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The thermodynamic uncertainty relation offers a universal energetic constraint on the relative magnitude of current fluctuations in nonequilibrium steady states. However, it has only been derived for long observation times. Here, we prove a…

Statistical Mechanics · Physics 2017-08-30 Jordan M. Horowitz , Todd R. Gingrich

The fluctuation theorems have remained one of the cornerstones in the study of systems that are driven far out of equilibrium, and they provide strong constraints on the fraction of trajectories that behave atypically in light of the second…

Statistical Mechanics · Physics 2015-06-05 Sourabh Lahiri , A. M. Jayannavar

An equilibrium system which is perturbed by an external potential relaxes to a new equilibrium state, a process obeying the fluctuation-dissipation theorem. In contrast, perturbing by nonconservative forces yields a nonequilibrium steady…

Statistical Mechanics · Physics 2019-12-17 Kiryl Asheichyk , Matthias Krüger

We prove a transient fluctuation theorem for the currents for continuous-time Markov jump processes with stationary rates, generalizing an asymptotic result by Andrieux and Gaspard [J. Stat. Phys. 127, 107 (2007)] to finite times. The…

Statistical Mechanics · Physics 2014-10-22 Matteo Polettini , Massimiliano Esposito

The Fluctuation Theorems are a group of exact relations that remain valid irrespective of how far the system has been driven away from equilibrium. Other than having practical applications, like determination of equilibrium free energy…

Statistical Mechanics · Physics 2016-11-04 Sourabh Lahiri , A. M. Jayannavar

These lecture notes give a short review of methods such as the matrix ansatz, the additivity principle or the macroscopic fluctuation theory, developed recently in the theory of non-equilibrium phenomena. They show how these methods allow…

Statistical Mechanics · Physics 2009-11-13 B. Derrida

Coarse-grained models are widely used to explain the effective behavior of partially observable physical systems with hidden degrees of freedom. Reduction procedures in state space typically disrupt Markovianity and a fluctuation relation…

Statistical Mechanics · Physics 2024-09-24 Alberto Garilli , Pedro E. Harunari , Matteo Polettini

Thermodynamics of equilibrium states is well established. However, in nonequilibrium few general results are known. One prime and important example is that of Nyquist theorem. It relates equilibrium tiny voltage fluctuations across a…

Statistical Mechanics · Physics 2014-09-24 Navinder Singh

In this perspective we consider how modern statistical mechanics and response theory can be applied to understand the response of polar molecules to an applied electric field and the fluctuations in these systems. Results that are…

Statistical Mechanics · Physics 2024-01-08 Debra J. Searles , Stephen Sanderson

The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of…

Statistical Mechanics · Physics 2019-06-11 Y. Mishin

We proved when random-variable fluctuations obey the central limit theorem the equality of the uncertainty relation corresponds to the thermodynamic equilibrium state. The inequality corresponds to the thermodynamic non-equilibrium state.…

Quantum Physics · Physics 2007-05-23 You-gang Feng

Two fundamental ingredients play a decisive role in the foundation of fluctuation relations: the principle of microreversibility and the fact that thermal equilibrium is described by the Gibbs canonical ensemble. Building on these two…

Statistical Mechanics · Physics 2012-09-06 Michele Campisi , Peter Hänggi , Peter Talkner

Previously, we have derived a generalization of the canonical fluctuation relation between heat capacity and energy fluctuations $C=\beta^{2}<\delta U^{2}>$, which is able to describe the existence of macrostates with negative heat…

Statistical Mechanics · Physics 2013-07-31 L. Velazquez , S. Curilef

We present a fluctuation relation for heat dissipation in a nonequilibrium system. A nonequilibrium work is known to obey the fluctuation theorem in any time interval $t$. A heat, which differs from a work by an energy change, is shown to…

Statistical Mechanics · Physics 2012-06-19 Jae Dong Noh , Jong-Min Park

Understanding the physics of nonequilibrium systems remains as one of the major challenges of theoretical physics. This problem can be cracked in part by investigating the macroscopic fluctuations of the currents characterizing…

Statistical Mechanics · Physics 2014-03-18 Pablo I. Hurtado , Carlos P. Espigares , Jesus J. del Pozo , Pedro L. Garrido

Near equilibrium, where all currents of a system vanish on average, the fluctuation-dissipation relation (FDR) connects a current's spontaneous fluctuations with its response to perturbations of the conjugate thermodynamic force. Out of…

Statistical Mechanics · Physics 2016-11-02 Bernhard Altaner , Matteo Polettini , Massimiliano Esposito

This paper reports on a macroscopic fluctuation theory developed over the last ten years in collaboration with L. Bertini, A. De Sole, D. Gabrielli and C. Landim. This theory has been inspired by and tested on stochastic models of…

Statistical Mechanics · Physics 2015-05-18 Giovanni Jona-Lasinio

We show for Markov diffusion processes that the quadratic entropic bound, recently derived for the rate functions of nonequilibrium currents, can be seen as being produced by an effective process that creates current fluctuations in a…

Statistical Mechanics · Physics 2023-03-30 Cesare Nardini , Hugo Touchette

The Fluctuation Theorem (FT) gives an analytic expression for the probability, in a nonequilibrium system of finite size observed for a finite time, that the dissipative flux will flow in the reverse direction to that required by the Second…

Statistical Mechanics · Physics 2007-09-10 Gary Ayton , Denis J. Evans , Debra J. Searles

There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…

Statistical Mechanics · Physics 2009-09-25 Gavin E. Crooks