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We reveal the existence of systematic variations of isobaric fragility in different supercooled Lennard-Jones binary mixtures by performing molecular dynamics simulations. The connection between fragility and local structures in the bulk is…

Statistical Mechanics · Physics 2007-10-02 D. Coslovich , G. Pastore

We study the influence of the softness of the interparticle interactions on the fragility of a glass former, by considering three model binary mixture glass formers. The interaction potential between particles is a modified Lennard-Jones…

Disordered Systems and Neural Networks · Physics 2012-06-19 Shiladitya Sengupta , Filipe Vasconcelos , Frédéric Affouard , Srikanth Sastry

By performing molecular dynamics simulations of binary Lennard-Jones systems with three different potentials, we show that increase of anharmonicity and capacity for intermolecular coupling of the potential is the cause of (i) the increase…

Condensed Matter · Physics 2009-11-10 P. Bordat , F. Affouard , M. Descamps , K. L. Ngai

The supercooled dynamics of a Lennard-Jones model liquid is numerically investigated studying relevant points of the potential energy surface, i.e. the minima of the square gradient of total potential energy $V$. The main findings are:…

Soft Condensed Matter · Physics 2009-11-07 L. Angelani , R. Di Leonardo , G. Ruocco , A. Scala , F. Sciortino

The phenomenology of glass-forming liquids is often described in terms of their underlying, high-dimensional potential energy surface. In particular, the statistics of stationary points sampled as a function of temperature provides useful…

Statistical Mechanics · Physics 2021-01-06 Masanari Shimada , Daniele Coslovich , Hideyuki Mizuno , Atsushi Ikeda

Dynamical properties of a Lennard-Jones binary mixture embedded in an off lattice matrix of soft spheres are studied in the direct space upon supercooling by molecular dynamics simulations. On lowering temperature the smaller particles tend…

Soft Condensed Matter · Physics 2009-11-10 P. Gallo , R. Pellarin , M. Rovere

The concept of fragility provides a possibility to rank different supercooled liquids on the basis of the temperature dependence of dynamic and/or thermodynamic quantities. We recall here the definitions of kinetic and thermodynamic…

Statistical Mechanics · Physics 2009-11-10 G. Ruocco , F. Sciortino , F. Zamponi , C. De Michele , T. Scopigno

By means of molecular dynamics simulations, we study the stationary points of the potential energy in a Lennard-Jones liquid, giving a purely geometric characterization of the energy landscape of the system. We find a linear relation…

Statistical Mechanics · Physics 2009-10-31 Kurt Broderix , Kamal K. Bhattacharya , Andrea Cavagna , Annette Zippelius , Irene Giardina

We numerically study the interplay between heterogeneous dynamics and properties of negatively curved regions of the potential energy surface in a model glassy system. We find that the unstable modes of saddles and quasi-saddles undergo a…

Statistical Mechanics · Physics 2007-05-23 D. Coslovich , G. Pastore

The connectivity of the potential energy landscape in supercooled atomic liquids is investigated through the calculation of the instantaneous normal modes spectrum and a detailed analysis of the unstable directions in configuration space.…

Soft Condensed Matter · Physics 2009-10-31 Claudio Donati , Francesco Sciortino , Piero Tartaglia

A model based on the existence of two different competing local structures in water is described. It is shown that it can explain the transition between fragile and strong behavior that supercooled water has around 220 K. The high…

Statistical Mechanics · Physics 2009-10-31 E. A. Jagla

We report Molecular Dynamics simulations for a new model of tetrahedral network glass-former, based on short-range, spherical potentials. Despite the simplicity of the forcefield employed, our model reproduces some essential physical…

Statistical Mechanics · Physics 2016-09-08 D. Coslovich , G. Pastore

We consider the energetics of a superconducting double dot, comprising two superconducting islands coupled in series via a Josephson junction. The periodicity of the stability diagram is governed by the competition between the charging…

Mesoscale and Nanoscale Physics · Physics 2014-03-27 N. J. Lambert , M. Edwards , A. A. Esmail , F. A. Pollock , B. W. Lovett , A. J. Ferguson

The potential energy landscape in the Kob-Andersen Lennard-Jones binary mixture model has been studied carefully from liquid down to the supercooled regime, from T =2 down to T =0.46. One thousand of independent configurations along the…

Disordered Systems and Neural Networks · Physics 2016-08-31 M. Sampoli , P. Benassi , R. Eramo , L. Angelani , G. Ruocco

Surface and interfacial energies play important roles in a number of instability phenomena in liquids and soft matters, but are rare to play a similar role in solids. Here we report a new type of mechanical instabilities that are controlled…

Mesoscale and Nanoscale Physics · Physics 2019-06-26 Cangyu Qu , Songlin Shi , Quanshui Zheng

We consider a horizontal ferrofluid layer sandwiched between two layers of immiscible non-magnetic fluids. In a sufficiently strong vertical magnetic field the flat interfaces between magnetic and non-magnetic fluids become unstable to the…

Materials Science · Physics 2009-11-10 Dirk Rannacher , Andreas Engel

We use molecular dynamics simulation results on viscous binary Lennard-Jones mixtures to examine the correlation between the potential energy and the virial. In accord with a recent proposal [U. R. Pedersen et. al. Phys. Rev. Lett. 100,…

Statistical Mechanics · Physics 2009-01-08 D. Coslovich , C. M. Roland

Metastable states in first-order phase transitions reveal interesting behavior about a wide range of systems in statistical mechanics, including spin systems, cellular automata and condensed matter systems. These metastable states are often…

Statistical Mechanics · Physics 2019-08-23 Vivianne Olguín-Arias , Sergio Davis , Gonzalo Gutiérrez

Computer experiments concerning interactions between a graphite surface and the rigid pyramidal nanoasperity of a friction force microscope tip when it is brought close to and retracted from the graphitic sample are presented. Covalent…

Statistical Mechanics · Physics 2010-10-19 A. V. Khomenko , N. V. Prodanov

Advances in high-precision dielectric spectroscopy has enabled access to non-linear susceptibilities of polar molecular liquids. The observed non-monotonic behavior has been claimed to provide strong support for theories of dynamic arrest…

Soft Condensed Matter · Physics 2021-07-07 Thomas Speck
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