at nm-distances. We show that depending on the properties of the surface-liquid interfaces, the interacting surfaces induce…

Soft Condensed Matter · Physics 2013-04-24 P. O. Fedichev , L. I. Menshikov