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A polymer chain containing $N$ monomers confined in a finite cylindrical tube of diameter $D$ grafted at a distance $L$ from the open end of the tube may undergo a rather abrupt transition, where part of the chain escapes from the tube to…

Soft Condensed Matter · Physics 2009-11-13 Hsiao-Ping Hsu , Kurt Binder , Leonid I. Klushin , Alexander M. Skvortsov

The equilibrium thermodynamic properties of a linear polymer chain confined to a space between two impenetrable walls (lines) at a distance $D$ under various solvent conditions have been studied using series analysis and exact enumeration…

Statistical Mechanics · Physics 2007-05-23 P. K. Mishra , Sanjay Kumar

A linear polymer grafted to a hard wall and underneath an AFM tip can be modelled in a lattice as a grafted lattice polymer (or self-avoiding walk) compressed underneath a piston approaching the wall. As the piston approaches the wall the…

Soft Condensed Matter · Physics 2023-08-16 EJ Janse van Rensburg

The escape transition of a polymer "mushroom" (a flexible chain grafted to a flat non-adsorbing substrate surface in a good solvent) occurs when the polymer is compressed by a cylindrical piston of radius $R$, that by far exceeds the chain…

Soft Condensed Matter · Physics 2014-03-05 J. Paturej , A. Milchev , S. A. Egorov , K. Binder

Single two dimensional polymers confined to a strip are studied by Monte Carlo simulations. They are described by N-step self-avoiding random walks on a square lattice between two parallel hard walls with distance 1 << D << N^\nu (\nu = 3/4…

Soft Condensed Matter · Physics 2007-05-23 Hsiao-Ping Hsu , Peter Grassberger

The nature of the globule-coil transition of surface-confined polymers has been an issue of debate. Here this 2D collapse transition is studied through a partially directed lattice model. In the general case of polymers with positive…

Soft Condensed Matter · Physics 2007-05-23 Haijun Zhou , Jie Zhou , Zhong-Can Ou-Yang , Sanjay Kumar

We present a scaling theory and Monte Carlo (MC) simulation results for a flexible polymer chain slowly dragged by one end into a nanotube. We also describe the situation when the completely confined chain is released and gradually leaves…

Soft Condensed Matter · Physics 2009-11-13 Leonid I. Klushin , Alexander M. Skvortsov , Hsiao-Ping Hsu , Kurt Binder

The crumpled-to-flat phase transition that occurs in D-dimensional polymerized phantom membranes embedded in a d-dimensional space is investigated nonperturbatively using a field expansion up to order eight in powers of the order parameter.…

Statistical Mechanics · Physics 2014-04-11 K. Essafi , J. -P. Kownacki , D. Mouhanna

Using Brownian Dynamics, we study the dynamical behavior of a polymer grafted onto an adhesive surface close to the mechanically induced adsorption-stretching transition. Even though the transition is first order, (in the infinite chain…

We investigate the motion of two overlapping polymers with self-avoidance confined in a narrow 2d box. A statistical model is constructed using blob free-energy arguments. We find spontaneous segregation under the condition: $L > R_{//}$,…

Biological Physics · Physics 2012-11-20 Ya Liu , Bulbul Chakraborty

The rate of escape of polymers from a two-dimensionally confining potential well has been evaluated using self-avoiding as well as ideal chain representations of varying length, up to 80 beads. Long timescale Langevin trajectories were…

Soft Condensed Matter · Physics 2015-03-27 Harri Mökkönen , Timo Ikonen , Tapio Ala-Nissila , Hannes Jónsson

Using exact enumeration methods and Monte Carlo simulations we study the phase diagram relative to the conformational transitions of a two dimensional diblock copolymer. The polymer is made of two homogeneous strands of monomers of…

Statistical Mechanics · Physics 2009-10-31 Marco Baiesi , Enrico Carlon , Enzo Orlandini , Attilio L. Stella

Polymers in confined spaces are compressed and have reduced conformational entropy, and will partially or fully escape from confinement if conditions are suitable. This is in particular the case for a polymer grafted in a pore. The escape…

Soft Condensed Matter · Physics 2024-08-05 CJ Bradly , EJ Janse van Rensburg

Through extensive Monte Carlo simulations, we systematically study the effect of chain stiffness on the packing ability of linear polymers composed of hard spheres in extremely confined monolayers, corresponding effectively to 2D films.…

The dynamic transition between the ordered flow and the plastic flow is studied for a two-dimensional driven vortex lattice, in the presence of sharp and dense pinning centers, from numerical simulations. For this system, which does not…

Superconductivity · Physics 2009-11-07 L. Fruchter

We consider the dynamics of polymer translocation out of confined environments. Analytic scaling arguments lead to the prediction that the translocation time scales like $\tau\sim N^{\beta+\nu_{2D}}R^{1+(1-\nu_{2D})/\nu}$ for translocation…

Soft Condensed Matter · Physics 2009-08-11 Kaifu Luo , Ralf Metzler , Tapio Ala-Nissila , See-Chen Ying

We have considered the model of the phase transition of the second order for the Coulomb frustrated 2D charged system. The coupling of the order parameter with the charge was considered as the local temperature. We have found that in such…

Strongly Correlated Electrons · Physics 2018-04-04 R. F. Mamin , T. S. Shaposhnikova , V. V. Kabanov

In the absence of magnetic field or spin-orbit coupling the one-parameter scaling theory predicts localization of all states in two-dimensional (2D) disordered systems, for any amount of disorder. However, a 2D metallic phase has been…

Disordered Systems and Neural Networks · Physics 2016-04-20 Shie-Jie Xiong , G. N. Katomeris , S. N. Evangelou

A polymer chain tethered to a surface may be compact or extended, adsorbed or desorbed, depending on interactions with the surface and the surrounding solvent. This leads to a rich phase diagram with a variety of transitions. To investigate…

Soft Condensed Matter · Physics 2009-11-13 Jutta Luettmer-Strathmann , Federica Rampf , Wolfgang Paul , Kurt Binder

We investigate the ordered morphologies occurring in thin-films diblock copolymer. For temperatures above the order-disorder transition and for an arbitrary two-dimensional surface pattern, we use a Ginzburg-Landau expansion of the free…

Soft Condensed Matter · Physics 2007-05-23 Yoav Tsori , David Andelman
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