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Small thermodynamic systems exhibit peculiar behavior different from that observed in long-scale systems. Non-equilibrium processes taking place in those systems are strongly influenced by the presence of fluctuations which can be large.…

Statistical Mechanics · Physics 2007-05-23 J. M. Rubi

A principle on the macroscopic motion of systems in thermodynamic equilibrium, rarely discussed in texts, is reviewed: Very small but still macroscopic parts of a fully isolated system in thermal equilibrium move as if points of a rigid…

General Physics · Physics 2017-03-09 Juan R. Sanmartin

A recently developed approach to the thermodynamics of open quantum systems, on the basis of the principle of minimal dissipation, is applied to the spin-boson model. Employing a numerically exact quantum dynamical treatment based on the…

Quantum Physics · Physics 2024-08-30 Salvatore Gatto , Alessandra Colla , Heinz-Peter Breuer , Michael Thoss

The thermodynamic approach to non-equilibrium dynamics describes the state of macroscopic systems by means of a collection of intensities or intensive variables. The latter are by definition the differentials of the entropy with respect to…

chao-dyn · Physics 2008-02-03 Z. Hens , X. de Hemptinne

We revisit the concavity property of the thermodynamic entropy in order to formulate a general proof of the minimum energy principle as well as of other equivalent extremum principles that are valid for thermodynamic potentials and…

Statistical Mechanics · Physics 2011-10-25 S. Prestipino , P. V. Giaquinta

A new approach to non-extensive thermodynamical systems with non-additive energy and entropy is proposed. The main idea of the paper is based on the statistical matching of the thermodynamical systems with the additive multi-step Markov…

Data Analysis, Statistics and Probability · Physics 2007-05-23 S. S. Apostolov , Z. A. Mayzelis , O. V. Usatenko , V. A. Yampol'skii

Open quantum systems are studied from the thermodynamical point of view unifying the principle of maximum informational entropy and the hypothesis of relaxation times hierarchy. The result of the unification is a non-Markovian and local in…

Quantum Physics · Physics 2014-11-24 Vitalii Semin , Francesco Petruccione

The accurate determination of transport coefficients in numerical simulations is becoming increasingly important in a wide range of applications. Here we consider the linear response in systems driven away from thermal equilibrium into a…

Statistical Mechanics · Physics 2016-08-24 Thomas Speck

In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this…

Quantum Physics · Physics 2017-06-28 Thibaut Josset

Reducing work fluctuation and dissipation in heat engines or, more generally, information heat engines that perform feedback control is vital to maximize their efficiency. The same problem arises when we attempt to maximize the efficiency…

Statistical Mechanics · Physics 2016-01-06 Ken Funo , Masahito Ueda

We challenge claims that the principle of maximum entropy production produces physical phenomenological relations between conjugate currents and forces, even beyond the linear regime, and that currents in networks arrange themselves to…

Statistical Mechanics · Physics 2016-11-26 Matteo Polettini

We study a micro-magnet that interacts with a spin-polarized electric current, a heat bath, as well as a static magnetic field. The resulting non-equilibrium steady-state transports entropy between the current and the heat bath, without…

Statistical Mechanics · Physics 2025-02-11 Mingnan Ding , Jun Wu , Xiangjun Xing

Adaptive systems -- such as a biological organism gaining survival advantage, an autonomous robot executing a functional task, or a motor protein transporting intracellular nutrients -- must model the regularities and stochasticity in their…

Statistical Mechanics · Physics 2021-04-13 A. B. Boyd , J. P. Crutchfield , M. Gu

We present the stochastic thermodynamics analysis of an open quantum system weakly coupled to multiple reservoirs and driven by a rapidly oscillating external field. The analysis is built on a modified stochastic master equation in the…

Statistical Mechanics · Physics 2015-05-12 Gregory Bulnes Cuetara , Andreas Engel , Massimiliano Esposito

It is shown that an oldest form of variational calculus of mechanics, the Maupertuis least action principle, can be used as a simple and powerful approach for the formulation of the variational principle for damped motions, allowing a…

Statistical Mechanics · Physics 2015-12-18 Qiuping A. Wang

Many have speculated whether nonequilibrium systems obey principles of maximum or minimum entropy production. In this work, we use stochastic thermodynamics to derive the condition for the minimum entropy production state (MEPS) for…

Statistical Mechanics · Physics 2025-07-25 Kyle J. Ray , Alexander B. Boyd

Thermodynamics is a well developed tool to study systems in equilibrium but no such general framework is available for non-equilibrium processes. Only hope for a quantitative description is to fall back upon the equilibrium language as…

Statistical Mechanics · Physics 2015-05-14 Poulomi Sadhukhan , Somendra M. Bhattacharjee

The principle of maximum entropy is a broadly applicable technique for computing a distribution with the least amount of information possible while constrained to match empirically estimated feature expectations. However, in many real-world…

Machine Learning · Computer Science 2022-08-16 Kenneth Bogert , Yikang Gui , Prashant Doshi

In this paper, we consider the stochastic optimal control problem for the interacting particle system. We obtain the stochastic maximum principle of the optimal control system by introducing a generalized backward stochastic differential…

Probability · Mathematics 2025-05-14 Andrey A. Dorogovtsev , Yuecai Han , Kateryna Hlyniana , Yuhang Li

The goal of the paper is to derive a revised condition of global equilibrium in complex chemical systems as variational principle in formalism of recently developed discrete thermodynamics (DTD) of chemical equilibria. In classical approach…

Chemical Physics · Physics 2010-11-13 B. Zilbergleyt