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Non-stoichiometric NaxCoO2 (0.5 < x < 1) consists of CoO2 layers made up of edge-sharing CoO6 octahedra, and exhibits strongly anisotropic magnetic susceptibilities as well as metallic properties. A modified Curie-Weiss law was proposed for…

Strongly Correlated Electrons · Physics 2007-05-23 M. -H. Whangbo , D. Dai , R. K. Kremer

Sodium cobaltate Na_xCoO_2 as dopable strongly correlated layered material with a triangular sublattice still poses a challenging problem in condensed matter. The intriguing interplay between lattice, charge, spin and orbital degrees of…

Strongly Correlated Electrons · Physics 2014-07-22 Lewin Boehnke , Frank Lechermann

Resistivity under magnetic field, thermopower and Hall coefficient are systematically studied for [Bi$_2$Ba$_{1.3}$K$_{0.6}$Co$_{0.1}$]$^{RS}$[CoO$_2$]$_{1.97}$ single crystal. In-plane resistivity ($\rho_{ab}$(T)) shows metallic behavior…

Strongly Correlated Electrons · Physics 2015-05-13 X. G. Luo , H. Chen , G. Y. Wang , G. Wu , T. Wu , L. Zhao , X. H. Chen

Here we report the magnetic properties of the layered cobalt oxide system, LixCoO2, in the whole range of Li composition, 0 <= x <= 1. Based on dc-magnetic susceptibility data, combined with results of 59Co-NMR/NQR observations, the…

Strongly Correlated Electrons · Physics 2009-10-17 T. Motohashi , T. Ono , Y. Sugimoto , Y. Masubuchi , S. Kikkawa , R. Kanno , M. Karppinen , H. Yamauchi

Based on experimental 59Co-NMR data in the temperature range between 0.1 and 300 K, we address the problem of the character of the Co 3d-electron based magnetism in Na0.7CoO2. Temperature dependent 59Co-NMR spectra reveal different Co…

Materials Science · Physics 2009-11-11 J. L. Gavilano , B. Pedrini , K. Magishi , J. Hinderer , M. Weller , H. R. Ott , S. M. Kazakov , J. Karpinski

Here we report an unconventional magnetic and transport phenomenon in a layered cobalt oxide, NaxCoO2. Only for x = 0.75, a magnetic transition of the second order was clearly detected at Tm ~ 22 K where an apparent specific-heat jump, an…

Strongly Correlated Electrons · Physics 2009-11-07 T. Motohashi , R. Ueda , E. Naujalis , T. Tojo , I. Terasaki , T. Atake , M. Karppinen , H. Yamauchi

We report on susceptibility measurements in the strongly correlated layered cobalt oxide [BiBa0.66K0.36O2]CoO2, which demonstrate the existence of a magnetic quantum critical point (QCP) governing the electronic properties. The investigated…

Strongly Correlated Electrons · Physics 2010-07-12 P. Limelette , W. Saulquin , H. Muguerra , D. Grebille

The layered misfit cobaltate Ca$_3$Co$_4$O$_9$, also known as Ca$_2$CoO$_3$[CoO$_2$]$_{1.62}$, is a promising p-type thermoelectric oxide. Employing density functional theory, we study its electronic structure and determine, on the basis of…

Materials Science · Physics 2017-06-13 Bin Amin , Ulrich Eckern , Udo Schwingenschlögl

We investigate the low temperature magnetic field dependence of the resistivity in the thermoelectric misfit cobalt oxide [Bi1.7Ca2O4]0.59CoO2 from 60 K down to 3 K. The scaling of the negative magnetoresistance demonstrates a spin…

Strongly Correlated Electrons · Physics 2008-11-05 Patrice Limelette , Sylvie Hebert , Herve Muguerra , Raymond Fresard , Charles Simon

The magnetothermopower and the magnetoresistance of single Co Ni/Cu multilayered nan-owires with various thicknesses of the Cu spacer are investigated. Both kinds of measurement have been performed as a function of temperature (50 K to 325…

We present our NMR studies of double-layer hydrated cobalt oxides NaxCoO2-yH2O (x ~ 0.35, y ~ 1.3) with various Tc = 0 - 4.8 K and magnetic transition temperatures. High-resolution $^{1}$H NMR spectrum served as an evidence for the…

Superconductivity · Physics 2015-05-13 Y. Itoh , H. Ohta , C. Michioka , M. Kato , K. Yoshimura

The magnetic properties of $\alpha$-NaFeO$_2$ are studied by neutron diffraction and magnetization measurements. An ordered phase with spins aligned along the b$_hex$ axis exists at low temperatures (T < 4 K). At intermediate temperatures…

Strongly Correlated Electrons · Physics 2009-02-02 T. M. McQueen , Q. Huang , J. W. Lynn , R. F. Berger , T. Klimczuk , B. G. Ueland , P. Schiffer , R. J. Cava

We have studied the dielectric responses of the layered cobalt oxysulfide Sr$_2$Cu$_2$CoO$_2$S$_2$ with the CoO$_2$ square-planes. With decreasing temperature below the N\'eel temperature, the resistivity increases like a semiconductor, and…

Materials Science · Physics 2009-11-10 S. Okada , I. Terasaki , H. Ooyama , M. Matoba

We probe the real space electronic response to a local magnetic impurity in isovalent and heterovalent doped BaFe2As2 (122) using Nuclear Magnetic Resonance (NMR). The local moments carried by Mn impurities doped into…

Superconductivity · Physics 2021-11-24 D. LeBoeuf , Y. Texier , M. Boselli , A. Forget , D. Colson , J. Bobroff

The dielectric properties of Fe$_{3}$O$_{4}$ magnetic nanoparticles with an insulating coating layer of SiO$_{2}$ were investigated. At high temperatures, the changes of the dielectric constant and loss induced by the magnetic field are…

Materials Science · Physics 2011-03-18 C. -C. Chang , L. Zhao , M. -K. Wu

We report 23Na NMR studies of the polycrystalline samples of double-layer hydrated cobalt oxides NaxCoO2.yH2O (x ~ 0.35 and y ~ 1.3) with the superconducting transition temperatures Tc < 1.8K and ~4.5K, and the dehydrated NaxCoO2 (x ~…

Superconductivity · Physics 2009-11-11 H. Ohta , Y. Itoh , C. Michioka , K. Yoshimura

We investigate the low temperature magnetic field dependences of both the resistivity and the magnetization in the misfit cobaltate Ca3Co4O9 from 60 K down to 2 K. The measured negative magnetoresistance reveals a scaling behavior with the…

Strongly Correlated Electrons · Physics 2008-11-05 P. Limelette , J. C. Soret , H. Muguerra , D. Grebille

The cobaltates have demonstrated a wide variety complex behavior. The Na rich region of the phase diagram displays various degrees of anomalous behavior, such as Curie-Weiss behavior near a band insulator\cite{Foo:2004}, charge…

Strongly Correlated Electrons · Physics 2009-11-11 C. A. Marianetti , K. Haule , O. Parcollet

A weak magnetic order was found in a non-superconducting bilayered-hydrate Na$_{x}$CoO$_{2}\cdot y$H$_{2}$O sample by a Co Nuclear Quadrupole Resonance (NQR) measurement. The nuclear spin-lattice relaxation rate divided by temperature…

Superconductivity · Physics 2009-11-10 Y. Ihara , K. Ishida , C. Michioka , M. Kato , K. Yoshimura , K. Takada , T. Sasaki , H. Sakurai , E. Takayama-Muromachi

Studies of the NMR Knight shift K of Na0.3CoO2.yH2O have been carried out in detail. The suppression of K by the occurrence of the superconductivity reported previously by the present authors in both magnetic field directions perpendicular…

Superconductivity · Physics 2009-11-11 Yoshiaki Kobayashi , Taketo Moyoshi , Hidekazu Watanabe , Mai Yokoi , Masatoshi Sato