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We have produced ultracold, polar RbCs* molecules via photoassociation in a laser-cooled mixture of Rb and Cs atoms. Using a model of the RbCs* molecular interaction which reproduces the observed rovibrational structure, we infer decay…

Atomic Physics · Physics 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , David DeMille , Thomas Bergeman

We demonstrate the production of ultracold polar RbCs molecules in their vibronic ground state, via photoassociation of laser-cooled atoms followed by a laser-stimulated state transfer process. The resulting sample of $X ^1\Sigma^+ (v=0)$…

Atomic Physics · Physics 2009-11-11 J. M. Sage , S. Sainis , T. Bergeman , D. DeMille

A novel atom-molecule conversion technique has been investigated. Ultracold 85Rb atoms sitting in a DC magnetic field near the 155G Feshbach resonance are associated by applying a small sinusoidal oscillation to the magnetic field. There is…

Other Condensed Matter · Physics 2009-11-11 S. T. Thompson , E. Hodby , C. E. Wieman

We describe the theoretical advances that influenced the experimental creation of vibrationally and translationally cold polar $^{40}$K$^{87}$Rb molecules \cite{nphys08,science08}. Cold molecules were created from very-weakly bound…

Quantum Physics · Physics 2015-05-13 Svetlana Kotochigova , Eite Tiesinga , Paul S. Julienne

Recently, the quest for an ultracold and dense ensemble of polar molecules has attracted strong interest. Polar molecules have bright prospects for novel quantum gases with long-range and anisotropic interactions, for quantum information…

In a combined experimental and theoretical effort, we demonstrate a novel type of dipolar system made of ultracold bosonic dipolar molecules with large magnetic dipole moments. Our dipolar molecules are formed in weakly bound Feshbach…

The conversion of ultracold atoms to molecules via a magnetic Feshbach resonance with a sinusoidal modulation of the field is studied. Different practical realizations of this method in Bose atomic gases are analyzed. Our model incorporates…

Quantum Gases · Physics 2015-06-24 S. Brouard , J. Plata

We discuss the possibility of trapping polar molecules in the standing-wave electromagnetic field of a microwave resonant cavity. Such a trap has several novel features that make it very attractive for the development of ultracold molecule…

Atomic Physics · Physics 2009-11-10 D. DeMille , D. R. Glenn , J. Petricka

We consider the formation of cold ground-state polar molecules in a low vibrational level by laser fields. Starting from a pair of cold colliding atoms of dissimilar species, we propose a strategy consisting of three steps. In the first…

Atomic Physics · Physics 2026-01-14 Emanuel F. de Lima

Using resonance-enhanced two-photon ionization, we detect ultracold, ground-state RbCs molecules formed via photoassociation in a laser-cooled mixture of 85Rb and 133Cs atoms. We obtain extensive bound-bound excitation spectra of these…

Atomic Physics · Physics 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , Thomas Bergeman , David DeMille

Ultracold LiCs molecules in the absolute ground state X$^1\Sigma^+$, v"=0, J"=0 are formed via a single photo-association step starting from laser-cooled atoms. The selective production of v"=0, J"=2 molecules with a 50-fold higher rate is…

Quantum Physics · Physics 2010-08-09 J. Deiglmayr , A. Grochola , M. Repp , K. Mörtlbauer , C. Glück , J. Lange , O. Dulieu , R. Wester , M. Weidemüller

We present a proposal for controlling the conversion of ultracold atoms into molecules by fixing the phase difference between two oscillating magnetic fields. The scheme is based on the use of a magnetic Feshbach resonance with a field…

Quantum Gases · Physics 2015-11-05 J. Plata

We show that radiofrequency (RF) radiation may be used to create Feshbach resonances in ultracold gases of alkali-metal atoms at desired magnetic fields that are convenient for atomic cooling and degeneracy. For the case of…

Atomic Physics · Physics 2016-08-24 Daniel J. Owens , Ting Xie , Jeremy M. Hutson

We report the creation and characterization of a near quantum-degenerate gas of polar $^{40}$K-$^{87}$Rb molecules in their absolute rovibrational ground state. Starting from weakly bound heteronuclear KRb Feshbach molecules, we implement…

We investigate the interactions between ultracold alkali metal atoms and closed-shell atoms using electronic structure calculations on the prototype system Rb+Sr. There are molecular bound states that can be tuned across atomic thresholds…

Atomic Physics · Physics 2015-05-19 Piotr S. Zuchowski , J. Aldegunde , Jeremy M. Hutson

We calculate the microwave spectra of ultracold KRb alkali metal dimers, including hyperfine interactions and in the presence of electric and magnetic fields. We show that microwave transitions may be used to transfer molecules between…

Chemical Physics · Physics 2015-05-13 J. Aldegunde , Hong Ran , Jeremy M. Hutson

A theoretical model is proposed for the formation of ultracold ground-state triatomic molecules in weakly bound energy levels. The process is driven by the electric component of a microwave field, which induces the association of an…

Atomic Physics · Physics 2026-01-16 Baraa Shammout , Leon Karpa , Silke Ospelkaus , Eberhard Tiemann , Olivier Dulieu

Magnetically tunable Feshbach resonances were employed to associate cold diatomic molecules in a series of experiments involving both atomic Bose as well as two spin component Fermi gases. This review illustrates theoretical concepts of…

Other Condensed Matter · Physics 2007-05-23 Thorsten Koehler , Krzysztof Goral , Paul S. Julienne

We report the creation of ultracold bosonic $^{23}$Na$^{87}$Rb Feshbach molecules via magneto-association. By ramping the magnetic field across an interspecies Feshbach resonance, at least 4000 molecules can be produced out of the near…

Atomic Physics · Physics 2015-03-10 Fudong Wang , Xiaodong He , Xiaoke Li , Bing Zhu , Jun Chen , Dajun Wang

The formation of ultracold metastable RbCs molecules is observed in a double species magneto-optical trap through photoassociation below the ^85Rb(5S_1/2)+^133Cs(6P_3/2) dissociation limit followed by spontaneous emission. The molecules are…

Atomic Physics · Physics 2015-06-03 N. Bouloufa-Maafa , M. Aymar , O. Dulieu , C. Gabbanini
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