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Time-dependent measurements of both power conversion efficiency and ultraviolet-visible absorption spectroscopy have been observed for solar cell blends containing the polymer poly(3-hexylthiophene-2,5-diyl) (P3HT) with two different…

The time dependence of device performance has been measured for photocells using blends containing the conjugated polymer, poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) with two different functionalized C60 electron…

Hybrid conjugated polymer/fullerene filaments based on MEH-PPV/PVP/PCBM are prepared by electrospinning, and their properties assessed by scanning electron, atomic and lateral force, tunnelling, and confocal microscopy, as well as by…

From a fundamental and application point of view it is of importance to understand how charge carrier generation and transport in a conjugated polymer (CP):fullerene blend are affected by the blend morphology. In this work light-induced…

Soft Condensed Matter · Physics 2017-09-13 Tom J. Savenije , Andreas Sperlich , Hannes Kraus , Oleg G. Poluektov , Martin Heeney , Vladimir Dyakonov

Improvement of the photovoltaic efficiency (from 1.2% to 3%) via exposure of organic poly(3-hexylthiophene) (P3HT) + phenyl-C61-butyric acid methyl ester (PCBM) devices to solvent vapor at room temperature is reported. In situ…

Materials Science · Physics 2007-05-23 Giovanni Fanchini , Steve Miller , Manish Chhowalla

In organic semiconductor based bulk heterojunction solar cells, the presence of acceptor increases the formation of charge transfer (CT) excitons, thereby leading to higher exciton dissociation probabilities. In this work we used steady…

Blends of carbon nanotubes with conjugated polymer and fullerene derivatives are complex nanocomposite systems, which have recently attracted a great research interest for their photovoltaic ability. Therefore, gaining a better…

Mesoscale and Nanoscale Physics · Physics 2018-05-17 Diana Gisell Figueroa del Valle , Giuseppe M. Paternò , Francesco Scotognella

The trap states in three fullerene derivatives, namely PC61BM ([6,6]-phenyl C61 butyric acid methyl ester), bisPC61BM (bis[6,6]-phenyl C61 butyric acid methyl ester) and PC71BM ([6,6]-phenyl C71 butyric acid methyl ester), are investigated…

Soft Condensed Matter · Physics 2011-07-19 Julia Schafferhans , Carsten Deibel , Vladimir Dyakonov

Blends of polymer and C$_{60}$-derived molecules are in the spotlight in recent years for application in organic photovoltaics, forming what is known as bulk-heterojunction active layers. The character of the heterojunction is determinant,…

Materials Science · Physics 2018-05-29 Rodrigo Ramos , Marília J. Caldas

Organic solar cells (OSCs) containing an active layer consisting of a nanostructured blend of a conjugated polymer like poly(3-hexylthiophene) (P3HT) and an electron acceptor molecule have the potential of competing against silicon-based…

Materials Science · Physics 2020-09-25 Li Quan , Dongrun Ju , Stephanie Lee , Dilhan M. Kalyon

Organic bulk-heterojunctions (BHJ) and solar cells containing the trimetallic nitride endohedral fullerene 1-[3-(2-ethyl)hexoxy carbonyl]propyl-1-phenyl-Lu3N@C80 (Lu3N@C80-PCBEH) show an open circuit voltage (VOC) 0.3 V higher than similar…

Organic solar cells (OSCs) based on ADA-type (acceptor-donor-acceptor) non-fullerene acceptors (NFAs) exhibit improved power conversion efficiency (PCE) compared to the conventional fullerene-based analogues. The optoelectronic properties…

We investigated the charge carrier mobility in pristine poly(3-hexyl thiophene-2,5-diyl) (P3HT):[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) blend devices by applying the time resolved photoconductivity experiment in dependence on the…

Materials Science · Physics 2008-12-23 A. Baumann , J. Lorrmann , C. Deibel , V. Dyakonov

Suppressing charge recombination is key for organic solar cells to become commercial reality. However, there is still no conclusive picture of how recombination losses are influenced by the complex nanoscale morphology. Here, new insight is…

We investigated photogeneration yield and recombination dynamics in blends of poly(3-hexyl thiophene) (P3HT) and poly[2-methoxy-5-(30,70-dimethyloctyloxy)-1,4-phenylenevinylene] (MDMO-PPV) with [6,6]- phenyl-C61 butyric acid methyl ester…

Materials Science · Physics 2012-05-09 Markus Mingebach , Stefan Walter , Vladimir Dyakonov , Carsten Deibel

Optimizing the performance of organic solar cells (OSCs) hinges on a comprehensive understanding of their nanostructures, yet traditional characterization methods often fall short, delivering incomplete structural snapshots. We introduce…

Large-scale practical applications of fullerene (C60) in nanodevices could be significantly facilitated if the commercially-available micrometer-scale raw C60 powder were further processed into a one-dimensional (1D) nanowire-related…

The rapid rise of artificial intelligence, and in-memory computing has reinvigorated research on scalable, energy-efficient, and reconfigurable photonic hardware. Non-volatile phase-change materials (PCMs) are attractive, as they offer…

The incorporation of noble metal nanoparticles, displaying localized surface plasmon resonance, in the active area of donor-acceptor bulk-heterojunction organic photovoltaic devices is an industrially compatible light trapping strategy,…

Materials Science · Physics 2015-11-23 Samuele Lilliu , Mejd Alsari , Oier Bikondoa , J. Emyr Macdonald , Marcus S. Dahlem

Charge carrier recombination is studied in operational organic solar cells made from the polymer:fullerene system PCDTBT:PC71BM (poly[N-9"-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] :…

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