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We examine the fluid phase behaviour of the binary mixture of hard superellipses using the scaled particle theory The superellipse is a general two dimensional convex object which can be tuned between circular and rectangular shapes…

Soft Condensed Matter · Physics 2020-09-02 Sakine Mizani , Peter Gurin , Roohollah Aliabadi , Hamdollah Salehi , Szabolcs Varga

We numerically investigate two-dimensional systems of hard rectangles at constant pressure through extensive hard-particle Monte Carlo simulations. We determine the complete phase diagram as a function of packing fraction and aspect ratio,…

Soft Condensed Matter · Physics 2025-05-15 Denis Dertli , Thomas Speck

Using a version of density-functional theory which combines Onsager approximation and fundamental-measure theory for spatially nonuniform phases, we have studied the phase diagram of freely rotating hard rectangles and hard discorectangles.…

Soft Condensed Matter · Physics 2009-11-10 Yuri Martinez-Raton , Enrique Velasco , Luis Mederos

We formulate the scaled particle theory for a general mixture of hard isosceles triangles and calculate different phase diagrams for the one-component fluid and for certain binary mixtures. The fluid of hard triangles exhibits a complex…

Soft Condensed Matter · Physics 2018-05-16 Yuri Martinez-Raton , Ariel Diaz-De Armas , Enrique Velasco

Scaled particle theory for a binary mixture of hard discorectangles and for a binary mixture of hard rectangles is used to predict possible liquid-crystal demixing scenarios in two dimensions. Through a bifurcation analysis from the…

Soft Condensed Matter · Physics 2009-11-11 Yuri Martinez-Raton , Enrique Velasco , Luis Mederos

We show that the relative stability of the nematic tetratic phase with respect to the usual uniaxial nematic phase can be greatly enhanced by clustering effects. Two--dimensional rectangles of aspect ratio $\kappa$ interacting via hard…

Soft Condensed Matter · Physics 2009-11-13 Yuri Martinez-Raton , Enrique Velasco

Previous Monte Carlo investigations by Wojciechowski \emph{et al.} have found two unusual phases in two-dimensional systems of anisotropic hard particles: a tetratic phase of four-fold symmetry for hard squares [Comp. Methods in Science and…

Statistical Mechanics · Physics 2009-11-11 A. Donev , J. Burton , F. H. Stillinger , S. Torquato

Using Density Functional Theory we theoretically study the orientational properties of uniform phases of hard kites -- two isosceles triangles joined by their common base. Two approximations are used: Scaled Particle Theory, and a new…

Soft Condensed Matter · Physics 2020-11-25 Yuri Martínez-Ratón , Enrique Velasco

We study an experimental system of hard granular squares in two dimensions, energized by vibration. The interplay of order in the orientations and positions of anisotropic particles allows for a rich set of phases. We measure the structure…

Soft Condensed Matter · Physics 2016-08-23 Lee Walsh , Narayanan Menon

We introduce a model for a fluid of polydisperse rounded hard rectangles where the length and width of the rectangular core are fixed, while the roundness is taken into account by the convex envelope of a disk displaced along the perimeter…

Soft Condensed Matter · Physics 2022-09-07 Yuri Martinez-Raton , Enrique Velasco

We report the discovery of a mixed orientational structure in the quasi-one-dimensional fluid of hard non-spherical bodies with the exact calculation of the thermodynamic and structural quantities using the transfer operator method. The…

Soft Condensed Matter · Physics 2025-10-13 Sakineh Mizani , Martin Oettel , Péter Gurin , Szabolcs Varga

Orientational and positional ordering properties of liquid crystal monolayers are examined by means of Fundamental-Measure Density Functional Theory. Particles forming the monolayer are modeled as hard parallelepipeds of square section of…

Soft Condensed Matter · Physics 2015-06-19 Yuri Martinez-Raton , Szabolcs Varga y Enrique Velasco

We develop the scaled particle theory to describe the thermodynamic properties and orientation ordering of a binary mixture of hard spheres (HS) and hard spherocylinders (HSC) confined in a disordered porous medium. Using this theory the…

Soft Condensed Matter · Physics 2019-02-12 M. Hvozd , T. Patsahan , M. Holovko

We have calculated the phase diagrams of one--component fluids made of five types of biaxial particles differing in their cross sections. The orientation of the principal particle axis is fixed in space, while the second axis is allowed to…

Soft Condensed Matter · Physics 2009-11-13 Yuri Martinez-Raton , Szabolcs Varga , Enrique Velasco

We analyze the sedimentation behavior of a polydisperse two-dimensional liquid-crystal fluid using a local density functional theory based on scaled particle theory. Polydispersity is incorporated through variations in the roundness of hard…

Soft Condensed Matter · Physics 2025-11-11 Tobias Eckert , Daniel de las Heras , Enrique Velasco , Yuri Martínez-Ratón

We theoretically study the phase behaviour of monolayers of hard rod-plate mixtures using a fundamental-measure density functional in the restricted-orientation (Zwanzig) approximation. We consider both species to be subject to an…

Soft Condensed Matter · Physics 2016-09-01 Yuri Martinez-Raton , Miguel Gonzalez-Pinto , Enrique Velasco

We use density-functional theory, of the fundamental-measure type, to study the relative stability of the biaxial nematic phase, with respect to non-uniform phases such as smectic and columnar, in fluids made of hard board-like particles…

Soft Condensed Matter · Physics 2017-09-13 Yuri Martinez-Raton , Szabolcs Varga , Enrique Velasco

Using the classical density functional theory of freezing and Monte Carlo computer simulations, we explore the liquid-crystalline phase behavior of hard rectangles on flat and cylindrical manifolds. Moreover, we study the effect of a static…

Soft Condensed Matter · Physics 2018-02-19 Christoph E. Sitta , Frank Smallenburg , Raphael Wittkowski , Hartmut Löwen

Many physical systems involve two types of orientational order, which are coupled together. For example, ferroelectric nematic liquid crystals have coupled polar and nematic order, and tilted hexatic phases have coupled polar and hexatic…

Soft Condensed Matter · Physics 2026-03-16 Lincoln Paik , Jonathan V. Selinger

We investigate fluids of dipolar hard particles by a certain variant of density-functional theory. The proper treatment of the long range of the dipolar interactions yields a contribution to the free energy which favors ferromagnetic order.…

Condensed Matter · Physics 2009-10-28 B. Groh , S. Dietrich
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