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We show that the relative effect of variation of the fine structure constant in microwave transitions between very close and narrow rotational-hyperfine levels may be enhanced 2-3 orders of magnitude in diatomic molecules like LaS, LaO,…

Atomic Physics · Physics 2009-11-11 V. V. Flambaum

Recently it was pointed out that transition frequencies in certain diatomic molecules have an enhanced sensitivity to variations in the fine-structure constant $\alpha$ and the proton-to-electron mass ratio $m_p/m_e$ due to a near…

Atomic Physics · Physics 2010-08-31 K. Beloy , A. Borschevsky , P. Schwerdtfeger , V. V. Flambaum

The relative effects of variation of the fine structure constant alpha=e^2/hc and dimensionless strong interaction parameter m_q/Lambda_{QCD} are enhanced 5-6 orders of magnitude in very narrow ultraviolet transition between the ground and…

Atomic Physics · Physics 2011-11-23 V. V. Flambaum

High accuracy measurements in M\"ossbauer transitions open up the possibility to use them in the search for temporal and spatial variation of the fine-structure constant $\alpha$, quark mass $m_q$, and dark matter field which may lead to…

Nuclear Theory · Physics 2022-06-08 Pavel Fadeev , Julian C. Berengut , Victor V. Flambaum

The ^{207}Pb^{19}F molecule possesses a pair of closely spaced levels of opposite parity due to near cancelation of the omega-type doubling and magnetic hyperfine interaction energy shifts [Alphei et al., Phys. Rev. A, 83, 040501 (2011)].…

Atomic Physics · Physics 2014-05-08 V. V. Flambaum , Y. V. Stadnik , M. G. Kozlov , A. N. Petrov

Microwave and submillimeter molecular transition frequencies between nearly degenerated rotational levels, tunneling transitions, and mixed tunneling-rotational transitions show an extremely high sensitivity to the values of the…

Atomic Physics · Physics 2016-10-26 M. G. Kozlov , S. A. Levshakov

Quasi-forbidden electronic transitions in atoms and quasi-degenerate vibronic transitions in molecules serve as powerful probes of hypothetical temporal variations of fundamental constants. Computation of the sensitivity of a transition to…

Chemical Physics · Physics 2025-11-17 Carsten Zülch , Konstantin Gaul , Robert Berger

We study ultranarrow $5s_{1/2}$ - $4f_{5/2}$ transitions in Nd$^{13+}$ and Sm$^{15+}$ and demonstrate that they lie in the optical region. The transitions are insensitive to external perturbations. At the same time they are sensitive to the…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

Sensitivity coefficients to temporal variation of the fine-structure constant alpha for transitions between the fine-structure (FS) sub-levels of the ground states of C I, Si I, S I, Ti I, Fe I, N II, Fe II, O III, S III, Ar III, Fe III, Mg…

Astrophysics · Physics 2009-09-01 M. G. Kozlov , S. G. Porsev , S. A. Levshakov , D. Reimers , P. Molaro

Accurate measurements of different transition frequencies between atomic levels of the electronic and hyperfine structure over time are used to investigate temporal variations of the fine structure constant $\alpha$ and the…

Atomic Physics · Physics 2014-12-01 N. Huntemann , B. Lipphardt , Chr. Tamm , V. Gerginov , S. Weyers , E. Peik

The search for variation of the fundamental constants such as the fine structure constant $\alpha$ ($\alpha=e^2/\hbar c$) and the ratios of fundamental masses (e.g., electron to proton mass ratio $\mu=m_e/m_p$) is reviewed. Strong emphasis…

Atomic Physics · Physics 2015-05-13 V. V. Flambaum , V. A. Dzuba

Peik and Tamm [Europhys. Lett. 61, 181 (2003)] proposed a nuclear clock based on the isomeric transition between the ground state and the first excited state of thorium-229. This transition was recognized as a potentially sensitive probe of…

Atomic Physics · Physics 2021-01-19 Pavel Fadeev , Julian C. Berengut , Victor V. Flambaum

Theories unifying gravity with other interactions suggest spatial and temporal variation of fundamental "constants" in the Universe. A change in the fine structure constant, alpha, could be detected via shifts in the frequencies of atomic…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , J. A. King , M. G. Kozlov , M. T. Murphy , J. K. Webb

We present a review of recent works devoted to the variation of the fine structure constant alpha, strong interaction and fundamental masses. There are some hints for the variation in quasar absorption spectra, Big Bang nucleosynthesis, and…

Atomic Physics · Physics 2009-08-18 V. V. Flambaum

We study atomic systems that are in the frequency range of optical atomic clocks and have enhanced sensitivity to potential time-variation of the fine structure constant, alpha. The high sensitivity is due to coherent contributions from…

Atomic Physics · Physics 2010-09-16 J. C. Berengut , V. A. Dzuba , V. V. Flambaum

We identify two metastable excited states in Sm$ ^{10+} $ highly charged ion as candidates for high accuracy optical clocks. Several atomic properties relevant to optical clock development are calculated using relativistic many-body…

High Energy Physics - Phenomenology · Physics 2024-09-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

The sensitivity of rotational transitions in CH and CD to a possible variation of fundamental constants has been investigated. Largely enhanced sensitivity coefficients are found for specific transitions which are due to accidental…

Atomic Physics · Physics 2015-06-05 Adrian J. de Nijs , Wim Ubachs , Hendrick L. Bethlem

Experiments aimed at searching for variations in the fine-structure constant $\alpha$ are based on spectroscopy of transitions in microscopic bound systems, such as atoms and ions, or resonances in optical cavities. The sensitivities of…

Atomic Physics · Physics 2023-05-22 Beata Zjawin , Marcin Bober , Roman Ciuryło , Daniel Lisak , Michał Zawada , Piotr Wcisło

Theories unifying gravity with other interactions suggest spatial and temporal variation of fundamental ``constants'' in the Universe. A change in the fine structure constant, alpha, could be detected via shifts in the frequencies of atomic…

We report precise measurements of ground-state, $\lambda$-doublet microwave transitions in the hydroxyl radical molecule (OH). Utilizing slow, cold molecules produced by a Stark decelerator we have improved over the precision of the…

Atomic Physics · Physics 2009-11-11 Eric R. Hudson , H. J. Lewandowski , Brian C. Sawyer , Jun Ye
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